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Synthesis of phenanthrylboroles and formal nitrene insertion to access azaborapyrenes.
Zacharias, Harie; Begum, Ayesha; Han, Jianhua; Bartholome, Tyler A; Marder, Todd B; Martin, Caleb D.
Afiliação
  • Zacharias H; Department of Chemistry and Biochemistry, Baylor University, One Bear Place #97348, Waco, Texas 76798, USA. caleb_d_martin@baylor.edu.
  • Begum A; Department of Chemistry and Biochemistry, Baylor University, One Bear Place #97348, Waco, Texas 76798, USA. caleb_d_martin@baylor.edu.
  • Han J; Institut für Anorganische Chemie, and Institute for Sustainable Chemistry & Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany.
  • Bartholome TA; Department of Chemistry and Biochemistry, Baylor University, One Bear Place #97348, Waco, Texas 76798, USA. caleb_d_martin@baylor.edu.
  • Marder TB; Institut für Anorganische Chemie, and Institute for Sustainable Chemistry & Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany.
  • Martin CD; Department of Chemistry and Biochemistry, Baylor University, One Bear Place #97348, Waco, Texas 76798, USA. caleb_d_martin@baylor.edu.
Chem Commun (Camb) ; 60(66): 8740-8743, 2024 Aug 13.
Article em En | MEDLINE | ID: mdl-39072482
ABSTRACT
Extended conjugation has been introduced into boroles but only on the 2,3- or 4,5-positions of the central BC4 core. In this work we synthesize phenanthrylboroles that also have conjugation on the 3,4-positions and demonstrate their insertion reactivity with azides to furnish B,N-analogues of pyrene.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2024 Tipo de documento: Article