Fluorescence 'Turn-on' Probe for Chromium Reduction, Adsorption and Detection Based on Cellulosic Nitrogen-Doped Carbon Quantum Dots Hydrogels.

ABSTRACT

This paper proposes a new, highly effective fluorescence test for Cr(VI) detection. This method utilizes a hydrogel composed of hydroxyethyl cellulose (HEC), nitrogen-doped carbon quantum dots (N-CQDs), and poly(co-acrylamido-2-methyl-1-propane sulfonic acid) (AMPS). The N-CQDs were successfully synthesized using a simple microwave method, and then conjugated with HEC and AMPS. The higher adsorption (99.41%) and higher reduction rate in H1 likely stems from both the presence of N-CQDs (absent in HB) and their increased free functional groups (compared to H2/H3, where N-CQDs block them). This facilitates the release (desorption) of Cr(VI) from the hydrogels, making it more available for reduction to the less toxic Cr(III). The fluorescent brightness of the HEC-N-CQDs-g-poly(AMPS) hydrogel increases gradually when Cr(VI) is added in amounts ranging from 15 to 120 mg/L. The fluorescent enhancement of the HEC-N-CQDs-g-poly(AMPS) hydrogel appeared to exhibit a good linear relationship with the 15-120 mg of the Cr(VI) concentration, with a detection limit of 0.0053 mg/L, which is lower than the standard value published by WHO. Our study found that the HEC-N-CQDs-g-poly(AMPS) hydrogel served effectively as a fluorescent probe for Cr(VI) detection in aqueous solutions, demonstrating high sensitivity.