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Organic photoredox catalyzed C(sp3)-H functionalization of saturated aza-heterocycles via a cross-dehydrogenative coupling reaction.
Zhang, Yi-Fan; Chen, Han-Nan; Xiao, Yi; Cui, Zhencun; Wang, Wei David; Xu, Guo-Qiang.
Afiliação
  • Zhang YF; State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, MOE Frontiers Science Center for Rare Isotopes, Lanzhou Magnetic Resonance Center, Lanzhou University, Lanzhou 730000, P.R. China. ww@lzu.edu.cn.
  • Chen HN; State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, MOE Frontiers Science Center for Rare Isotopes, Lanzhou Magnetic Resonance Center, Lanzhou University, Lanzhou 730000, P.R. China. ww@lzu.edu.cn.
  • Xiao Y; State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, MOE Frontiers Science Center for Rare Isotopes, Lanzhou Magnetic Resonance Center, Lanzhou University, Lanzhou 730000, P.R. China. ww@lzu.edu.cn.
  • Cui Z; Department of Nuclear Medicine, MOE Frontiers Science Center for Rare Isotopes, Second Hospital of Lanzhou University, Lanzhou University, Lanzhou 730030, P.R. China.
  • Wang WD; State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, MOE Frontiers Science Center for Rare Isotopes, Lanzhou Magnetic Resonance Center, Lanzhou University, Lanzhou 730000, P.R. China. ww@lzu.edu.cn.
  • Xu GQ; State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, MOE Frontiers Science Center for Rare Isotopes, Lanzhou Magnetic Resonance Center, Lanzhou University, Lanzhou 730000, P.R. China. ww@lzu.edu.cn.
Org Biomol Chem ; 21(41): 8284-8288, 2023 Oct 25.
Article em En | MEDLINE | ID: mdl-37814526
Herein we present a novel protocol to access α-functionalized saturated aza-heterocycles, and a variety of nucleophilic groups, such as indole, naphthol, phenol, pyrrole, furyl, nitromethyl, and cyano, could be easily installed into saturated aza-heterocycles. Furthermore, a range of biologically valuable 3,3'-diindolylmethane derivatives could also be readily accessed under mild photocatalytic conditions.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article
Texto completo
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PubMed Links
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article