Linking the Photoinduced Surface Potential Difference to Interfacial Charge Transfer in Photoelectrocatalytic Water Oxidation.

Charge transfer at the semiconductor/solution interface is fundamental to photoelectrocatalytic water splitting. Although insights into charge transfer in the electrocatalytic process can be gained from the phenomenological Butler-Volmer theory, there is limited understanding of interfacial charge transfer in the photoelectrocatalytic process, which involves intricate effects of light, bias, and catalysis. Here, using operando surface potential measurements, we decouple the charge transfer and surface reaction processes and find that the surface reaction enhances the photovoltage via a reaction-related photoinduced charge transfer regime as demonstrated on a SrTiO3 photoanode. We show that the reaction-related charge transfer induces a change in the surface potential that is linearly correlated to the interfacial charge transfer rate of water oxidation. The linear behavior is independent of the applied bias and light intensity and reveals a general rule for interfacial transfer of photogenerated minority carriers. We anticipate the linear rule to be a phenomenological theory for describing interfacial charge transfer in photoelectrocatalysis.

Graphene Mediates Charge Transfer between Lead Chromate and a Cobalt Cubane Cocatalyst for Photocatalytic Water Oxidation.

The interfacial barrier of charge transfer from semiconductors to cocatalysts means that the photogenerated charges cannot be fully utilized, especially for the challenging water oxidation reaction. Using cobalt cubane molecules (Co4 O4 ) as water oxidation cocatalysts, we rationally assembled partially oxidized graphene (pGO), acting as a charge-transfer mediator, on the hole-accumulating {-101} facets of lead chromate (PbCrO4 ) crystal. The assembled pGO enables preferable immobilization of Co4 O4 molecules on the {-101} facets of the PbCrO4 crystal, which is favorable for the photogenerated holes transferring from PbCrO4 to Co4 O4 molecules. The surface charge-transfer efficiency of PbCrO4 was boosted by selective assembly of pGO between PbCrO4 and Co4 O4 molecules. An apparent quantum efficiency for photocatalytic water oxidation on the Co4 O4 /pGO/PbCrO4 photocatalyst exceeded 10 % at 500 nm. This strategy of rationally assembling charge-transfer mediator provides a feasible method for acceleration of charge transfer and utilization in semiconductor photocatalysis.

Tuning the Anisotropic Facet of Lead Chromate Photocatalysts to Promote Spatial Charge Separation.

A crucial issue in artificial photosynthesis is how to modulate the behaviors of photogenerated charges of semiconductor photocatalysts. Here, using lead chromate (PbCrO4 ) as an example, we conducted the morphology tailoring from parallelepiped (p-PbCrO4 ) to truncated decahedron (t-PbCrO4 ) and elongated rhombic (r-PbCrO4 ), resulting in exposed anisotropic facets. The spatial separation of photogenerated charges closely correlates to the anisotropic facets of crystals, which can only be realized for t-PbCrO4 and r-PbCrO4 . The charge-separation efficiencies exhibit a quasilinear relation with the surface photovoltage difference between anisotropic facets. The r-PbCrO4 gives an apparent quantum efficiency of 6.5 % at 500 nm for photocatalytic water oxidation using Fe3+ ions as electron acceptors. Moreover, the oxidation reverse reaction from Fe2+ to Fe3+ ions was completely blocked with ∼100 % of Fe3+ conversion achieved on the anisotropic PbCrO4 crystals.

N170 changes reflect competition between faces and identifiable characters during early visual processing.

According to the neuronal recycling hypothesis, brain circuits can gain new functions through cultural learning, which are distinct from their evolutionarily established functions, creating competition between processes such as facial and identifiable character processing. In the present study, event-related potential (ERP) recording was used to examine electrophysiological correlates of identification levels of Chinese characters as well as the competition between facial and Chinese character processing after the characters were learnt. Twenty volunteers performed a lateralized face detection task, and N170 responses were recorded when the participants viewed only Chinese characters (identifiable or unidentifiable in Xiaozhuan font), or Chinese characters and faces concurrently. Viewing identifiable Chinese characters bilaterally elicited larger N170 amplitudes than viewing unidentifiable ones. N170 amplitudes in response to faces bilaterally declined when identifiable Chinese characters and faces were viewed concurrently as compared to viewing unidentifiable Chinese characters and faces concurrently. These results indicate that the N170 component is modulated by the observer's identification level of Chinese characters, and that identifiable Chinese characters compete with faces during early visual processing.

Inductive Reasoning Differs Between Taxonomic and Thematic Contexts: Electrophysiological Evidence.

Inductive reasoning can be performed in different contexts, but it is unclear whether the neural mechanism of reasoning performed in a thematic context (e.g., bee has x, so honey has x) is the same as that performed in a taxonomic context (e.g., bee has x, so butterfly has x). In the present study, participants were required to judge whether a conclusion was acceptable or not based on its premise, for which the taxonomic or thematic distances between premise and conclusion objects were either far or near. The Event related potential (ERP) results indicated that the effect of context (taxonomic vs. thematic) was initially observed in the P2 component; while the distance effect (far vs. near) was observed in N400 and late components. Moreover, the distance effect on thematic-based inductive reasoning was found in the anterior regions, while the distance effect on taxonomic-based inductive reasoning conditions was found in the posterior regions. These results support the view that inductive reasoning is performed differently under different semantic contexts.

Women Overestimate Temporal Duration: Evidence from Chinese Emotional Words.

Numerous studies have proven the effect of emotion on temporal perception, using various emotional stimuli. However, research investigating this issue from the lexico-semantic perspective and gender difference remains scarce. In this study, participants were presented with different types of emotional words designed in classic temporal bisection tasks. In Experiment 1 where the arousal level of emotional words was controlled, no pure effect of valence on temporal perception was found; however, we observed the overestimation of women relative to men. Furthermore, in Experiment 2, an orthogonal design of valence and arousal with neutral condition was employed to study the arousal-mechanism of temporal distortion effect and its difference between genders. The results showed that the gender difference observed in Experiment 1 was robust and was not influenced by valence and arousal. Taken together, our findings suggest a stable gender difference in the temporal perception of semantic stimuli, which might be related to some intrinsic properties of linguistic stimuli and sex differences in brain structure as well as physiological features. The automatic processing of time information was also discussed.

The N170 component is sensitive to face-like stimuli: a study of Chinese Peking opera makeup.

The N170 component is considered a neural marker of face-sensitive processing. In the present study, the face-sensitive N170 component of event-related potentials (ERPs) was investigated with a modified oddball paradigm using a natural face (the standard stimulus), human- and animal-like makeup stimuli, scrambled control images that mixed human- and animal-like makeup pieces, and a grey control image. Nineteen participants were instructed to respond within 1000 ms by pressing the 'F' or 'J' key in response to the standard or deviant stimuli, respectively. We simultaneously recorded ERPs, response accuracy, and reaction times. The behavioral results showed that the main effect of stimulus type was significant for reaction time, whereas there were no significant differences in response accuracies among stimulus types. In relation to the ERPs, N170 amplitudes elicited by human-like makeup stimuli, animal-like makeup stimuli, scrambled control images, and a grey control image progressively decreased. A right hemisphere advantage was observed in the N170 amplitudes for human-like makeup stimuli, animal-like makeup stimuli, and scrambled control images but not for grey control image. These results indicate that the N170 component is sensitive to face-like stimuli and reflect configural processing in face recognition.

Visual working memory capacity for color is independent of representation resolution.

BACKGROUND: The relationship between visual working memory (VWM) capacity and resolution of representation have been extensively investigated. Several recent ERP studies using orientation (or arrow) stimuli suggest that there is an inverse relationship between VWM capacity and representation resolution. However, different results have been obtained in studies using color stimuli. This could be due to important differences in the experimental paradigms used in previous studies. METHODOLOGY/PRINCIPAL FINDINGS: We examined whether the same relationship between capacity and resolution holds for color information. Participants performed a color change detection task while their electroencephalography was recorded. We manipulated representation resolution by asking participants to detect either a salient change (low-resolution) or a subtle change (high-resolution) in color. We used an ERP component known as contralateral delay activity (CDA) to index the amount of information maintained in VWM. The result demonstrated the same pattern for both low- and high-resolution conditions, with no difference between conditions. CONCLUSIONS/SIGNIFICANCE: This result suggests that VWM always represents a fixed number of approximately 3-4 colors regardless of the resolution of representation.

Neural processes underlying the"same"-"different" judgment of two simultaneously presented objects--an EEG study.

The present study investigated the neural processes underlying "same" and -"different" judgments for two simultaneously presented objects, that varied on one or both, of two dimensions: color and shape. Participants judged whether or not the two objects were "same" or "different" on either the color dimension (color task) or the shape dimension (shape task). The unattended irrelevant dimension of the objects was either congruent (same-same; different-different) or incongruent (same-different). ERP data showed a main effect of color congruency in the time window 190-260 ms post-stimulus presentation and a main effect of shape congruency in the time window 220-280 ms post-stimulus presentation in both color and shape tasks. The interaction between color and shape congruency in the ERP data occurred in a later time window than the two main effects, indicating that mismatches in task-relevant and task-irrelevant dimensions were processed automatically and independently before a response was selected. The fact that the interference of the task-irrelevant dimension occurred after mismatch detection, supports a confluence model of processing.