Field assessment of metal and base cation accumulation in green stormwater infrastructure soils.

Green stormwater infrastructure (GSI) is adopted to reduce the impact of stormwater on urban flooding and water quality issues. This study assessed the performance of GSI, like bioretention basins, in accumulating metals. Twenty one GSI basins were considered for this study, which were located in New York and Pennsylvania, USA. Shallow (0-5 cm) soil samples were collected from each site at inlet, pool, and adjacent reference locations. The study analyzed 3 base cations (Ca, Mg, Na) and 6 metals (Cd, Cr, Cu, Ni, Pb, and Zn), some of which are toxic to ecosystem and human health. The accumulation of cations/metals at the inlet and pool differed between the selected basins. However, accumulation was consistently higher at the inlet or the pool of the basin as compared to the reference location. Contrary to prior research, this study did not find significant accumulation with age, suggesting that other factors such as site characteristics (e.g., loading rate) might be confounding. GSI basins that receive water only from parking lots or parking lots and building roofs combined showed higher metals and Na accumulation as compared to the basins that received stormwater only from building roofs. Cu, Mg and Zn accumulation showed a positive relationship with the organic matter content in soil, indicating likely sorption of metals on organic matter. Ca and Cu accumulation was greater in GSI basins with larger drainage areas. A negative relationship between Cu and Na implies that Na loading from de-icers may reduce Cu retention. Overall, the study found that the GSI basins are successfully accumulating metals and some base cations, with highest accumulation at the inlet. Additionally, this study provided evidence of GSI effectiveness in accumulating metals using a more cost efficient and time averaged approach compared to traditional means of stormwater inflow and outflow monitoring.