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Regioselective Dehydrogenative Reverse Prenylation of Indoles with 2-Methyl-2-butene.
Li, Yong-Hua; Wang, Meng-Yue; Zhao, Bao-Yin; Zhang, Hong-Xia; Guo, Shi-Huan; Jia, Qiong; Wang, Yong-Qiang.
Afiliação
  • Li YH; Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, School of Foreign Languages, College of Chemistry & Materials Science, Northwest University, 710069, Xi'an, P. R. China.
  • Wang MY; Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, School of Foreign Languages, College of Chemistry & Materials Science, Northwest University, 710069, Xi'an, P. R. China.
  • Zhao BY; Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, School of Foreign Languages, College of Chemistry & Materials Science, Northwest University, 710069, Xi'an, P. R. China.
  • Zhang HX; Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, School of Foreign Languages, College of Chemistry & Materials Science, Northwest University, 710069, Xi'an, P. R. China.
  • Guo SH; Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, School of Foreign Languages, College of Chemistry & Materials Science, Northwest University, 710069, Xi'an, P. R. China.
  • Jia Q; Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, School of Foreign Languages, College of Chemistry & Materials Science, Northwest University, 710069, Xi'an, P. R. China.
  • Wang YQ; Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, School of Foreign Languages, College of Chemistry & Materials Science, Northwest University, 710069, Xi'an, P. R. China.
Chemistry ; 29(37): e202300933, 2023 Jul 03.
Article em En | MEDLINE | ID: mdl-37040176
ABSTRACT
Bulk chemical 2-methyl-2-butene, one of the main C5 distillates of the petrochemical industry, has scarcely been utilized directly in synthesizing high-value-added fine chemicals. Herein, we use 2-methyl-2-butene as the starting material to develop a palladium-catalyzed highly site- and regio-selective C-3 dehydrogenation reverse prenylation of indoles. This synthetic method features mild reaction conditions, a broad substrate scope, atom- and step-economies.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article