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Tetra-µ-acetato-κ8 O:O'-bis-[(3-chloro-pyridine-κN)ruthenium(II,III)](Ru-Ru) hexa-fluorido-phosphate 1,2-di-chloro-ethane monosolvate.
Aquino, Anthony J; Gerrior, Daniel; Cameron, T Stanley; Robertson, Katherine N; Aquino, Manuel A S.
Afiliação
  • Aquino AJ; Department of Chemistry, St. Francis Xavier University, PO Box 5000, Antigonish, NS, Canada, B2G 2W5.
  • Gerrior D; Department of Chemistry, St. Francis Xavier University, PO Box 5000, Antigonish, NS, Canada, B2G 2W5.
  • Cameron TS; Department of Chemistry, Dalhousie University, 6274 Coburg Rd, Halifax, NS, Canada, B3H 4R2.
  • Robertson KN; Department of Chemistry, Saint Mary's University, Halifax, NS, Canada, B3H 3C3.
  • Aquino MAS; Department of Chemistry, St. Francis Xavier University, PO Box 5000, Antigonish, NS, Canada, B2G 2W5.
IUCrdata ; 7(Pt 3): x220249, 2022 Mar.
Article em En | MEDLINE | ID: mdl-36339799
ABSTRACT
The title compound, [Ru2(µ-O2CCH3)4(C5H4ClN)2]PF6·C2H4Cl2, was obtained via a rapid substitution reaction of 3-chloro-pyridine for water in [Ru2(µ-O2CCH3)4(H2O)2]PF6 in 2-propanol and subsequent crystallization from a di-chloro-ethane solution. The cationic diruthenium(II,III) tetra-acetate core lies on a crystallographic inversion center with Ru-Ru and Ru-N bond lengths of 2.2738 (3) and 2.2920 (17) Å, respectively. The Ru-Ru-N bond angle is close to linear at 176.48 (4)°, and a significant π-stacking inter-action of 3.5649 (16) Šis seen between overlapping pyridine rings of adjacent cations.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2022 Tipo de documento: Article
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2022 Tipo de documento: Article