A sequencing electroreduction-electrooxidation system driven by atomic hydrogen for enhancing 2,4-dichloronitrobenzene removal from wastewater.
Environ Res
; 252(Pt 3): 118986, 2024 Jul 01.
Article
em En
| MEDLINE
| ID: mdl-38663671
ABSTRACT
The sequencing electroreduction-electrooxidation process has emerged as a promising approach for the degradation of the chloronitrobenzenes (CNBs) due to its elimination of electro-withdrawing groups in the reduction process, facilitating further removal in the subsequent oxidation process. Herein, we developed a cathode consisting of atom Pd on a Ti plate, which enabled the electro-generation of atomic hydrogen (H*) and the efficient electrocatalytic activation of H2O2 to hydroxyl radical (â¢OH). Cyclic voltammetry (CV) curves and electron spin resonance (ESR) spectra verified the existence of H* and â¢OH. The electroreduction-electrooxidation system achieved 94.7% of 20 mg L-1 2,4-DCNB removal with a relatively low H2O2 addition (5 mM). Moreover, the inhibition rate of Photobacterium phosphoreum in the effluent decreased from 95% to 52% after the sequencing electroreduction-electrooxidation processes. It was further revealed that the H* dominated the electroreduction process and triggered the electrooxidation process. Our work sheds light on the effective removal of electron-withdrawing groups substituted aromatic contaminants from water and wastewater.
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Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Oxirredução
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Poluentes Químicos da Água
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Águas Residuárias
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Hidrogênio
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Nitrobenzenos
Idioma:
En
Ano de publicação:
2024
Tipo de documento:
Article