A Water-Soluble Leggero Pillar[5]arene.
Molecules
; 27(19)2022 Sep 23.
Article
em En
| MEDLINE
| ID: mdl-36234796
ABSTRACT
The study of aqueous-phase molecular recognition of artificial receptors is one of the frontiers in supramolecular chemistry since most biochemical processes and reactions take place in an aqueous medium and heavily rely on it. In this work, a water-soluble version of leggero pillar[5]arene bearing eight positively charged pyridinium moieties (CWP[5]L) was designed and synthesized, which exhibited good binding affinities with certain aliphatic sulfonate species in aqueous solutions. Significantly, control experiments demonstrate that the guest binding performance of CWP[5]L is superior to its counterpart water-soluble macrocyclic receptor in traditional pillararenes.
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Base de dados:
MEDLINE
Assunto principal:
Calixarenos
/
Receptores Artificiais
Idioma:
En
Ano de publicação:
2022
Tipo de documento:
Article