Spectral differences in resting-state EEG associated to individual Emotional Styles.

The ability to manage the emotions has been associated to the Emotional Styles (ES), a set of coherent ways to deal with life's experiences. Recently, the Emotional Style Questionnaire (ESQ) has been proposed as a self-report mea-sure to assess the individual ES. The present study investigates the spectral differences in the resting-state EEG due to the individual ES, in order to support the psychometric reliability of the ESQ with associated neurophysiological measurements. In the alpha and beta band, Social Intuition showed significant and large (d > 0.8) effect sizes on the parietal and parieto-occipital regions, as well as a significant and large effect size in the gamma band on the pre-frontal region. In the beta band, Attention showed a significant and large effect size on the parieto-occipital region.

Yellow (Lens) Better: Bioelectrical and Biometrical Measures to Assess Arousing and Focusing Effects.

Colours can induce several psychological effects, conditioning perceptions, cognitive/emotional states and human performances. In this exploratory study we investigated the effect of a yellow light exposure, obtained filtering the ambient light with coloured glasses, on the human's psychological functioning. In particular we wanted to assess if people are more able to focus when exposed to a yellow light. We recorded EEG, SC, HR and gaze-related data from 16 subjects (50% split in experimental and control group) during the execution of a reactivity test (the Hazard Perception Test, HPT). Compared with the control group, the experimental group showed increases in concentration, focus, visual attention and arousal, as measured by increases of first fixation duration and Beta over-Alpha ratio (BAR) as well as by decreases of distraction, workload, and number of gaze revisits.

Emotion assessment using Machine Learning and low-cost wearable devices.

The advancement in bioelectrical measurement technologies and the push towards a higher impact of the Brain Computer Interfaces and Affective Computing in the daily life have made non-invasive and low-priced devices available to the large population to record physiological states. The aim of this study is the assessment of the abilities of the MUSE headband, together with the Shimmer GSR+ device, to assess the emotional state of people during stimuli exposure. Twenty-four pictures from the IAPS database were showed to 54 subjects and were evaluated in their emotional values by means of the Self-Assessment Manikin (SAM). Using a Machine Learning approach, fifty-two scalar features were extracted from the signals and used to train 6 binary classifiers to predict the valence and arousal elicited by each stimulus. In all classifiers we obtained accuracies ranging from 53.6% to 69.9%, confirming that these devices are able to give information about the emotional state.

Neurocoaching: exploring the relationship between coach and coachee by means of bioelectrical signal similarities.

Coaching aims to unlock the human's potential, self-awareness and responsibility, improving the professional performances and the personal satisfaction. Its effectiveness is known to depend on the degree of bonding and mutual engagement of the coaching relationship. In this exploratory study we recorded synchronised EEG and SC data from both coach and coachee during 36 individual sessions, performed following 2 different coaching methods. Our principal aim was to investigate the temporal evolution of the bonding and the mutual engagement along the different steps of a session, by means of a "similarity" metric based on the DTW distance between signals (namely, S-TVM). We found significant differences between session phases for the EEG-related S-TVMs (BAR, BATR and AWI), with maximum values (defined as "tuning") all in the same phase, but differentiated between the two experiments. The results suggest a temporal concurrency of the engagement and emotional tunings, whose specific location seems to be a function of the coaching approach.

Looking through blue glasses: bioelectrical measures to assess the awakening after a calm situation.

Colors can elicit cognitive and emotional states. In particular, blue colour is associated to "refresh" and "restart" effects and is suggested to enhance a wake-up after a calm situation. In this exploratory study, these claims are investigated using Electroencephalographic (EEG), Skin Conductance (SC) and pupil diameter data. The results confirmed the "wake-up effect" for subjects wearing the lenses, as measured by Global Field Power (GFP) in Theta Band, Skin Conductance Response (SCR) and pupil diameter data.

Vibrational structure of titanium silicate catalysts. A spectroscopic and theoretical study.

A thorough analysis of the vibrational features of the titanium silicalite-1 (TS-1) catalyst is presented, based on quantitative IR measurements, Raman and resonant Raman experiments, quantitative XANES, and quantum chemical calculations on cluster and periodic models. The linear correlation of the intensity of the IR and Raman bands located at 960 and 1125 cm(-1) and the XANES peak at 4967 eV with the amount of tetrahedral Ti are quantitatively demonstrated. Raman and resonant Raman spectra of silicalite and TS-1 with variable Ti content are presented, showing main features at 960 and 1125 cm(-1) associated with titanium insertion into the zeolite framework. The enhancement of the intensity of the 1125 cm(-1) feature and the invariance of the 960 cm(-1) feature in UV-Raman experiments, are discussed in terms of resonant Raman selection rules. Quantum chemical calculations on cluster models Si[OSi(OH)(3)](4) and Ti[OSi(OH)(3)](4) at the B3LYP/6-31G(d) level of theory provide the basis for the assignment of the main vibrational contributions and for the understanding of Raman enhancement. The resonance-enhanced 1125 cm(-1) mode is unambiguously associated with a totally symmetric vibration of the TiO(4) tetrahedron, achieved through in-phase antisymmetric stretching of the four connected Ti-O-Si bridges. This vibration can also be described as a totally symmetric stretching of the four Si-O bonds pointing toward Ti. The resonance enhancement of this feature is explained in terms of the electronic structure of the Ti-containing moiety. Asymmetric stretching modes of TO(4) units show distinct behavior when (i) T is occupied by Si as in perfect silicalite, (ii) T is occupied by Ti as in TS-1, or (iii) the oxygen atom belongs to an OH group, such as in terminal tetrahedra of cluster models and in real defective zeolites. Asymmetric SiO(4) and TiO(4) stretching modes appear above and below 1000 cm(-1), respectively, when they are achieved through antisymmetric stretching of the T-O-Si bridges, and around 800 cm(-1) (in both SiO(4) and TiO(4)) when they involve symmetric stretching of the T-O-Si units. In purely siliceous models, the transparency gap between the main peaks at 800 and 1100 cm(-1) contains only vibrational features associated with terminal Si-OH groups, while in Ti-containing models it contains also the above-mentioned asymmetric TiO(4) modes, which in turn are strongly coupled with Si-OH stretching modes. Calculations on periodic models of silicalite and TS-1 free of OH groups using the QMPOT embedding method correctly reproduce the transparency gap of silicalite and the appearance of asymmetric TiO(4) vibrations at 960 cm(-1) in TS-1. Finally, we demonstrate, for the first time, that the distortion of the tetrahedral symmetry around Ti caused by water adsorption quenches the UV-Raman enhancement of the 1125 cm(-1) band.