Transition Metal-Free Aromatic C-H, C-N, C-S and C-O Borylation.
Chem Rec
; 23(4): e202300023, 2023 Apr.
Article
em En
| MEDLINE
| ID: mdl-36850026
ABSTRACT
Aromatic organoboron compounds are highly valuable building blocks in organic chemistry. They were mainly synthesized through aromatic C-H and C-Het borylation, in which transition metal-catalysis dominate. In the past decade, with increasing attention to sustainable chemistry, numerous transition metal-free C-H and C-Het borylation transformations have been developed and emerged as efficient methods towards the synthesis of aromatic organoboron compounds. This account mainly focuses on recent advances in transition metal-free aromatic C-H, C-N, C-S, and C-O borylation transformations and provides insights to where further developments are required.
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MEDLINE
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En
Ano de publicação:
2023
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Article