Biomass-derived carbon-sulfur hybrids boosting electrochemical kinetics to achieve high potassium storage performance.

ABSTRACT

Potassium-ion batteries (PIBs) as an emerging battery technology have garnered significant research interest. However, the development of high-performance PIBs critically hinges on reliable anode materials with comprehensive electrochemical performance and low cost. Herein, low-cost N-doped biomass-derived carbon-sulfur hybrids (NBCSHs) were prepared through a simple co-carbonization of the mixture of a biomass precursor (coffee grounds) and sulfur powder. The sulfur in NBCSHs predominantly exists in the form of single-atomic sulfur bonded with carbon atoms (CSC), functioning as main active redox sites to achieve high reversible capacity. Electrochemical evaluations reveal that the NBCSH 1-3 with moderate sulfur content shows significantly improved potassium storage performance, such as a high reversible capacity of 484.7 mAh g-1 and rate performance of 119.4 mAh g-1 at 5 A g-1, 4.5 and 14.7 times higher than that of S-free biomass-derived carbon, respectively. Furthermore, NBCSH 1-3 exhibits stable cyclability (no obvious capacity fading even after 1000 cycles at 0.5 A g-1) and excellent electrochemical kinetics (low overpotentials and apparent diffusion coefficients). The improved performance of NBCSHs is primarily attributed to pseudocapacitance-dominated behavior with fast charge transfer capability. Density functional theory calculations also reveal that co-doping with S, N favors for achieving a stronger potassium adsorbing capability. Assemble K-ion capacitors with NBCS 1-3 as anodes demonstrate stable cyclability and commendable rate performance. Our research envisions the potential of NBCSHs as efficient and sustainable materials for advanced potassium-ion energy storage systems.