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Enhanced basicity of an electron donor-acceptor complex.
Stevenson, Bernard G; Prascsak, Amanada V; Lee, Annemarie A; Talbott, Eric D; Fredin, Lisa A; Swierk, John R.
Afiliação
  • Stevenson BG; Department of Chemistry, State University of New York Binghamton, 4400 Vestal Parkway East, Binghamton, NY 13902, USA. jswierk@binghamton.edu.
  • Prascsak AV; Department of Chemistry, Lehigh University, 6 E. Packer Ave, Seeley G. Mudd, Bethlehem, PA 18015, USA. laf218@lehigh.edu.
  • Lee AA; Department of Chemistry, State University of New York Binghamton, 4400 Vestal Parkway East, Binghamton, NY 13902, USA. jswierk@binghamton.edu.
  • Talbott ED; Department of Chemistry, State University of New York Binghamton, 4400 Vestal Parkway East, Binghamton, NY 13902, USA. jswierk@binghamton.edu.
  • Fredin LA; Department of Chemistry, Lehigh University, 6 E. Packer Ave, Seeley G. Mudd, Bethlehem, PA 18015, USA. laf218@lehigh.edu.
  • Swierk JR; Department of Chemistry, State University of New York Binghamton, 4400 Vestal Parkway East, Binghamton, NY 13902, USA. jswierk@binghamton.edu.
Chem Commun (Camb) ; 59(20): 2943-2945, 2023 Mar 07.
Article em En | MEDLINE | ID: mdl-36799450
ABSTRACT
An electron donor-acceptor (EDA) complex forms between 1,4-dicyanobenzene and N-phenylpyrrolidine, which are coupling partners for the α-aminoarylation photoredox reaction. Calculations and experiments demonstrate the EDA complex is a better base than N-phenylpyrroline. A re-analysis of the α-aminoarylation reaction suggests that the EDA complex is a proton acceptor in the reaction.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article