Ultra-Narrow Alkane Product Distribution in Polyethylene Waste Hydrocracking by Zeolite Micro-Mesopore Diffusion Optimization.

ABSTRACT

Plastic pollution poses a pressing environmental challenge in modern society. Chemical catalytic conversion has emerged as a promising solution for upgrading waste plastics into valuable liquid alkanes and other high value products. However, the current methods yield mixed products with a wide carbon distribution. To address this challenge, we present a bifunctional catalytic system consisting of ß zeolite mixed hierarchical Pt@Hie-TS-1, designed for the conversion of low-density polyethylene (LDPE) into liquid alkanes. This system achieves a 94.0 % yield of liquid alkane, with 84.8 % of C5-C7 light alkanes. Combined with in situ FTIR and molecular dynamics simulation, the shape-selective mechanisms is elucidated, which ensures that only olefins of the appropriate size can diffuse to the encapsulated Pt sites within the zeolite for hydrogenation, resulting in an ultra-narrow product distribution. Furthermore, by optimizing the micro-mesopores of Pt@Hie-TS-1, the scaling relationship between the pore structure and the conversion/selectivity is identified. The rapid diffusion of olefins within these micro-mesopores significantly enhances the catalytic efficiency. Our findings contribute to the design of efficient catalysts for plastic waste valorization.