Box-Behnken Design for Mitigation of Cadmium Bivalent Ions from Aqueous Medium.

ABSTRACT

Statistical analysis is essential for minimizing the time, cost, and number of experiments needed to get the maximum output. In this work, the removal of cadmium bivalent (Cd (II)) ions was optimized using Box-Behnken design methodology. The effects of pH, concentration, time, and temperature were investigated for the removal of cadmium. Maximum removal (85.70%) was achieved at pH of 5.34, initial Cd(II) ions concentration 46.61,contact time 166.09 (min), and at 59.40 oC temperature on Punica Granatum carpellary membrane powder (PGCMP) and 88.61% removal was achieved on its modified forms (MPGCMP) at pH of 5.79, initial Cd(II) ions concentration 65.70,contact time 178.96, and at 59.91 oC temperature. The model was validated by analyzing variance (ANOVA). The practical data was well fitted to the quadratic model. PGCMP and MPGCMP were found to be naturally occurring, environmentally friendly adsorbents for the mitigation of Cd (II) ions as well as other toxic heavy metals from drinkable or wastewater.