Synthesis of phenanthrylboroles and formal nitrene insertion to access azaborapyrenes.
Chem Commun (Camb)
; 60(66): 8740-8743, 2024 Aug 13.
Article
em En
| MEDLINE
| ID: mdl-39072482
ABSTRACT
Extended conjugation has been introduced into boroles but only on the 2,3- or 4,5-positions of the central BC4 core. In this work we synthesize phenanthrylboroles that also have conjugation on the 3,4-positions and demonstrate their insertion reactivity with azides to furnish B,N-analogues of pyrene.
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MEDLINE
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En
Ano de publicação:
2024
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Article