Kirkendall Effect-Induced Ternary Heterointerfaces Engineering for High Polarization Loss MOF-LDH-MXene Absorbers.

ABSTRACT

Heterogeneous interfacial engineering has garnered widespread attention for optimizing polarization loss and enhancing the performance of electromagnetic wave absorption. A novel Kirkendall effect-assisted electrostatic self-assembly method is employed to construct a metal-organic framework (MOF, MIL-88A) decorated with Ni-Fe layered double hydroxide (LDH), forming a multilayer nano-cage coated with Ti3C2Tx. By modulating the surface adsorption of Ti3C2Tx on LDH, the heterointerfaces in MOF-LDH-MXene ternary composites exhibit excellent interfacial polarization loss. Additionally, the Ni-Fe LDH@Ti3C2Tx nano-cage exhibits a large specific surface area, abundant defects, and a large number of heterojunction structures, resulting in excellent electromagnetic wave absorption performance. The MIL-88A@Ni-Fe LDH@Ti3C2Tx-1.0 nano-cage achieves a reflection loss value of -46.7 dB at a thickness of 1.4 mm and an effective absorption bandwidth of 5.12 GHz at a thickness of 1.8 mm. The heterojunction interface composed of Ni-Fe LDH and Ti3C2Tx helps to enhance polarization loss. Additionally, Ti3C2Tx forms a conductive network on the surface, while the cavity between the MIL-88A core and the Ni-Fe LDH shell facilitates multiple attenuations by increasing the transmission path of internal incident waves. This work may reveal a new structural design of multi-component composites by heterointerfaces engineering for electromagnetic wave absorption.