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Synthesis of chroman-annulated cyclopropanols via photoinduced intramolecular [2 + 1]-cycloaddition of 2-allyloxybenzaldehydes.
Zaitseva, Elvira R; Opryshko, Victoria E; Ivanov, Dmitrii S; Mikhaylov, Andrey A; Smirnov, Alexander Yu; Baranov, Mikhail S.
Afiliação
  • Zaitseva ER; Institute of Bioorganic Chemistry Russian Academy of Sciences, Miklukho-Maklaya 16/10, 117997, Moscow, Russia. baranovmikes@gmail.com.
  • Opryshko VE; Institute of Bioorganic Chemistry Russian Academy of Sciences, Miklukho-Maklaya 16/10, 117997, Moscow, Russia. baranovmikes@gmail.com.
  • Ivanov DS; Institute of Bioorganic Chemistry Russian Academy of Sciences, Miklukho-Maklaya 16/10, 117997, Moscow, Russia. baranovmikes@gmail.com.
  • Mikhaylov AA; Institute of Bioorganic Chemistry Russian Academy of Sciences, Miklukho-Maklaya 16/10, 117997, Moscow, Russia. baranovmikes@gmail.com.
  • Smirnov AY; Institute of Bioorganic Chemistry Russian Academy of Sciences, Miklukho-Maklaya 16/10, 117997, Moscow, Russia. baranovmikes@gmail.com.
  • Baranov MS; Pirogov Russian National Research Medical University, Ostrovitianov 1, 117997, Moscow, Russia.
Org Biomol Chem ; 21(45): 9082-9085, 2023 Nov 22.
Article em En | MEDLINE | ID: mdl-37942901
2-Allyloxybenzaldehydes undergo [2 + 1] cycloadditions under 365 nm LED irradiation to form the corresponding chroman-fused cyclopropanols. The reaction proceeds easily without any catalysts or additives in dimethyl sulfoxide.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2023 Tipo de documento: Article