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Nickel-Catalyzed Direct Cross-Coupling of Aryl Thioether with Aryl Bromide.
Ma, Na-Na; Hu, Xuan-Bo; Wu, Yuan-Shuai; Zheng, Ya-Wen; Ma, Mengtao; Chu, Xue-Qiang; Xu, Hao; Luo, Haiqing; Shen, Zhi-Liang.
Afiliação
  • Ma NN; Technical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China.
  • Hu XB; Technical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China.
  • Wu YS; Technical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China.
  • Zheng YW; Technical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China.
  • Ma M; College of Science, Nanjing Forestry University, Nanjing 210037, China.
  • Chu XQ; Technical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China.
  • Xu H; Technical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China.
  • Luo H; Department of Chemistry & Chemical Engineering, Gannan Normal University, Ganzhou 341000, China.
  • Shen ZL; Technical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China.
Org Lett ; 25(10): 1771-1775, 2023 Mar 17.
Article em En | MEDLINE | ID: mdl-36862539
ABSTRACT
A straightforward cross-coupling of aryl thioether with aryl bromide with the aid of nickel salt, magnesium, and lithium chloride in tetrahydrofuran at ambient temperature was accomplished. The one-pot reactions proceeded efficiently via C-S bond cleavage to produce the desired biaryls in modest to good yields, avoiding the use of pregenerated or commercial organometallic reagents.

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article