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Nature-inspired polymer photocatalysts for green NADH regeneration and nitroarene transformation.
Singh, Ranjeet; Yadav, Rajesh K; Singh, Satyam; Shahin, Rehana; Umar, Ahmad; Ibrahim, Ahmed A; Singh, Omvir; Gupta, Navneet K; Singh, Chandani; Baeg, Jin OoK; Baskoutas, Sotirios.
Afiliação
  • Singh R; Department of Chemistry and Environmental Science, Madan Mohan Malviya University of Technology, Gorakhpur, 273010, U. P., India.
  • Yadav RK; Department of Chemistry and Environmental Science, Madan Mohan Malviya University of Technology, Gorakhpur, 273010, U. P., India. Electronic address: rajeshkr_yadav2003@yahoo.co.in.
  • Satyanath; Department of Chemistry and Environmental Science, Madan Mohan Malviya University of Technology, Gorakhpur, 273010, U. P., India.
  • Singh S; Department of Chemistry and Environmental Science, Madan Mohan Malviya University of Technology, Gorakhpur, 273010, U. P., India.
  • Shahin R; Department of Chemistry and Environmental Science, Madan Mohan Malviya University of Technology, Gorakhpur, 273010, U. P., India.
  • Umar A; Department of Chemistry, Faculty of Science and Arts, and Promising Centre for Sensors and Electronic Devices (PCSED), Najran University, Najran, 11001, Kingdom of Saudi Arabia; Department of Materials Science and Engineering, The Ohio State University, Columbus, 43210, OH, USA. Electronic address:
  • Ibrahim AA; Department of Chemistry, Faculty of Science and Arts, and Promising Centre for Sensors and Electronic Devices (PCSED), Najran University, Najran, 11001, Kingdom of Saudi Arabia.
  • Singh O; Centre for Sustainable Technologies, Indian Institute of Science, Gulmohar Marg, Mathikere, Bengaluru, 560012, India.
  • Gupta NK; Centre for Sustainable Technologies, Indian Institute of Science, Gulmohar Marg, Mathikere, Bengaluru, 560012, India.
  • Singh C; Artificial Photosynthesis Research group, Korea Research Institute of Chemical Technology, Yuseong-gu, Daejeon, 34114, Republic of Korea.
  • Baeg JO; Artificial Photosynthesis Research group, Korea Research Institute of Chemical Technology, Yuseong-gu, Daejeon, 34114, Republic of Korea. Electronic address: jobaeg@krict.re.kr.
  • Baskoutas S; Department of Materials Science, University of Patras, Greece.
Chemosphere ; 353: 141491, 2024 Apr.
Article em En | MEDLINE | ID: mdl-38395365
ABSTRACT
Photocatalysis has emerged as a promising approach for generating solar chemical and organic transformations under the solar light spectrum, employing polymer photocatalysts. In this study, our aim is to achieve the regeneration of NADH and fixation of nitroarene compounds, which hold significant importance in various fields such as pharmaceuticals, biology, and chemistry. The development of an in-situ nature-inspired artificial photosynthetic pathway represents a challenging task, as it involves harnessing solar energy for efficient solar chemical production and organic transformation. In this work, we have successfully synthesized a novel artificial photosynthetic polymer, named TFc photocatalyst, through the Friedel-Crafts alkylation reaction between triptycene (T) and a ferrocene motif (Fc). The TFC photocatalyst is a promising material with excellent optical properties, an appropriate band gap, and the ability to facilitate the regeneration of NADH and the fixation of nitroarene compounds through photocatalysis. These characteristics are necessary for several applications, including organic synthesis and environmental remediation. Our research provides a significant step forward in establishing a reliable pathway for the regeneration and fixation of solar chemicals and organic compounds under the solar light spectrum.
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Texto completo: 1 Base de dados: MEDLINE Assunto principal: Energia Solar / NAD Idioma: En Ano de publicação: 2024 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Assunto principal: Energia Solar / NAD Idioma: En Ano de publicação: 2024 Tipo de documento: Article