Photoinduced Catalyst-Free Deuterodefunctionalization of Aryltriazenes with CDCl3.
Org Lett
; 26(20): 4329-4334, 2024 May 24.
Article
em En
| MEDLINE
| ID: mdl-38743509
ABSTRACT
A photoinduced deuterodetriazenation of aryltriazenes with CDCl3 under catalyst-free conditions is reported. The reactions featured simple operation, ecofriendly conditions, readily available reagents, inexpensive D sources, precise site selectivity, and a wide range of substrates. Since aryltriazenes could be readily synthesized from arylamine, this protocol can be used as a general method for easily and accurately incorporating deuterium into aromatic systems by using CDCl3 as a D source.
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MEDLINE
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En
Ano de publicação:
2024
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Article