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Palladium-catalyzed synthesis of monofluoroalkenes from 3,3-difluoropropenes using dimethylmalonate and derivatives as nucleophiles.

Drouin, Myriam; Tremblay, Sébastien; Paquin, Jean-François.
Org Biomol Chem ; 15(11): 2376-2384, 2017 Mar 21.
Artículo en Inglés | MEDLINE | ID: mdl-28244537
The synthesis of monofluoroalkenes bearing a malonate or its derivatives at the ß position is presented. The reaction can be performed with various 3,3-difluoropropenes. A preliminary result for an enantioselective variant is also reported. Further synthetic transformations of a monofluoroalkene were also accomplished.