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1.
Pharm Res ; 41(2): 375-385, 2024 Feb.
Article in English | MEDLINE | ID: mdl-38114802

ABSTRACT

PURPOSE: This study is focused on monitoring process parameters and quality attributes of aluminum phosphate (AlPO4) using multiple in-line probes incorporated into an industrial-scale adjuvant suspension manufacturing unit. METHODS: The manufacturing of aluminum adjuvant suspension was monitored at manufacturing scale using conductivity, turbidity, infrared, and particle sizing and count probes to follow the continuous evolution of particle formation and size distribution, and the reaction kinetics during the synthesis of AlPO4. RESULTS: The data showed that AlPO4 forms large particles at the early stages of mixing, followed by a decrease in size and then stabilization towards the later stages of mixing and pH adjustment. The results provided a complementary view of process events and assisted in optimizing several parameters, e.g., flow rate of reactants AlCl3 and Na3PO4 solutions, mixing rate, pH, and conductivity of AlPO4, as well as adjuvant quality attribute such as particle size, thus streamlining and shortening the process development stage. CONCLUSION: The results of this study showed the usefulness of the in-line probes to automate continuous assessment of AlPO4 batch-to-batch consistency during in-house adjuvant production at the industrial scale.


Subject(s)
Adjuvants, Immunologic , Aluminum Compounds , Phosphates , Particle Size , Technology, Pharmaceutical/methods
2.
Environ Res ; 241: 117638, 2024 Jan 15.
Article in English | MEDLINE | ID: mdl-37972812

ABSTRACT

Satellite imagery has emerged as the predominant method for performing spatial and temporal water quality analyses on a global scale. This study employs remote sensing techniques to monitor the water quality of the Bisalpur wetland during both the pre and post-monsoon seasons in 2013 and 2022. The study aims to investigate the prospective use of Landsat-8 (L8) and Landsat-9 (L9) data acquired from the Operational Land Imager (OLI) and Thermal Infrared Sensor (TIRS) for the temporal monitoring of turbidity. Concurrently, the study examines the relationship of turbidity with water surface temperature (WST) and chlorophyll-a (Chl-a) concentrations. We utilized visible and near-infrared (NIR) bands to conduct a single-band spectral response analysis of wetland turbidity. The results reveal a notable increase in turbidity concentration in May 2022, as this timeframe recorded the highest reflectance (0.28) in the NIR band. Additionally, the normalized difference turbidity index (NDTI) formula was used to assess the overall turbidity levels in the wetland. The results indicated that the highest concentration was observed in May 2013, with a value of 0.37, while the second-highest concentration was recorded in May 2022, with a value of 0.25. The WST was calculated using thermal band-10 in conjunction with Chlorophyll-a, utilizing the normalized difference chlorophyll index (NDCI). The regression analysis shows a positive correlation between turbidity and WST, as indicated by R2 values of 0.41 in May 2013 and 0.40 in May 2022. Furthermore, a robust positive relationship exists between turbidity and Chl-a, with a high R2 value of 0.71 in May 2022. These findings emphasize the efficacy of the L8 and L9 datasets for conducting temporal analyses of wetland turbidity, WST, and Chl-a. Additionally, this research underscores the critical role of satellite imagery in assessing and managing water quality, particularly in situations where in-situ data is lacking.


Subject(s)
Satellite Imagery , Wetlands , Environmental Monitoring/methods , India , Chlorophyll A/analysis , Chlorophyll/analysis
3.
Environ Res ; 255: 119134, 2024 Aug 15.
Article in English | MEDLINE | ID: mdl-38751002

ABSTRACT

The deep removal of organic pollutants is challenging for coagulation technology in drinking water and wastewater treatment plants to satisfy the rising water standards. Iron (III) chloride (FeCl3) is a popular inorganic coagulant; although it has good performance in removing the turbidity (TB) in water at an alkaline medium, it cannot remove dissolved pollutants and natural organic matter such as humic acid water solution. Additionally, its hygroscopic nature complicates determining the optimal dosage for effective coagulation. Biochar (BC), a popular adsorbent with abundant functional groups, porous structure, and relatively high surface area, can adsorb adsorbates from water matrices. Therefore, combining BC with FeCl3 presents a potential solution to address the challenges associated with iron chloride. Consequently, this study focused on preparing and characterizing a novel biochar/ferric chloride-based coagulant (BC-FeCl3) for efficient removal of turbidity (TB) and natural organic matter, specifically humic acid (HA), from synthetic wastewater. The potential solution for the disposal of produced sludge was achieved by its recovering and recycling, then used in adsorption of HA from aqueous solution. The novel coagulant presented high TB and HA removal within 10 min of settling period at pH solution of 7.5. Furthermore, the recovered sludge presented a good performance in the adsorption of HA from aqueous solution. Adsorption isotherm and kinetics studies revealed that the Pseudo-second-order model best described kinetic adsorption, while the Freundlich model dominated the adsorption isotherm.


Subject(s)
Charcoal , Chlorides , Ferric Compounds , Humic Substances , Wastewater , Humic Substances/analysis , Charcoal/chemistry , Adsorption , Chlorides/chemistry , Ferric Compounds/chemistry , Wastewater/chemistry , Water Pollutants, Chemical/chemistry , Water Pollutants, Chemical/analysis , Sewage/chemistry , Waste Disposal, Fluid/methods , Water Purification/methods
4.
Article in English | MEDLINE | ID: mdl-39110197

ABSTRACT

PURPOSE: To evaluate tear meniscus parameters in soft contact lens wearers (SCL) using optical coherence tomography (OCT) and ImageJ software. METHODS: This prospective study included 50 soft contact lens wearers (group 1: 25 symptomatic SCL wearers (SCLW), group 2: 25 asymptomatic SCL wearers (ASCW)) and 25 healthy non-CL wearers (group 3 (NCLW)). SCLs were fitted on each eye of CL wearers, and the lower tear meniscus was imaged using OCT before CL insertion, immediately afterward, and reimaged 2, 5 and 10 h after insertion. Tear meniscus parameters, including tear meniscus height (TMH), depth (TMD), turbidity, and percentage area occupied by particles (PAOP) were measured in all groups. RESULTS: Turbidity and PAOP measurements at baseline in SCLW were significantly higher than in other groups (p < 0.05). There was no significant difference between TMH, TMD, turbidity, and PAOP parameters calculated at baseline visit and two hours after SCL insertion in all groups (p > 0.05 for 2 comparisons). The symptomatic SCL users had a significant decrease in TMH and TMD in the fifth hour. The turbidity and PAOP measurements of SCLW and ASCW at the fifth and tenth hours were significantly higher than those of NCLW (p < 0.05). CONCLUSION: TMD and height TMH decrease throughout the day in all participants; however, a significant decrease in these parameters was observed only in symptomatic SCL users at the fifth hour, at the earliest. As the duration of CL wear increases, turbidity and PAOP even in asymptomatic SCL wearers become significantly higher than those in healthy non-CL wearers. KEY MESSAGES: What Is Known • Contact lens wear is associated with an increased risk of dry eye. • Tear volume decreases gradually during contact lens wear. What Is New • Tear meniscus turbidity and particle area occupied by particles (PAOP) were higher in symptomatic contact lens wearers and they increase gradually during contact lens wear. • Tear meniscus turbidity and PAOP may be measures of how well the tear film and meniscus are functioning in contact lens wearers.

5.
Sensors (Basel) ; 24(5)2024 Feb 23.
Article in English | MEDLINE | ID: mdl-38474972

ABSTRACT

Salivary turbidity is a promising indicator for evaluating oral hygiene. This study proposed a wearable mouthguard-type sensor for continuous and unconstrained measurement of salivary turbidity. The sensor evaluated turbidity by measuring the light transmittance of saliva with an LED and a phototransistor sealed inside a double-layered mouthguard. The sensor was also embedded with a Bluetooth wireless module, enabling the wireless measurement of turbidity. The mouthguard materials (polyethylene terephthalate-glycol and ethylene-vinyl acetate) and the wavelength of the LED (405 nm) were experimentally determined to achieve high sensitivity in salivary turbidity measurement. The turbidity quantification characteristic of the proposed sensor was evaluated using a turbidity standard solution, and the sensor was capable of turbidity quantification over a wide dynamic range of 1-4000 FTU (formazine turbidity unit), including reported salivary turbidity (400-800 FTU). In vitro turbidity measurement using a saliva sample showed 553 FTU, which is equivalent to the same sample measured with a spectrophotometer (576 FTU). Moreover, in vivo experiments also showed results equivalent to that measured with a spectrophotometer, and wireless measurement of salivary turbidity was realized using the mouthguard-type sensor. Based on these results, the proposed mouthguard-type sensor has promising potential for the unconstrained continuous evaluation of oral hygiene.


Subject(s)
Mouth Protectors , Wearable Electronic Devices , Oral Hygiene , Saliva
6.
Sensors (Basel) ; 24(12)2024 Jun 17.
Article in English | MEDLINE | ID: mdl-38931710

ABSTRACT

Turbidity stands as a crucial indicator for assessing water quality, and while turbidity sensors exist, their high cost prohibits their extensive use. In this paper, we introduce an innovative turbidity sensor, and it is the first low-cost turbidity sensor that is designed specifically for long-term stormwater in-field monitoring. Its low cost (USD 23.50) enables the implementation of high spatial resolution monitoring schemes. The sensor design is available under open hardware and open-source licences, and the 3D-printed sensor housing is free to modify based on different monitoring purposes and ambient conditions. The sensor was tested both in the laboratory and in the field. By testing the sensor in the lab with standard turbidity solutions, the proposed low-cost turbidity sensor demonstrated a strong linear correlation between a low-cost sensor and a commercial hand-held turbidimeter. In the field, the low-cost sensor measurements were statistically significantly correlated to a standard high-cost commercial turbidity sensor. Biofouling and drifting issues were also analysed after the sensors were deployed in the field for more than 6 months, showing that both biofouling and drift occur during monitoring. Nonetheless, in terms of maintenance requirements, the low-cost sensor exhibited similar needs compared to the GreenSpan sensor.

7.
J Fish Biol ; 104(4): 1054-1066, 2024 Apr.
Article in English | MEDLINE | ID: mdl-38168734

ABSTRACT

Diadromous fish have exhibited a dramatic decline since the end of the 20th century. The allis shad (Alosa alosa) population in the Gironde-Garonne-Dordogne (GGD) system, once considered as a reference in Europe, remains low despite a fishing ban in 2008. One hypothesis to explain this decline is that the downstream migration and growth dynamics of young stages have changed due to environmental modifications in the rivers and estuary. We retrospectively analysed juvenile growth and migration patterns using otoliths from adults caught in the GGD system 30 years apart during their spawning migration, in 1987 and 2016. We coupled otolith daily growth increments and laser ablation inductively-coupled plasma mass spectrometry measurements of Sr:Ca, Ba:Ca, and Mn:Ca ratios along the longest growth axis from hatching to an age of 100 days (i.e., during the juvenile stage). A back-calculation allowed us to estimate the size of juveniles at the entrance into the brackish estuary. Based on the geochemistry data, we distinguished four different zones that juveniles encountered during their downstream migration: freshwater, fluvial estuary, brackish estuary, and lower estuary. We identified three migration patterns during the first 100 days of their life: (a) Individuals that reached the lower estuary zone, (b) individuals that reached the brackish estuary zone, and (c) individuals that reached the fluvial estuary zone. On average, juveniles from the 1987 subsample stayed slightly longer in freshwater than juveniles from the 2016 subsample. In addition, juveniles from the 2016 subsample entered the brackish estuary at a smaller size. This result suggests that juveniles from the 2016 subsample might have encountered more difficult conditions during their downstream migration, which we attribute to a longer exposure to the turbid maximum zone. This assumption is supported by the microchemical analyses of the otoliths, which suggests based on wider Mn:Ca peaks that juveniles in 2010s experienced a longer period of physiological stress during their downstream migration than juveniles in 1980s. Finally, juveniles from the 2016 subsample took longer than 100 days to exit the lower estuary than we would have expected from previous studies. Adding a new marker (i.e., Ba:Ca) helped us refine the interpretation of the downstream migration for each individual.


Subject(s)
Fresh Water , Rivers , Animals , Retrospective Studies , France/epidemiology , Europe , Fishes
8.
J Environ Manage ; 364: 121256, 2024 Jul.
Article in English | MEDLINE | ID: mdl-38865918

ABSTRACT

To address the deleterious impacts of excess soil erosion from the construction sites, the United States Clean Water Act requires that erosion and sediment control measures (ESCs) be implemented on construction projects disturbing more than 0.4 ha. Inlet protection devices (IPDs) are a common ESC utilized on construction projects to reduce the amount of sediment entering storm sewers. In Ohio, regulatory agencies use approved, non-proprietary IPDs made from commonly available materials (e.g., silt fence, geotextile, lumber, and aggregate) to mitigate sediment on construction projects; however, these IPDs often rely on extended ponding to remove sediment and require frequent maintenance making these unsuitable for road construction projects. Commercially manufactured (i.e., proprietary) IPDs which rely on filtration to quickly dewater following rainfall may prove more practical for road construction projects. However, little research which quantitatively compares the holistic performance of these two types of IPDs in field settings has been performed to date. To address this knowledge gap, the performance of 24 proprietary IPDs was evaluated at field-scale using simulated construction site runoff and compared to three non-proprietary IPDs currently approved for use in Ohio. Bypass flows, which typically occurred due to poor IPD fit to standard drainage inlets used in Ohio transportation settings, significantly increased effluent total suspended solids (TSS) and turbidity compared to tests of IPDs where bypass did not occur. Overflow, or intentional bypass around primary IPD flow pathways during high flows, did not significantly impact effluent water quality. Despite differences in treatment mechanisms (i.e., sedimentation versus filtration), the water quality performance of non-proprietary and proprietary IPDs were not statistically different, indicating comparable sediment removal was provided by both categories. Findings from this research can provide design engineers and state regulatory agencies the necessary tools to evaluate IPD performance in road construction settings and, ultimately, alleviate the impact of excess sediment discharged from construction sites.


Subject(s)
Geologic Sediments , Ohio , Environmental Monitoring
9.
J Environ Manage ; 366: 121726, 2024 Aug.
Article in English | MEDLINE | ID: mdl-38972184

ABSTRACT

Drinking water (DW) production treatments can be affected by climate change, in particular intense rainfall events, having an impact on the availability and quality of the water source. The current study proposes a methodology for the evaluation of the costs of the different treatment steps for surface water (SW) and groundwater (GW), through the analysis and quantification of the main cost items. It provides the details to count for strong variations in the key quality parameters of inlet water following severe rainfalls (namely turbidity, iron, manganese, and E. coli). This methodology is then applied to a large drinking water treatment plant (DWTP) in Italy, which treats both SW, around 70 %, and GW, around 30%. It discusses the overall DW production costs (from 7.60 c€/m3 to 10.43 c€/m3) during the period 2019-2021 and analyzes the contributions of the different treatment steps in water and sludge trains. Then it focuses on the effects on the treatments of significant variations in SW turbidity (up to 1863 NTU) due to intense rainfalls, and on the daily costs of DW with respect to the average (baseline) costs evaluated on the annual basis. It emerges that, when SW has low turbidity levels, the energy-based steps have the biggest contribution on the costs (final pumping 22 % for SW and 10 % for GW, withdrawal 15 % and 14 %, respectively), whereas at very high turbidity levels, sludge greatly increases, and its treatment and disposal costs become significant (up to 14 % and 50 %). Efforts are being made to adopt the best strategies for the management of DWTPs in these adverse conditions, with the aim to guarantee potable water and optimize water production costs. A mitigation measure consists of increasing GW withdrawal up to the authorized flow rate, thus reducing SW withdrawal. In this context, the study is completed by discussing the potential upgrading of the DWTP by only treating GW withdrawn from riverbank filtration. The DW production cost would be 7.76 c€/m3, which is lower than that seen for the same year (2021) with the current plant configuration (8.32 c€/m3).


Subject(s)
Climate Change , Drinking Water , Water Purification , Water Purification/economics , Groundwater , Italy , Water Supply
10.
J Environ Manage ; 354: 120258, 2024 Mar.
Article in English | MEDLINE | ID: mdl-38387343

ABSTRACT

Global sustainable development faces several challenges in addressing the needs of a growing population. Regarding food industries, the heightening pressure to meet these needs has resulted in increased waste generation. Thus, recognising these wastes as valuable resources is crucial to integrating sustainable models into current production systems. For instance, the current 24 billion tons of nutrient-rich livestock wastewater (LW) generated yearly could be recovered and valorised via biological uptake through microalgal biomass. Microalgae-based livestock wastewater treatment (MbLWT) has emerged as an effective technology for nutrient recovery, specifically targeting carbon, nitrogen, and phosphorus. However, the viability and efficacy of these systems rely on the characteristics of LW, including organic matter and ammonium concentration, content of suspended solids, and microbial load. Thus, this systematic literature review aims to provide guidance towards implementing an integral MbLWT system for nutrient control and recovery, discussing several pre-treatments used in literature to overcome the challenges regarding LW as a suitable media for microalgae cultivation.


Subject(s)
Livestock , Microalgae , Nitrogen , Nutrients , Phosphorus , Waste Disposal, Fluid , Wastewater , Microalgae/growth & development , Microalgae/metabolism , Animals , Waste Disposal, Fluid/methods , Carbon , Biomass
11.
Pharm Dev Technol ; 29(7): 684-690, 2024 Sep.
Article in English | MEDLINE | ID: mdl-38995216

ABSTRACT

The appearance of an extrudate formulation was monitored during hot-melt extrusion (HME) continuous manufacturing over 3 days. The formulation matrix consisted of a polymeric component, copovidone, and a low molecular weight surfactant, polysorbate 80. Based on studies prior to the continuous manufacturing, the desired appearance of the target extrudate is translucent. Although process parameters such as feed rate and screw speed were fixed during the continuous manufacturing, the extrudate appearance changed over time from turbid to translucent. For root-cause investigation, the extrudates were analyzed offline by differential scanning calorimetry (DSC) and advanced polymer chromatography (APC™). Although the polysorbate 80 content of both turbid and translucent extrudates was within target, the glass transition temperature of the turbid extrudate was 2 °C above expected value. The observed turbidity was traced to lot-to-lot variability of the polysorbate 80 used in the continuous manufacturing, where APC™ analysis revealed that the relative content of the low molecular weight component varied from 23% to 27% in correlation with the evolution from turbid to translucent extrudates. This work stresses the importance of taking feeding material variability into account during continuous manufacturing.


Subject(s)
Calorimetry, Differential Scanning , Polysorbates , Surface-Active Agents , Polysorbates/chemistry , Surface-Active Agents/chemistry , Pyrrolidines/chemistry , Hot Melt Extrusion Technology/methods , Vinyl Compounds/chemistry , Excipients/chemistry , Transition Temperature , Chemistry, Pharmaceutical/methods
12.
Environ Monit Assess ; 196(10): 874, 2024 Sep 02.
Article in English | MEDLINE | ID: mdl-39222246

ABSTRACT

The present study deals with the assessment of different physicochemical parameters (pH, electrical conductivity (E.C.), turbidity, total dissolved solids (TDS), and dissolved oxygen) in different surface water such as pond, river, and canal water in four different seasons, viz. March, June, September, and December 2023. The research endeavors to assess the impact of a cationic polyelectrolyte, specifically poly(diallyl dimethyl ammonium chloride) (PDADMAC), utilized as a coagulation aid in conjunction with lime for water treatment. Employing a conventional jar test apparatus, turbidity removal from diverse water samples is examined. Furthermore, the samples undergo characterization utilizing X-ray diffraction (XRD) and scanning electron microscopy (SEM) techniques. The study also conducts correlation analyses on various parameters such as electrical conductivity (EC), pH, total dissolved solids (TDS), turbidity of raw water, polyelectrolyte dosage, and percentage of turbidity removal across different water sources. Utilizing the Statistical Package for Social Science (SPSS) software, these analyses aim to establish robust relationships among initial turbidity, temperature, percentage of turbidity removal, dosage of coagulant aid, electrical conductivity, and total dissolved solids (TDS) in pond water, river water, and canal water. A strong positive correlation could be found between the percentage of turbidity removal and the value of initial turbidity of all surface water. However, a negative correlation could be observed between the polyelectrolyte dosage and raw water's turbidity. By elucidating these correlations, the study contributes to a deeper understanding of the effectiveness of PDADMAC and lime in water treatment processes across diverse environmental conditions. This research enhances our comprehension of surface water treatment methodologies and provides valuable insights for optimizing water treatment strategies to address the challenges posed by varying water sources and seasonal fluctuations.


Subject(s)
Calcium Compounds , Oxides , Quaternary Ammonium Compounds , Rivers , Seasons , Water Purification , Oxides/chemistry , Calcium Compounds/chemistry , Quaternary Ammonium Compounds/chemistry , Quaternary Ammonium Compounds/analysis , Rivers/chemistry , Water Purification/methods , Polyethylenes/chemistry , Water Pollutants, Chemical/analysis , Ponds/chemistry , Environmental Monitoring/methods
13.
Environ Monit Assess ; 196(3): 292, 2024 Feb 22.
Article in English | MEDLINE | ID: mdl-38383658

ABSTRACT

Human use index caused by population pressure in Opa catchment Ile Ife, Southwestern Nigeria, has resulted in catchment denudation, accelerated erosion, and sediment delivery into a man-made (1978) reservoir (Opa) in the catchment. This study is aimed at evaluating the suspended sediment balance of Opa reservoir with a view to ascertain the annual siltation rate. River discharges, water levels, suspended sediment concentrations/yield, and flow velocities were monitored, and data collected from all the tributaries of the Opa reservoir and the spillway (outlet) in the period 2017-2018. Water samples collected were subjected to gravimetric analysis, and the results utilized to obtain sediment rating curves and to compute the suspended sediment balance. Suspended sediment inflow from the six sub-catchments ranged from 8.49 to 29.05tons/ha, with a total inflow of 1146.50tons/ha into the reservoir during the hydrological year. The corresponding outflow through the spillway was 615.70tons/ha. 530.80tons/ha was sequestered in the reservoir, equivalent to an estimate of 46% suspended sediment deposited in the reservoir. The high sediment yield in Opa reservoir is due to the dredging and clearing of the river channels in the catchment of any impediment thereby enhancing sediment delivery into the reservoir. Sediment loads were higher in the rainy season suggesting catchment erosion as the main factor responsible for the sediment yield into the reservoir. The study concluded that the positive suspended sediment balance suggests sediment sequestration with an increasing tendency for accelerated elimination of the wetland in the face of poor environmental management and enhanced human activities.


Subject(s)
Environmental Monitoring , Geologic Sediments , Humans , Nigeria , Geologic Sediments/analysis , Seasons , Rivers , Water/analysis
14.
Environ Sci Technol ; 57(35): 13161-13171, 2023 09 05.
Article in English | MEDLINE | ID: mdl-37610829

ABSTRACT

Environmental DNA (eDNA) in aquatic systems is a complex mixture that includes dissolved DNA, intracellular DNA, and particle-adsorbed DNA. Information about the various components of eDNA and their relative proportions could be used to discern target organism abundance and location. However, a limited knowledge of eDNA adsorption dynamics and interactions with other materials hinders these applications. To address this gap, we used recirculating stream mesocosms to investigate the impact of suspended materials (fine particulate organic matter, plankton, clay, and titanium dioxide) on the eDNA concentration and particle size distribution (PSD) from two fish species in flowing water. Our findings revealed that eDNA rapidly adsorbs to other materials in the water column, affecting its concentration and PSD. Nonetheless, only particulate organic matter affected eDNA removal rate after 30 h. Moreover, we observed that the removal of larger eDNA components (≥10 µm) was more strongly influenced by physical processes, whereas the removal of smaller eDNA components was driven by biological degradation. This disparity in removal mechanisms between larger and smaller eDNA components could explain changes in eDNA composition over time and space, which have implications for modeling the spatial distribution and abundance of target species and optimizing eDNA detection in high turbidity systems.


Subject(s)
DNA, Environmental , Animals , Particle Size , Physical Phenomena , Adsorption , Particulate Matter , Water
15.
J Appl Microbiol ; 134(10)2023 Oct 04.
Article in English | MEDLINE | ID: mdl-37709569

ABSTRACT

AIMS: While fecal indicator bacteria (FIB) testing is used to monitor surface water for potential health hazards, observed variation in FIB levels may depend on the scale of analysis (SOA). Two decades of citizen science data, coupled with random effects models, were used to quantify the variance in FIB levels attributable to spatial versus temporal factors. METHODS AND RESULTS: Separately, Bayesian models were used to quantify the ratio of spatial to non-spatial variance in FIB levels and identify associations between environmental factors and FIB levels. Separate analyses were performed for three SOA: waterway, watershed, and statewide. As SOA increased (from waterway to watershed to statewide models), variance attributable to spatial sources generally increased and variance attributable to temporal sources generally decreased. While relationships between FIB levels and environmental factors, such as flow conditions (base versus stormflow), were constant across SOA, the effect of land cover was highly dependent on SOA and consistently smaller than the effect of stormwater infrastructure (e.g. outfalls). CONCLUSIONS: This study demonstrates the importance of SOA when developing water quality monitoring programs or designing future studies to inform water management.


Subject(s)
Citizen Science , Water Quality , Environmental Monitoring/methods , Bayes Theorem , Escherichia coli , Water Microbiology , Feces/microbiology , Bacteria
16.
Environ Res ; 237(Pt 1): 116946, 2023 Nov 15.
Article in English | MEDLINE | ID: mdl-37619631

ABSTRACT

Water hyacinth is the target of nine biological control agents in South Africa including Neochetina eichhorniae (Warner) and Neochetina bruchi (Hustache) (Coleoptera: Curculionidae). These two weevils have also been released against water hyacinth in Rwanda, but failed to control the weed invasion, possibly due to high turbidity in the country's water bodies. This study therefore aimed to investigate the effect of water turbidity on the establishment and performance of N. eichhorniae in Rwanda. Turbidity levels were measured over two seasons in four Rwandan rivers and two lakes. The results were then used to benchmark laboratory trials to test the effect of turbidity on the weevils' development. Water hyacinth plants were maintained at four turbidity levels: Clear water (2 Nephelometric Turbidity Units (NTU): low (85 NTU), medium (600 NTU) and high (1500 NTU). Each treatment plant was inoculated with three N. eichhorniae larvae, while control plants were free of larvae. Plant growth was measured weekly for three months, while adult weevil emergence was recorded from the 56th day of the experiment. The number of adults emerging from the treatment plants grown in the clear water, low, medium and high turbidity levels were 24, 21, 12 and 0, respectively. Larval feeding was greater on plants growing in clear water and the low turbidity, compared to the medium and high turbidity treatments. These results indicate that N. eichhorniae may not establish or perform well in water bodies with high levels of turbidity, which in turn enhances the growth of water hyacinth, allowing compensatory growth for weevil feeding.

17.
Environ Res ; 234: 116581, 2023 10 01.
Article in English | MEDLINE | ID: mdl-37423364

ABSTRACT

Soil erosion is a very serious environmental problem worldwide, with agriculture considered the main source of sediment in inland waters. In order to determine the extent and importance of soil erosion in the Spanish region of Navarra, in 1995 the Government of Navarra established the Network of Experimental Agricultural Watersheds (NEAWGN), which consists of five small watersheds representative of local conditions. In each watershed, key hydrometeorological variables, including turbidity, were recorded every 10 min, and daily samples were taken to determine suspended sediment concentration. In 2006, the frequency of suspended sediment sampling was increased during hydrologically relevant events. The main objective of this study is to explore the possibility of obtaining long and accurate time series of suspended sediment concentration in the NEAWGN. To this end, simple linear regressions between sediment concentration and turbidity are proposed. In addition, supervised learning models incorporating a larger number of predictive variables are used for the same purpose. A series of indicators are proposed to objectively characterize the intensity and timing of sampling. It was not possible to obtain a satisfactory model for estimating the concentration of suspended sediment. This would be mainly due to the large temporal variability found of the physical and mineralogical characteristics of the sediment, which would be affecting the turbidity value, independently of the sediment concentration, per se. This fact would be particularly important in small river watersheds such as those of this study, and especially if their physical conditions are spatially and temporally radically disturbed by agricultural tillage and by a constant modification of the vegetation cover, as is the case in cereal basins. Our findings suggest that better results could be obtained by including in the analysis variables such as soil texture and exported sediment texture, rainfall erosivity, and the state of vegetation cover and riparian vegetation.


Subject(s)
Environmental Monitoring , Geologic Sediments , Spain , Environmental Monitoring/methods , Geologic Sediments/analysis , Agriculture , Soil , Rivers
18.
Proc Natl Acad Sci U S A ; 117(31): 18278-18284, 2020 Aug 04.
Article in English | MEDLINE | ID: mdl-32690702

ABSTRACT

Long-running gravity currents are flows that are submerged beneath a deep layer of quiescent fluid and they travel over long distances along inclined or horizontal surfaces. They are driven by the density difference between the current and the clear ambient fluid above. In this work we present results on highly resolved direct numerical simulations of turbid underflows that involve nearly 1 billion degrees of freedom. We assess the effect of bed slope on the flow statistics. We explore the turbulence dynamics of the interface in the classical sub- and supercritical regimes. We investigate the structure of interfacial turbulence and its relation to the turbulence statistic. A transcritical regime is identified where intermittent cascading interfacial instabilities appear. We investigate how departure from the self-sustaining equilibrium state may be the mechanism responsible for this cyclic evolution of the transcritical regime.

19.
Sensors (Basel) ; 23(6)2023 Mar 13.
Article in English | MEDLINE | ID: mdl-36991784

ABSTRACT

Given progress in water-quality analytical technology and the emergence of the Internet of Things (IoT) in recent years, compact and durable automated water-quality monitoring devices have substantial market potential. Due to susceptibility to the influence of interfering substances, which lowers measurement accuracy, existing automated online monitoring devices for turbidity, a key indicator of a natural water body, feature a single light source and are thus insufficient for more complicated water-quality measurement. The newly developed modularized water-quality monitoring device boasts dual light sources (VIS/NIR), capable of measuring the intensity of scattering, transmission, and reference light at the same time. Coupled with a water-quality prediction model, it can attain a good estimate for continuing monitoring of tap water (<2 NTU, error < 0.16 NTU, relative error < 19.6%) and environmental water samples (<400 NTU, error < 3.86 NTU, relative error < 2.3%). This indicates the optical module can both monitor water quality in low turbidity and provide water-treatment information alerts in high turbidity, thereby materializing automated water-quality monitoring.

20.
Sensors (Basel) ; 23(18)2023 Sep 09.
Article in English | MEDLINE | ID: mdl-37765828

ABSTRACT

Due to the regional differences between the North and South Yellow Sea, and under the influence of winter winds, the relative changes in the coastal current and the Yellow Sea warm current will lead to the instability of the front, which will lead to the cross-front transport of sediment. Therefore, the study of sediment exchange between the North and South Yellow Sea has become an indispensable part of the study of the Yellow Sea environment. In this study, the current field and sediment concentration in the southern part of Chengshantou, a representative area of the Yellow Sea, were observed in winter in order to analyze the sediment exchange process between the North Yellow Sea and the South Yellow Sea in winter. The observation results show that in the southern sea area of Chengshantou, in winter, the current velocity does not change with the water depth when it exceeds 15 m, and the tides are regular semi-diurnal tides. When the water depth is less than 15 m, the current direction changes clockwise with the increase in the water depth. The turbidity increases rapidly when the wind direction is offshore and the bottom residual current is onshore, which may cause the sediment transported offshore under the action of wind and ocean current to settle under the obstruction of the Yellow Sea warm current, resulting in the rise of bottom turbidity. This also indicates that the change in residual current direction at different water depths may also lead to an increase in suspended sediment concentration. Based on this, in the estuarine area, the relative change in the current direction between the wind current and the coastal current may also be the cause of the change in the maximum turbidity zone.

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