A lens-shaped supramolecule based on the bulky pentaphosphaferrocene [CpBIGFe(η5-P5)] and CuBr2.
Chem Commun (Camb)
; 59(68): 10263-10266, 2023 Aug 22.
Article
em En
| MEDLINE
| ID: mdl-37534857
ABSTRACT
Besides inherent fullerene-like hollow spheres, the metallasupramolecular chemistry of pentaphosphaferrocenes and CuBr2 afforded a conceptually new product, a compact 3.2 nm sized supramolecule [{1d}6(CuBr)32(CH3CN)6] formed by six largest pentaphosphaferrocene units [CpBIGFe(η5-P5)] (1d CpBIG = η5-C5(4-nBuC6H4)5) so far and a framework of 32 copper and 32 bromide ions.
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MEDLINE
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En
Ano de publicação:
2023
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Article