Role of acidic hydrochar on dechlorination of waste PVC in high temperature hydrothermal treatment and fuel properties enhancement of solid residues.
Waste Manag
; 169: 125-136, 2023 Sep 01.
Article
em En
| MEDLINE
| ID: mdl-37423054
ABSTRACT
In this study, the chlorine mitigation from waste polyvinyl chloride (WPVC) during high temperature co-hydrothermal treatment (co-HTT) and the properties of the generated solid products were assessed. WPVC was co-fed with acidic hydrochar (AHC), which was produced via hydrothermal carbonization of pineapple waste in the presence of citric acid water solution. High temperature co-HTT experiments were performed at 300-350 °C, 0.25-4 h of reaction time, and 0-20 wt% AHC loading. Co-HTT solid products (co-HTT_SP) were characterized via proximate analysis, ultimate analyses, combustion analysis, and ash analysis. The results show that the addition of 5% AHC enhances the dechlorination efficiency (DE) of WPVC from 89.35% to 97.66% at 325 °C and 0.5 h. The highest DE, reaching 99.46%, was achieved at 350 °C and 1 h in the presence of 5 wt% AHC. Furthermore, loading 5% AHC improved the higher heat value (HHV) of the solid products from 23.09 to 31.25 MJ/kg at 325 °C and 0.5 h. The maximum HHV (34.77 MJ/kg) of a solid product was achieved at 350 °C, 4 h, in the presence of 5 wt% of AHC. The co-HTT solids shown low slagging indices, fouling indices, alkali indices, and medium chlorine contents. These findings support the viability of WPVC conversion into clean solid fuel via co-HTT.
Palavras-chave
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Carbono
/
Cloro
Idioma:
En
Ano de publicação:
2023
Tipo de documento:
Article