Preparation and study of the flame retardant properties of C60/PMMA microspheres.
RSC Adv
; 12(35): 22623-22630, 2022 Aug 10.
Article
em En
| MEDLINE
| ID: mdl-36105985
ABSTRACT
In this paper, highly flame retardant C60/PMMA composites were prepared using an in situ polymerization method by introducing fullerene (C60) into polymethyl methacrylate (PMMA) to improve its combustion characteristics. The apparent morphologies of PMMA and C60/PMMA microspheres were observed by scanning electron microscopy (SEM), and the structure was characterized by infrared spectroscopy (FT-IR). The thermal stability and flame retardancy were characterized using a synchronous thermal analyzer, a cone calorimeter and an oxygen index tester. The results show that the maximum initial decomposition temperature of C60/PMMA-2 (prepared using C60 with a concentration of 2 mg mL-1) is 234.89 °C, which is about 59.89 °C higher than that of PMMA, and the thermal stability is the best. The limiting oxygen index of the C60/PMMA-2 composite is 21.8, which is 28.2% higher than that of pure PMMA. In addition, the peak heat release rate (PHRR) of C60/PMMA is reduced by 630.4 kW m-2 when compared with pure PMMA, which means that the flame retardant property is improved. Meanwhile, the mechanical properties of the PMMA are also improved by adding C60.
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MEDLINE
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Ano de publicação:
2022
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Article