Tetracoordinated 15-Electron Ruthenium(I) in a Discrete Triruthenium Framework.

ABSTRACT

This paper highlights the unique case of a tetracoordinated Ru(I) (15-electron) component in a structurally characterized discrete triruthenium setup, [(acac)2RuIIIL1(µ-RuI)L1RuII (acac)2](ClO4)2 ([3](ClO4)2, where acac = acetylacetonate; S = 1), which was formed along with the monomeric [(acac)2RuIII(L1)] ([1]ClO4; S = 1/2) and dimeric [{(acac)2RuIII}2(µ-L1)](ClO4)2 ([2](ClO4)2; S = 1) counterparts upon interaction of {Ru(acac)2} and L1 = 3,3'-dipyridin-2-yl-1,1'-bis(imidazo[1,5-a]pyridinyl).