Your browser doesn't support javascript.
loading
Show: 20 | 50 | 100
Results 1 - 20 de 66
Filter
1.
J Phys Chem A ; 128(18): 3635-3645, 2024 May 09.
Article in English | MEDLINE | ID: mdl-38662914

ABSTRACT

High-field magic angle spinning (MAS) dynamic nuclear polarization (DNP) is becoming a common technique for improving the sensitivity of solid-state nuclear magnetic resonance (SSNMR) by the hyperpolarization of nuclear spins. Recently, we have shown that gamma irradiation is capable of creating long-lived free radicals that are amenable to MAS DNP in quartz and a variety of organic solids. Here, we demonstrate that ball milling is able to generate millimolar concentrations of stable radical species in diverse materials such as polystyrene, cellulose, borosilicate glass, and fused quartz. High-field electron paramagnetic resonance (EPR) was used to obtain further insight into the nature of the radicals formed in ball milled quartz and borosilicate glass. We further show that radicals generated in quartz by ball milling can be used for solid-effect DNP. We obtained 29Si DNP enhancements of approximately 114 and 33 at 110 K and room temperature, respectively, from a sample of ball milled quartz.

2.
Phys Chem Chem Phys ; 24(41): 25088-25098, 2022 Oct 27.
Article in English | MEDLINE | ID: mdl-35789354

ABSTRACT

Molten chloride salts are currently under consideration as combined coolant and liquid fuel for next-generation molten salt nuclear reactors. Unlike complementary light-water reactor technologies, the radiation science underpinning molten salts is in its infancy, and thus requires a fundamental mechanistic investigation to elucidate the radiation-driven chemistry within molten salt reactors. Here we present an electron pulse radiolysis kinetics study into the behaviour of the primary radiolytic species generated in molten chloride systems, i.e., the solvated electron (eS-) and di-chlorine radical anion (Cl2˙-). We examine the reaction of eS- with Zn2+ from 400-600 °C (Ea = 30.31 ± 0.09 kJ mol-1), and the kinetics and decay mechanisms of Cl2˙- in molten lithium chloride-potassium chloride (LiCl-KCl) eutectic. In the absence of Zn2+, the lifetime of eS- was found to be dictated by residual impurities in ostensibly "pure" salts, and thus the observed decay is dependent on sample history rather than being an intrinsic property of the salt. The decay of Cl2˙- is complex, owing to the competition of Cl2˙- disproportionation with several other chemical pathways, one of which involves reduction by radiolytically-produced Zn+ species. Overall, the reported findings demonstrate the richness and complexity of chemistry involving the interactions of ionizing radiation with molten salts.

3.
Solid State Nucl Magn Reson ; 119: 101785, 2022 06.
Article in English | MEDLINE | ID: mdl-35405629

ABSTRACT

In the past 15 years, magic angle spinning (MAS) dynamic nuclear polarization (DNP) has emerged as a method to increase the sensitivity of high-resolution solid-state NMR spectroscopy experiments. Recently, γ-irradiation has been used to generate significant concentrations of homogeneously distributed free radicals in a variety of solids, including quartz, glucose, and cellulose. Both γ-irradiated quartz and glucose previously showed significant MAS DNP enhancements. Here, γ-irradiation is applied to twelve small organic molecules to test the applicability of γ-irradiation as a general method of creating stable free radicals for MAS DNP experiments on organic solids and pharmaceuticals. Radical concentrations in the range of 0.25 â€‹mM-10 â€‹mM were observed in irradiated glucose, histidine, malic acid, and malonic acid, and significant 1H DNP enhancements of 32, 130, 19, and 11 were obtained, respectively, as measured by 1H→13C CPMAS experiments. However, concentrations of free radicals below 0.05 â€‹mM were generally observed in organic molecules containing aromatic rings, preventing sizeable DNP enhancements. DNP sensitivity gains for several of the irradiated compounds exceed that which can be obtained with the relayed DNP approach that uses exogeneous polarizing agent solutions and impregnation procedures. In several cases, significant 1H DNP enhancements were realized at room temperature. This study demonstrates that in many cases γ-irradiation is a viable alternative to addition of stable exogenous radicals for DNP experiments on organic solids.


Subject(s)
Histidine , Quartz , Free Radicals , Glucose , Histidine/chemistry , Magnetic Resonance Spectroscopy/methods
4.
J Am Chem Soc ; 143(37): 15298-15308, 2021 09 22.
Article in English | MEDLINE | ID: mdl-34499512

ABSTRACT

To examine ion solvation, exchange, and speciation for minority components in molten salts (MS) typically found as corrosion products, we propose a multimodal approach combining extended X-ray absorption fine structure (EXAFS) spectroscopy, optical spectroscopy, ab initio molecular dynamics (AIMD) simulations, and rate theory of ion exchange. Going beyond conventional EXAFS analysis, our method can accurately quantify populations of different coordination states of ions with highly disordered coordination environments via linear combination fitting of the EXAFS spectra of these coordination states computed from AIMD to the experimental EXAFS spectrum. In a case study of dilute Ni(II) dissolved in the ZnCl2+KCl melts, our method reveals heterogeneous distributions of coordination states of Ni(II) that are sensitive to variations in temperature and melt composition. These results are fully explained by the difference in the chloride exchange dynamics at varied temperatures and melt compositions. This insight will enable a better understanding and control of ion solubility and transport in MS.

5.
Phys Chem Chem Phys ; 23(17): 10384-10394, 2021 May 05.
Article in English | MEDLINE | ID: mdl-33889900

ABSTRACT

Room temperature post-irradiation measurements of diffuse reflectance and electron paramagnetic resonance spectroscopies were made to characterize the long-lived radiation-induced species formed from the gamma irradiation of solid KCl, MgCl2, and ZnCl2 salts up to 100 kGy. The method used showed results consistent with those reported for electron and gamma irradiation of KCl in single crystals. Thermal bleaching of irradiated KCl demonstrated accelerated disaggregation of defect clusters above 400 K, due to decomposition of Cl3-. The defects formed in irradiated MgCl2 comprised a mixture of Cl3-, F-centers, and Mg+ associated as M-centers. Further, Mg metal cluster formation was also observed at 100 kGy, in addition to accelerated destruction of F-centers above 20 kGy. Irradiated ZnCl2 afforded the formation of Cl2- due to its high ionization potential and crystalline structure, which decreases recombination. The presence of aggregates in all cases indicates the high diffusion of radicals and the predominance of secondary processes at 295 K. Thermal bleaching studies showed that chloride aggregates' stability increases with the ionization potential of the cation present. The characterization of long-lived radiolytic transients of pure salts provides important information for the understanding of complex salt mixtures under the action of gamma radiation.

6.
J Synchrotron Radiat ; 27(Pt 3): 746-752, 2020 May 01.
Article in English | MEDLINE | ID: mdl-32381777

ABSTRACT

A versatile, compact heater designed at National Synchrotron Light Source-II for in situ X-ray nano-imaging in a full-field transmission X-ray microscope is presented. Heater design for nano-imaging is challenging, combining tight spatial constraints with stringent design requirements for the temperature range and stability. Finite-element modeling and analytical calculations were used to determine the heater design parameters. Performance tests demonstrated reliable and stable performance, including maintaining the exterior casing close to room temperature while the heater is operating at above 1100°C, a homogenous heating zone and small temperature fluctuations. Two scientific experiments are presented to demonstrate the heater capabilities: (i) in situ 3D nano-tomography including a study of metal dealloying in a liquid molten salt extreme environment, and (ii) a study of pore formation in icosahedral quasicrystals. The progression of structural changes in both studies were clearly resolved in 3D, showing that the new heater enables powerful capabilities to directly visualize and quantify 3D morphological evolution of materials under real conditions by X-ray nano-imaging at elevated temperature during synthesis, fabrication and operation processes. This heater design concept can be applied to other applications where a precise, compact heater design is required.

7.
Angew Chem Int Ed Engl ; 59(51): 23180-23187, 2020 Dec 14.
Article in English | MEDLINE | ID: mdl-32881197

ABSTRACT

Super-concentrated "water-in-salt" electrolytes recently spurred resurgent interest for high energy density aqueous lithium-ion batteries. Thermodynamic stabilization at high concentrations and kinetic barriers towards interfacial water electrolysis significantly expand the electrochemical stability window, facilitating high voltage aqueous cells. Herein we investigated LiTFSI/H2 O electrolyte interfacial decomposition pathways in the "water-in-salt" and "salt-in-water" regimes using synchrotron X-rays, which produce electrons at the solid/electrolyte interface to mimic reductive environments, and simultaneously probe the structure of surface films using X-ray diffraction. We observed the surface-reduction of TFSI- at super-concentration, leading to lithium fluoride interphase formation, while precipitation of the lithium hydroxide was not observed. The mechanism behind this photoelectron-induced reduction was revealed to be concentration-dependent interfacial chemistry that only occurs among closely contact ion-pairs, which constitutes the rationale behind the "water-in-salt" concept.

8.
J Phys Chem A ; 123(39): 8370-8376, 2019 Oct 03.
Article in English | MEDLINE | ID: mdl-31418567

ABSTRACT

Functionalization of the imidazolium (Im+) cationic component of ionic liquids (ILs) with ether chains affords the possibility of tuning their properties through manipulation of the resulting interion and intramolecular interactions. Herein, we quantify these interactions at the molecular level through analysis of the vibrational spectra displayed by size-selected and cryogenically cooled ions. These spectra are obtained using the "tagging" approach carried out with photofragmentation tandem mass spectrometry. In the isolated cations, we find that the oxygen atom on the ether chain binds exclusively to the acidic C(2)H position on the Im+ ring. Upon complexation with BF4- to form the ternary (ether-MIm+)2(BF4-) cation, however, the less acidic C(4,5)H groups also participate as contact points for the ionic assembly, in contrast to the behavior of the closely related (EMIm+)2(BF4-) system. These experimental results support the conclusions derived from earlier X-ray scattering and molecular dynamics results on bulk ILs regarding interactions with the ring CH groups and their implications on tuning the viscosities of this class of functionalized ILs.

9.
J Chem Phys ; 151(7): 074504, 2019 Aug 21.
Article in English | MEDLINE | ID: mdl-31438705

ABSTRACT

Ionic liquids (ILs) with relatively low viscosities and broad windows of electrochemical stability are often constructed by pairing asymmetric cations with bisfluorosulfonylimide (FSI-) or bistriflimide (NTf2 -) anions. In this work, we systematically studied the structures of ILs with these anions and related perfluorobis-sulfonylimide anions with asymmetry and/or longer chains: (fluorosulfonyl)(trifluoromethylsulfonyl)imide (BSI0,1 -), bis(pentafluoroethylsulfonyl)imide (BETI-), and (trifluoromethylsulfonyl) (nonafluorobutylsulfonyl)imide (BSI1,4 -) using high energy X-ray scattering and molecular dynamics simulation methods. 1-alkyl-3-methylimidazolium cations with shorter (ethyl, Im2,1 +) and longer (octyl, Im1,8 +) hydrocarbon chains were selected to examine how the sizes of nonpolar hydrocarbon and fluorous chains affect IL structures and properties. In comparison with these, we also computationally explored the structure of ionic liquids with anions having longer fluorinated tails.

10.
J Phys Chem A ; 122(12): 3148-3155, 2018 Mar 29.
Article in English | MEDLINE | ID: mdl-29510054

ABSTRACT

A pulse radiolysis study on pyrrolidinium cation based ionic liquids is presented herein. Time-resolved absorption spectra for 1-methyl-1-propylpyrrolidinium dicyanamide (DCA) at 500 ns after the electron pulse show broad absorption bands at wavelengths below 440 nm and at 640 nm. In pyrrolidinium bis(trifluoromethylsulfonyl)imide (NTf2) and tris(perfluoroethyl)trifluorophosphate (FAP) ILs, the transient absorption below 440 nm is much weaker. The absorption at 500 ns, which increases with wavelength from 500 nm to beyond 800 nm, was assigned to the tail of the solvated electron NIR absorption spectrum, since it disappears in the presence of N2O. In the DCA IL, the presence of a reducing species was confirmed by the formation of pyrene radical anion. The difference in the transient species in the case of the DCA IL compared to other two ILs should be due to the anion, with cations being similar. In pseudohalide ILs such as DCA, radicals are formed by direct hole trapping by the anion (X- + h+ → X•), followed by addition to the parent anion. Prediction of the UV/vis absorption spectra of the dimer radical anion by computational calculation supports the experimental results. The oxidizing efficiency of (DCA)2•- and its reduction potential ( E(DCA)2•-/(2DCA-)) have been determined.

11.
J Chem Phys ; 148(19): 193805, 2018 May 21.
Article in English | MEDLINE | ID: mdl-30307243

ABSTRACT

In this study, we investigate the temperature dependence of low-frequency spectra in the frequency range of 0.3-200 cm-1 for ionic liquids (ILs) whose cations possess two systematically different cyclic groups, using femtosecond Raman-induced Kerr effect spectroscopy. The target ILs are bis(trifluoromethylsulfonyl)amide [NTf2]- salts of 1-cyclohexylmethyl-1-methylpyrrolidinium [CHxmMPyrr]+, 1-cyclohexylmethyl-3-methylimidazolium [CHxmMIm]+, N-cyclohexylmethylpyridinium [CHxmPy]+, 1-benzyl-1-methylpyrrolidinium [BzMPyrr]+, 1-benzyl-3-methylimidazolium [BzMIm]+, and N-benzylpyridinium [BzPy]+ cations. The aim of this study is to better understand the effects of aromaticity in the cations' constituent groups on the temperature-dependent low-frequency spectral features of the ILs. The low-frequency spectra of these ILs are temperature dependent, but the temperature-dependent spectrum of [CHxmMPyrr][NTf2] is different from that of other ILs. While [CHxmMPyrr][NTf2] shows spectral changes with temperature in the low-frequency region below 50 cm-1, the other ILs also show spectral changes in the high-frequency region above 80 cm-1 (above 50 cm-1 in the case of [BzMPyrr][NTf2]). We conclude that the spectral change in the low-frequency region is due to both the cation and anion, while the change in the high-frequency region is attributed to the red shift of the aromatic ring librations. On the basis of the plots of the first moment of the spectra vs. temperature, we found that the first moment of the low-frequency spectrum of the IL whose cation does not have an aromatic ring is less temperature dependent than that of the other ILs. However, the intrinsic first moment, the first moment at 0 K, of the low-frequency spectrum is governed by the absence or presence of a charged aromatic group, while a neutral aromatic group does not have much influence on determining the intrinsic first moment.

12.
J Electrochem Soc ; 164(8): H5189-H5196, 2017.
Article in English | MEDLINE | ID: mdl-30034028

ABSTRACT

A comprehensive variable temperature, pressure and frequency multinuclear (1H, 2H, and 19F) magnetic resonance study was undertaken on selectively deuterated 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide (BMIM TFSA) ionic liquid isotopologues. This study builds on our earlier investigation of the effects of increasing alkyl chain length on diffusion and dynamics in imidazolium-based TFSA ionic liquids. Fast field cycling 1H T1 data revealed multiple modes of motion. Through calculation of diffusion coefficient (D) values and activation energies, the low- and high-field regimes were assigned to the translational and reorientation dynamics respectively. Variable-pressure 2H T1 measurements reveal site-dependent interactions in the cation with strengths in the order MD3 > CD3 > CD2, indicating dissimilarities in the electric field gradients along the alkyl chain, with the CD2 sites having the largest gradient. Additionally, the α saturation effect in T1 vs. P was observed for all three sites, suggesting significant reduction of the short-range rapid reorientational dynamics. This reduction was also deduced from the variable pressure 1H T1 data, which showed an approach to saturation for both the methyl and butyl group terminal methyl sites. Pressure-dependent D measurements show independent motions for both cations and anions, with the cations having greater D values over the entire pressure range.

13.
J Am Chem Soc ; 136(15): 5563-6, 2014 Apr 16.
Article in English | MEDLINE | ID: mdl-24679111

ABSTRACT

Using a new technique, which combines pulse radiolysis with nanosecond time-resolved infrared (TRIR) spectroscopy in the condensed phase, we have conducted a detailed kinetic and mechanistic investigation of the formation of a Mn-based CO2 reduction electrocatalyst, [Mn((t)Bu2-bpy)(CO)3]2 ((t)Bu2-bpy = 4,4'-(t)Bu2-2,2'-bipyridine), in acetonitrile. The use of TRIR allowed, for the first time, direct observation of all the intermediates involved in this process. Addition of excess [(n)Bu4N][HCO2] to an acetonitrile solution of fac-MnBr((t)Bu2-bpy)(CO)3 results in its quantitative conversion to the Mn-formate complex, fac-Mn(OCHO)((t)Bu2-bpy)(CO)3, which is a precatalyst for the electrocatalytic reduction of CO2. Formation of the catalyst is initiated by one-electron reduction of the Mn-formate precatalyst, which produces the bpy ligand-based radical. This radical undergoes extremely rapid (τ = 77 ns) formate dissociation accompanied by a free valence shift to yield the five-coordinate Mn-based radical, Mn(•)((t)Bu2-bpy)(CO)3. TRIR data also provide evidence that the Mn-centered radical does not bind acetonitrile prior to its dimerization. This reaction occurs with a characteristically high radical-radical recombination rate (2kdim = (1.3 ± 0.1) × 10(9) M(-1) s(-1)), generating the catalytically active Mn-Mn bound dimer.

14.
Beilstein J Org Chem ; 10: 271-5, 2014.
Article in English | MEDLINE | ID: mdl-24605146

ABSTRACT

Ionic liquids (ILs) incorporating cyclic phosphonium cations are a novel category of materials. We report here on the synthesis and characterization of four new cyclic phosphonium bis(trifluoromethylsulfonyl)amide ILs with aliphatic and aromatic pendant groups. In addition to the syntheses of these novel materials, we report on a comparison of their properties with their ammonium congeners. These exemplars are slightly less conductive and have slightly smaller self-diffusion coefficients than their cyclic ammonium congeners.

15.
J Phys Chem A ; 117(28): 5742-56, 2013 Jul 18.
Article in English | MEDLINE | ID: mdl-23819609

ABSTRACT

One- and two- photon excitation of halide anions (X(-)) in polar molecular solvents results in electron detachment from the dissociative charge-transfer-to-solvent state; this reaction yields a solvated halide atom and a solvated electron. How do such photoreactions proceed in ionic liquid (IL) solvents? Matrix isolation electron paramagnetic resonance (EPR) spectroscopy has been used to answer this question for photoreactions of bromide in aliphatic (1-butyl-1-methylpyrrolidinium) and aromatic (1-alkyl-3-methyl-imidazolium) ionic liquids. In both classes of ILs, the photoreaction (both 1- and 2-photon) yields bromine atoms that promptly abstract hydrogen from the alkyl chains of the IL cation; only in concentrated bromide solutions (containing >5-10 mol % bromide) does Br2(-•) formation compete with this reaction. In two-photon excitation, the 2-imidazolyl radical generated via the charge transfer promptly eliminates the alkyl arm. These photolytic reactions can be contrasted with radiolysis of the same ILs, in which large yield of BrA(-•) radicals was observed (where A(-) is a matrix anion), suggesting that solvated Br(•) atoms do not occur in the ILs, as such a species would form three-electron σ(2)σ(*1) bonds with anions present in the IL. It is suggested that chlorine and bromine atoms abstract hydrogen faster than they form such radicals, even at cryogenic temperatures, whereas iodine mainly forms such bound radicals. These XA(-•) radicals convert to X2(•-) radicals in a reaction with the parent halide anion. Ramifications of these observations for photodegradation of ionic liquids are discussed.

16.
J Phys Chem B ; 127(28): 6342-6353, 2023 Jul 20.
Article in English | MEDLINE | ID: mdl-37432303

ABSTRACT

Ionic liquid viscosity is one of the most important properties to consider for practical applications. Yet, the connection between local structure and viscosity remains an open question. This article explores the structural origin of differences in the viscosity and viscoelastic relaxation across several ionic liquids, including cations with alkyl, ether, and thioether tails, of the imidazolium and pyrrolidinium families coupled with the NTf2- anion. In all cases, for the systems studied here, we find that pyrrolidinium-based ions are "harder" than their imidazolium-based counterparts. We make a connection between the chemical concept of hardness vs softness and specific structural and structural dynamic quantities that can be derived from scattering experiments and simulations.

17.
Annu Rev Phys Chem ; 62: 85-105, 2011.
Article in English | MEDLINE | ID: mdl-21091193

ABSTRACT

Ionic liquids are subjects of intense current interest within the physical chemistry community. A great deal of progress has been made in just the past five years toward identifying the factors that cause these salts to have low melting points and other useful properties. Supramolecular structure and organization have emerged as important and complicated topics that may be key to understanding how chemical reactions and other processes are affected by ionic liquids. New questions are posed, and an active debate is ongoing regarding the nature of nanoscale ordering in ionic liquids. The topic of reactivity in ionic liquids is still relatively unexplored; however, the results that have been obtained indicate that distributed kinetics and dynamical heterogeneity may sometimes, but not always, be influencing factors.

18.
Appl Spectrosc ; 76(9): 1142-1153, 2022 Sep.
Article in English | MEDLINE | ID: mdl-35414202

ABSTRACT

We describe the first implementation of broadband, nanosecond time-resolved step-scan Fourier transform infrared (S2-FT-IR) spectroscopy at a pulse radiolysis facility. This new technique allows the rapid acquisition of nano- to microsecond time-resolved infrared (TRIR) spectra of transient species generated by pulse radiolysis of liquid samples at a pulsed electron accelerator. Wide regions of the mid-infrared can be probed in a single experiment, which often takes < 20-30 min to complete. It is therefore a powerful method for rapidly locating the IR absorptions of short-lived, radiation-induced species in solution, and for directly monitoring their subsequent reactions. Time-resolved step-scan FT-IR detection for pulse radiolysis thus complements our existing narrowband quantum cascade laser-based pulse radiolysis-TRIR detection system, which is more suitable for acquiring single-shot kinetics and narrowband TRIR spectra on small-volume samples and in strongly absorbing solvents, such as water. We have demonstrated the application of time-resolved step-scan FT-IR spectroscopy to pulse radiolysis by probing the metal carbonyl and organic carbonyl vibrations of the one-electron-reduced forms of two Re-based CO2 reduction catalysts in acetonitrile solution. Transient IR absorption bands with amplitudes on the order of 1 × 10-3 are easily detected on the sub-microsecond timescale using electron pulses as short as 250 ns.

19.
Sci Rep ; 12(1): 20785, 2022 Dec 01.
Article in English | MEDLINE | ID: mdl-36456654

ABSTRACT

Porous materials with high specific surface area, high porosity, and high electrical conductivity are promising materials for functional applications, including catalysis, sensing, and energy storage. Molten salt dealloying was recently demonstrated in microwires as an alternative method to fabricate porous structures. The method takes advantage of the selective dissolution process introduced by impurities often observed in molten salt corrosion. This work further investigates molten salt dealloying in bulk Ni-20Cr alloy in both KCl-MgCl2 and KCl-NaCl salts at 700 â„ƒ, using scanning electron microscopy, energy dispersive spectroscopy, and X-ray diffraction (XRD), as well as synchrotron X-ray nano-tomography. Micro-sized pores with irregular shapes and sizes ranging from sub-micron to several microns and ligaments formed during the process, while the molten salt dealloying was found to progress several microns into the bulk materials within 1-16 h, a relatively short reaction time, enhancing the practicality of using the method for synthesis. The ligament size increased from ~ 0.7 µm to ~ 1.3 µm in KCl-MgCl2 from 1 to 16 h due to coarsening, while remaining ~ 0.4 µm in KCl-NaCl during 16 h of exposure. The XRD analysis shows that the corrosion occurred primarily near the surface of the bulk sample, and Cr2O3 was identified as a corrosion product when the reaction was conducted in an air environment (controlled amount sealed in capillaries); thus surface oxides are likely to slow the morphological coarsening rate by hindering the surface diffusion in the dealloyed structure. 3D-connected pores and grain boundary corrosion were visualized by synchrotron X-ray nano-tomography. This study provides insights into the morphological and chemical evolution of molten salt dealloying in bulk materials, with a connection to molten salt corrosion concerns in the design of next-generation nuclear and solar energy power plants.

20.
J Phys Chem Lett ; 12(1): 157-164, 2021 Jan 14.
Article in English | MEDLINE | ID: mdl-33320682

ABSTRACT

Knowledge of structural and thermal properties of molten salts is crucial for understanding and predicting their stability in many applications such as thermal energy storage and nuclear energy systems. Probing the behavior of metal contaminants in molten salts is presently limited to either foreign ionic species or metal nanocrystals added to the melt. To bridge the gap between these two end states and follow the nucleation and growth of metal species in molten salt environment in situ, we use synchrotron X-rays as both a source of solvated electrons for reducing Ni2+ ions added to ZnCl2 melt and as an atomic-level probe for detecting formation of zerovalent Ni nanoparticles. By combining extended X-ray absorption fine structure analysis with X-ray absorption near edge structure modeling, we obtained the average size and structure of the nanoparticles and proposed a radiation-induced reduction mechanism of metal ions in molten salts.

SELECTION OF CITATIONS
SEARCH DETAIL