Dehydroabietane-type bifunctional organocatalysts in asymmetric synthesis: recent progress.
RSC Adv
; 13(44): 31047-31058, 2023 Oct 18.
Article
em En
| MEDLINE
| ID: mdl-37881754
ABSTRACT
Dehydroabietane-type bifunctional organocatalysts derived from rosane-type diterpenes of dehydroabietic acid (DHAA) and dehydroabietylamine (DA) have been utilized in a wide variety of highly enantioselective reactions. Since one well-documented review exclusively reported on the development of terpene-derived bifunctional thioureas in asymmetric organocatalysis in 2013, fragmentary progress on the dehydroabietane-type bifunctional thioureas and squaramides has been mentioned in other reviews. In this mini-review, we systematically analyze and reorganize the published literature on dehydroabietane-type bifunctional organocatalysts in the recent decade according to the type of catalysts. Our aim is for this review to provide helpful research information and serve as a foundation for further design and application of rosin-based organocatalysts.
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MEDLINE
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En
Ano de publicação:
2023
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Article