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Mixed potential type sensor based on Gd2Zr2O7 solid electrolyte and BiVO4 sensing electrode for effective detection of triethylamine.
Jiang, Li; Liu, Yong; Sun, Wei; Tang, Minghao; Zhang, Yueying; Lv, Siyuan; Wang, Jing; Liu, Yi; Wang, Chenguang; Sun, Peng; Zheng, Jie; Liu, Fangmeng; Lu, Geyu.
Afiliação
  • Jiang L; State Key Laboratory of Integrated Optoelectronics, Key Laboratory of Advanced Gas Sensors, Jilin Province, College of Electronic Science and Engineering, Jilin University, 2699 Qianjin Street, Changchun 130012, China.
  • Liu Y; State Key Laboratory of Integrated Optoelectronics, Key Laboratory of Advanced Gas Sensors, Jilin Province, College of Electronic Science and Engineering, Jilin University, 2699 Qianjin Street, Changchun 130012, China.
  • Sun W; State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, China.
  • Tang M; State Key Laboratory of Integrated Optoelectronics, Key Laboratory of Advanced Gas Sensors, Jilin Province, College of Electronic Science and Engineering, Jilin University, 2699 Qianjin Street, Changchun 130012, China.
  • Zhang Y; State Key Laboratory of Integrated Optoelectronics, Key Laboratory of Advanced Gas Sensors, Jilin Province, College of Electronic Science and Engineering, Jilin University, 2699 Qianjin Street, Changchun 130012, China.
  • Lv S; State Key Laboratory of Integrated Optoelectronics, Key Laboratory of Advanced Gas Sensors, Jilin Province, College of Electronic Science and Engineering, Jilin University, 2699 Qianjin Street, Changchun 130012, China.
  • Wang J; School of Electronic and Information Engineering, Changchun University of Science and Technology, Changchun 130022, China.
  • Liu Y; State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, China. Electronic address: yiliuchem@jlu.edu.cn.
  • Wang C; State Key Laboratory of Integrated Optoelectronics, Key Laboratory of Advanced Gas Sensors, Jilin Province, College of Electronic Science and Engineering, Jilin University, 2699 Qianjin Street, Changchun 130012, China; International Center of Future Science, Jilin University, 2699 Qianjin Street, Ch
  • Sun P; State Key Laboratory of Integrated Optoelectronics, Key Laboratory of Advanced Gas Sensors, Jilin Province, College of Electronic Science and Engineering, Jilin University, 2699 Qianjin Street, Changchun 130012, China; International Center of Future Science, Jilin University, 2699 Qianjin Street, Ch
  • Zheng J; State Key Laboratory of Integrated Optoelectronics, Key Laboratory of Advanced Gas Sensors, Jilin Province, College of Electronic Science and Engineering, Jilin University, 2699 Qianjin Street, Changchun 130012, China.
  • Liu F; State Key Laboratory of Integrated Optoelectronics, Key Laboratory of Advanced Gas Sensors, Jilin Province, College of Electronic Science and Engineering, Jilin University, 2699 Qianjin Street, Changchun 130012, China; International Center of Future Science, Jilin University, 2699 Qianjin Street, Ch
  • Lu G; State Key Laboratory of Integrated Optoelectronics, Key Laboratory of Advanced Gas Sensors, Jilin Province, College of Electronic Science and Engineering, Jilin University, 2699 Qianjin Street, Changchun 130012, China; International Center of Future Science, Jilin University, 2699 Qianjin Street, Ch
J Hazard Mater ; 440: 129695, 2022 10 15.
Article em En | MEDLINE | ID: mdl-35963092
ABSTRACT
Triethylamine (TEA), as a common and widely used industrial raw material, is extremely hazardous to the environment and human health. Therefore, the development of a portable gas-sensing technology for high-efficiency detection of TEA is of great worth for human health and environmental monitoring. In this work, a mixed potential type TEA sensor was initially developed based on pyrochlore Gd2Zr2O7 solid state electrolyte and BiVO4 sensing electrode. The sensor generates high response values of - 62.2 mV and - 134.4 mV to 5 ppm and 100 ppm TEA at 500 °C, respectively. The response value of the sensor displays a logarithmic linear relationship with the concentration of TEA in the range of 1-100 ppm with the sensitivity of - 50.8 mV/decade. Besides, the sensor shows good response and recovery characteristics, and the response and recovery time to 10 ppm TEA is 10 s and 89 s, respectively. Moreover, the sensor possesses good humidity resistance, reproducibility and stability. The sensing behavior of the sensor is explained by the mixed potential sensing mechanism, which is confirmed by the measurement of the polarization curves. This work provides a good supplement for TEA gas sensor, which holds important application value for the sensitive detection of TEA in the environment.
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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Eletrólitos / Etilaminas Idioma: En Ano de publicação: 2022 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Assunto principal: Eletrólitos / Etilaminas Idioma: En Ano de publicação: 2022 Tipo de documento: Article