An integrated framework for source apportionment and spatial distribution of mercury in agricultural soil near a primary ore mining site.

ABSTRACT

Mercury (Hg) is a global environmental concern that affects both humans and ecosystem. The comprehensive understanding of sources and dynamics is crucial for facilitating targeted and effective control strategies. Herein, a robust approach integrating Multivariate Statistics, Geostatistics, and Positive Matrix Factorization (PMF) was employed to quantitatively elucidate the distribution and sources of Hg in agricultural lands. Results indicated elevated Hg concentrations in the land with 74.46% of soils, including 84.85% of topsoil, 69.70% of subsoil, and 67.31% of deepsoil, exceeding risk screening value. Geoaccumulation Index of Hg in soil surpassed level Ⅱ with more than 50% of Hg in the residual fraction regardless of the layer or location. The levels of Hg in surface water for irrigation exhibited a negative correlation with the distance from the mine and a positive correlation with that in sediment (R2>0.78, p < 0.01), suggesting the downstream migration and remobilization from sediment. Source apportion revealed that human activities as primary contributors despite high variability across locations and soil layers. Contributions to downstream soil Hg from Natural Background (NB), Primary Ore Mining (OM), Agricultural Practices (AP), and Wastewater Irrigation (WI) were 15.5%, 83.1%, 1.3%, and 0.1%, respectively. A reliable approach for source apportionment of Hg in soil was suggested, demonstrating potential applicability in the risk management of Hg-contaminated sites.