A High-Potential Bipolar Phenothiazine Derivative Cathode for Aqueous Zinc Batteries.
ChemSusChem
; 16(19): e202300658, 2023 Oct 06.
Article
em En
| MEDLINE
| ID: mdl-37491683
ABSTRACT
Aqueous zinc ion batteries (AZIBs) are gaining popularity as advanced energy storage devices that are economical, safe, and use resource-abundant storage options. In this study, we have synthesized a bipolar phenothiazine organic scaffold known as 3,7-bis(melaminyl)phenothiazin-5-ium iodide (PTDM), which is obtained by undergoing nucleophilic substitution through phenothiazinium tetraiodide hydrate (PTD) and melamine. Electrochemical results indicate that PTDM can act as a high-potential cathode material for rechargeable AZIBs. In detail, the aqueous PTDM//Zn full cell exhibits a high average voltage of approximate 1.13â
V, along with a specific capacity of 118.3â
mAh g-1 at 0.1â
A g-1 . Furthermore, this demonstrated cell displays moderate long-term cycling stability over 6400 cycles, which is encouraging and suggests potential for developing advanced organic electrode materials for rechargeable AZIBs.
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MEDLINE
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En
Ano de publicação:
2023
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Article