Human carcinogenic risk analysis and utilization of shale gas water-based drilling cuttings in road materials.

ABSTRACT

Water-based drilling cuttings (WDC) generated during shale gas development will endanger human health and ecological security. The modern analytical techniques are used to analyze the organic pollutants in WDC, and the human health and ecological security risks of harmful pollutants in WDC under specific scenarios are evaluated. The results showed that the content of organic pollutants in WDC was evaluated by human health and safety risk assessment. The comprehensive carcinogenic risks of all exposure pathways of single pollutant benzo(a)anthracene, benzo(a)pyrene, benzo(k)fluoranthene, and indeno(1,2,3-cd)pyrene were acceptable. However, the cumulative carcinogenic risk of exposure to dibenzo(a,h)anthracene particles via skin exposure was not acceptable. It was considered that only dibenzo(a,h)anthracene had carcinogenic effect, and the risk control limit of dibenzo(a,h)anthracene in WDC was 1.8700 mg/kg by calculation. As well as, the "WDC-cement" gel composite structure was deeply analyzed, and the physical and chemical properties and mechanism of organic pollutants in cement solidified WDC were analyzed, which provided theoretical support for the study of WDC pavement cushion formula. Based on the above conclusions and combined with the actual site, by studying and adjusting the formula of WDC pavement cushion, the WDC pavement cushion was finally designed by 6% cement + 50% WDC + 44% crushed stone. The 7d unconfined compressive strength met the requirements of the Chinese standard "Technical Guidelines for Construction of Highway Roadbases" (JTG/T F20-2015). Also, the process route of WDC as road cushion product was sampled and analyzed. In addition, the leaching concentration of main pollutants all met the relevant standards of China. Therefore, this study can provide a favorable way for the efficient, safe, and environmentally friendly utilization of WDC, and ensure the ecological environment safety and human health safety of WDC in resource utilization.