Your browser doesn't support javascript.
loading
[GeRu6(CO)18HI]: A Germanium-Centered Ruthenium Carbonyl Cluster with Aromatic Ring Current.
Wolf, Silke; Köppe, Ralf; Treptow, Jens; Feuerstein, Wolfram; Wenzel, Jonas; Breher, Frank; Roesky, Peter W; Weigend, Florian; Klopper, Wim; Feldmann, Claus.
Afiliação
  • Wolf S; Institute for Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstraße 15, D-76131, Karlsruhe, Germany.
  • Köppe R; Institute for Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstraße 15, D-76131, Karlsruhe, Germany.
  • Treptow J; Institute for Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstraße 15, D-76131, Karlsruhe, Germany.
  • Feuerstein W; Institute for Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstraße 15, D-76131, Karlsruhe, Germany.
  • Wenzel J; Institute for Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstraße 15, D-76131, Karlsruhe, Germany.
  • Breher F; Institute for Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstraße 15, D-76131, Karlsruhe, Germany.
  • Roesky PW; Institute for Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstraße 15, D-76131, Karlsruhe, Germany.
  • Weigend F; Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße 4, D-35043, Marburg, Germany.
  • Klopper W; Institute of Physical Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 2, D-76131, Karlsruhe, Germany.
  • Feldmann C; Institute for Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstraße 15, D-76131, Karlsruhe, Germany.
Adv Sci (Weinh) ; 11(21): e2309043, 2024 Jun.
Article em En | MEDLINE | ID: mdl-38509846
ABSTRACT
The carbonyl cluster compound [GeRu6(CO)18HI] is unique in regard to its structure and bonding with a GeRu6 cluster core, a planar GeRu4HI unit, extensive multi-center bonding, and an aromatic ring current similar to benzene (9-10 nA T-1). The open-shell cluster core is a Ge-centered five-membered Ru4(Ru2) ring with CO ligands and an additional H and I atom, each bridging two Ru atoms on opposite sides of the cluster core. The compound is prepared at 130 °C in a weakly-coordinating ionic liquid.
Palavras-chave
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article