Facile synthesis of a GO-g-C3N4/BaTiO3 ternary nanocomposites for visible-light-driven photocatalytic degradation of rhodamine B.

Photogenerated charge carriers can undergo rapid recombination in conventional photocatalyst systems, reducing their photocatalytic efficiency. To address this bottleneck, a g-C3N4/BaTiO3 (CNB) heterojunction composite was decorated with different mass ratios of graphene oxide (GO) to form a novel visible-light responsive ternary GO-g-C3N4/BaTiO3 (GOCNB) nanocomposite using a facile fabrication method. The GOCNB photocatalyst exhibited significantly higher light absorption and greater charge transfer than CNB, g-C3N4, or BaTiO3. The photodegradation performance of GOCNB was optimized with a 2% mass loading of GO, and it achieved a degradation rate constant of 14.9 × 10-3 min-1 for rhodamine B with an efficiency of 94% within 180 min. The rate constant was 8-fold and 6-fold higher than that of bare BaTiO3 and CNB, respectively. The stronger photocatalytic activity was attributed to the synergistic effect of GO, g-C3N4, and BaTiO3, with g-C3N4 and BaTiO3 promoting charge transfer within a wider visible light range and GO promoting electron mobility and the photocatalyst's adsorption capacity. In particular, the proposed system maintained the spatial separation of photogenerated electron-hole pairs, which is vital for high photocatalytic activity. This study provides new insights into semiconductor-based photocatalytic systems and suggests a route for more environmentally sustainable technologies.