Cyclo-E5-bridged trinuclear triple-decker complexes (E = P, As) containing a triply-bonded Mo2 unit and their isomerisation.
Chem Commun (Camb)
; 59(75): 11192-11195, 2023 Sep 19.
Article
em En
| MEDLINE
| ID: mdl-37650148
ABSTRACT
The reaction of the low-coordinate quadruply-bonded dimolybdenum complex Mo2[µ,κ2-PhB(N-2,6-iPr2C6H3)2]2 (1) with Cp*Fe(η5-E5) (E = P, As) gives two trinuclear species Cp*Fe(µ3,η522-E5)Mo2[µ,κ2-PhB(N-2,6-iPr2C6H3)2]2 (E = P (4) and As (5)). 4 undergoes facile isomerisation upon heating to give Cp*FeMo2[κ2-PhB(N-2,6-iPr2C6H3)2](µ3,κκη2-P2)[µ3,κκη3κ-P3PhB(N-2,6-iPr2C6H3)2] (6), where the FeMo2P5 core motif displays a cubane-like structure.
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MEDLINE
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En
Ano de publicação:
2023
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Article