Chitosan functionalized bismuth oxychloride/zinc oxide nanocomposite for enhanced photocatalytic degradation of Congo red.

The industrial discharge of dye pollutant contaminated wastewater is the major cause of water and soil pollution. Photocatalysis is a promising and green remediation technology, which has received widespread attention in the remediation of hazardous dyes from aqueous environment and convert them into harmless compounds. Herein, we report the synthesis of chitosan (CS) functionalized bismuth oxychloride/zinc oxide (BiOCl/ZnO) nanocomposite by a modified hydrothermal route. The physiochemical characterization revealed that the synthesized nanocomposite have crystalline, agglomerated spherical along with rod shaped morphology and size range from 35 to 160 nm. FTIR peaks at 825, 727, 662 and 622 cm-1 specified the presence of BiO and ZnO bonds, whereas peak at 1635 cm-1 revealed the existence of amine groups which confirms the presence of CS in the synthesized CS-BiOCl/ZnO nanocomposite. Catalytic property of synthesized nanocomposite was evaluated by the degradation of Congo red (CR) under UV-light irradiation. CR dye degradation percentage was found to be 93 % within a short period of 40 min by utilizing UV-light. Furthermore, reusability of CS-BiOCl/ZnO photocatalyst was also investigated, and it remained significant photocatalytic activity after three consecutive cycles. Hence, the results obtained in this study revealed that CS-BiOCl/ZnO nanocomposite can be used as a potential photocatalyst to remediate organic pollutants in various industries.