Gold-Catalyzed Alkoxy-Carbonylation of Aryl and Vinyl Iodides.
Angew Chem Int Ed Engl
; 63(43): e202410794, 2024 Oct 21.
Article
em En
| MEDLINE
| ID: mdl-39039857
ABSTRACT
Herein, for the first time, we disclose the gold-catalyzed alkoxy-carbonylation of aryl and vinyl iodides utilizing ligand-enabled Au(I)/Au(III) redox catalysis. The present methodology is found to be general, efficient, employs mild reaction conditions and showcases a broad substrate scope even with structurally complex molecules. Density functional theory (DFT) calculations revealed mechanistic pathways distinct from those of conventional transition metal-catalyzed carbonylation reactions.
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MEDLINE
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En
Ano de publicação:
2024
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Article