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Icosidodecahedral Coordination-Saturated Cuprofullerene.
Zhan, Shun-Ze; Liu, Yu-Li; Cai, Hong; Li, Ming-De; Huang, Qibin; Wang, Xu-Dong; Li, Mian; Dang, Li; Ng, Seik Weng; Lu, Weigang; Li, Dan.
Afiliação
  • Zhan SZ; College of Chemistry and Chemical Engineering, and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Shantou, 515063, P. R. China.
  • Liu YL; College of Chemistry and Materials Science and Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou, 510632, P. R. China.
  • Cai H; College of Chemistry and Chemical Engineering, and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Shantou, 515063, P. R. China.
  • Li MD; School of Chemistry and Environmental Engineering, Hanshan Normal University, Chaozhou, 521041, P. R. China.
  • Huang Q; College of Chemistry and Chemical Engineering, and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Shantou, 515063, P. R. China.
  • Wang XD; College of Chemistry and Chemical Engineering, and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Shantou, 515063, P. R. China.
  • Li M; School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275, P. R. China.
  • Dang L; College of Chemistry and Chemical Engineering, and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Shantou, 515063, P. R. China.
  • Ng SW; College of Chemistry and Chemical Engineering, and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Shantou, 515063, P. R. China.
  • Lu W; UCSI University, Cheras, Kuala Lumpur, 56000, Malaysia.
  • Li D; College of Chemistry and Materials Science and Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou, 510632, P. R. China.
Angew Chem Int Ed Engl ; 62(43): e202312698, 2023 Oct 23.
Article em En | MEDLINE | ID: mdl-37682089
The first coordination-saturated buckyball with a C60 molecule totally encased in an icosidodecahedral Cu30 in a (µ30 -(η2 )30 )-fashion, namely C60 @Cu30 @Cl36 N12 , has been successfully realized by a C60 -templated assembly. The 48 outmost coordinating atoms (36Cl+12N) comprise a new simple polyhedron that is described by a ccf topology. Charge transfer from (CuI , Cl) to C60 explains the expansion of the light absorption up to 700 nm, and accounts for an ultrafast photophysical process that underpins its high photothermal conversion efficiency. This work makes a giant step forward in exohedral metallofullerene (ExMF) chemistry.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article
Texto completo
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XML
PubMed Links
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article