Combination of 3-O-Levulinoyl and 6-O-Trifluorobenzoyl Groups Ensures &#945;-Selectivity in Glucosylations: Synthesis of the Oligosaccharides Related to Aspergillus fumigatus &#945;-(1 â 3)-d-Glucan.

Komarova, Bozhena S; Novikova, Natalia S; Gerbst, Alexey G; Sinitsyna, Olga A; Rubtsova, Ekaterina A; Kondratyeva, Elena G; Sinitsyn, Arkady P; Nifantiev, Nikolay E

Combination of 3-O-Levulinoyl and 6-O-Trifluorobenzoyl Groups Ensures α-Selectivity in Glucosylations: Synthesis of the Oligosaccharides Related to Aspergillus fumigatus α-(1 â 3)-d-Glucan.

Komarova, Bozhena S; Novikova, Natalia S; Gerbst, Alexey G; Sinitsyna, Olga A; Rubtsova, Ekaterina A; Kondratyeva, Elena G; Sinitsyn, Arkady P; Nifantiev, Nikolay E.

Afiliação

Komarova BS; Laboratory of Glycoconjugate Chemistry, N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 119991, Russia.
Novikova NS; Laboratory of Glycoconjugate Chemistry, N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 119991, Russia.
Gerbst AG; Laboratory of Glycoconjugate Chemistry, N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 119991, Russia.
Sinitsyna OA; Department of Chemistry, M.V. Lomonosov Moscow State University, Vorobyevy Gory 1-11, Moscow 119992, Russia.
Rubtsova EA; FRC "Fundamentals of Biotechnology", Russian Academy of Sciences, Leninsky prospect 33-2, Moscow 119071, Russia.
Kondratyeva EG; FRC "Fundamentals of Biotechnology", Russian Academy of Sciences, Leninsky prospect 33-2, Moscow 119071, Russia.
Sinitsyn AP; Department of Chemistry, M.V. Lomonosov Moscow State University, Vorobyevy Gory 1-11, Moscow 119992, Russia.
Nifantiev NE; FRC "Fundamentals of Biotechnology", Russian Academy of Sciences, Leninsky prospect 33-2, Moscow 119071, Russia.

J Org Chem ; 88(17): 12542-12564, 2023 09 01.

Article em En | MEDLINE | ID: mdl-37593939

Assuntos

Aspergillus fumigatus; Oligossacarídeos; Teoria da Densidade Funcional; Elétrons; Glucanos

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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Oligossacarídeos / Aspergillus fumigatus Idioma: En Ano de publicação: 2023 Tipo de documento: Article

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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Oligossacarídeos / Aspergillus fumigatus Idioma: En Ano de publicação: 2023 Tipo de documento: Article