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Org Biomol Chem
; 16(32): 5748-5751, 2018 08 15.
Article
in English
| MEDLINE
| ID: mdl-30039830
ABSTRACT
An efficient and highly E-selective protocol for the synthesis of vinyl sulfones is described. This simple protocol demonstrates the first synthesis of vinyl sulfones via a silver-catalyzed C-S bond coupling reaction. In addition, the success of the reaction was found to be critically dependent on the use of TEMPO as the additive.