Tuning the Li+ Solvation Structure by a "Bulky Coordinating" Strategy Enables Nonflammable Electrolyte for Ultrahigh Voltage Lithium Metal Batteries.
ACS Nano
; 17(10): 9586-9599, 2023 May 23.
Article
em En
| MEDLINE
| ID: mdl-37127844
ABSTRACT
In battery electrolyte design principles, tuning Li+ solvation structure is an effective way to connect electrolyte chemistry with interfacial chemistry. Although recent proposed solvation tuning strategies are able to improve battery cyclability, a comprehensive strategy for electrolyte design remains imperative. Here, we report a solvation tuning strategy by utilizing molecular steric effect to create a "bulky coordinating" structure. Based on this strategy, the designed electrolyte generates an inorganic-rich solid electrolyte interphase (SEI) and cathode-electrolyte interphase (CEI), leading to excellent compatibility with both Li metal anodes and high-voltage cathodes. Under an ultrahigh voltage of 4.6 V, Li/NMC811 full-cells (N/P = 2.0) hold an 84.1% capacity retention over 150 cycles and industrial Li/NMC811 pouch cells realize an energy density of 495 Wh kg-1. This study provides innovative insights into Li+ solvation tuning for electrolyte engineering and offers a promising path toward developing high-energy Li metal batteries.
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MEDLINE
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En
Ano de publicação:
2023
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Article