Impact of Nanoparticle Additions on Life Cycle Assessment (LCA) of Ceramic Tiles Production.

The ceramic tile industry, with significant energy and material demands in its manufacturing processes, has employed technological innovations in energy efficiency, advanced equipment and tile thickness reduction to address these challenges. This study aimed to assess the impact of Ag2O, CuFe2O4, Fe3O4, and SiO2 nanoparticles (0%, 1%, and 5% by weight) on the mechanical strength, water absorption, and apparent thermal conductivity of ceramic tiles, as well as their capacity to reduce energy and raw material consumption. This reduction translates into a decrease in environmental impacts, which have been evaluated through life cycle assessment (LCA) methodology applied to the manufacturing processes. Nanoparticles (Ag2O, CuFe2O4, Fe3O4, and SiO2) were initially screened on TF clay (0%, 1%, 5% w/w), and the most effective were applied to CR1 and CR2 clays (0%, 1%, 5% w/w). Findings indicated a 32% increase in temperature gradient and a 16% improvement in flexural strength with the addition of Fe3O4 nanoparticle at 1% (w/w) in TF clay. Furthermore, there was a potential 48% reduction in energy consumption, and up to 16% decrease in tile weight or thickness without affecting the flexural strength property of the test tiles. LCA results demonstrated that the addition of Fe3O4 nanoparticle has potential reductions of up to 20% in environmental impacts. This study suggests that nanoparticle addition offers a viable alternative for reducing energy and material consumption in the ceramic tile industry. Future research should focus on assessing the economic impact of transitioning to a sustainable business model in the ceramic tile industry with nanoparticles addition.

Preparation and Performance of Ceramic Tiles with Steel Slag and Waste Clay Bricks.

Steel slag and waste clay bricks are two prevalent solid waste materials generated during industrial production. The complex chemical compositions of these materials present challenges to their utilization in conventional alumina silicate ceramics manufacturing. A new type of ceramic tile, which utilizes steel slag and waste clay brick as raw materials, has been successfully developed in order to effectively utilize these solid wastes. The optimal composition of the ceramic material was determined through orthogonal experimentation, during which the effects of the sample molding pressure, the soaking time, and the sintering temperature on the ceramic properties were studied. The results show that the optimal ceramic tile formula was 45% steel slag, 35% waste clay bricks, and 25% talc. The optimal process parameters for this composition included a molding pressure of 25 MPa, a sintering temperature of 1190 °C, and a soaking time of 60 min. The prepared ceramic tile samples had compositions in which solid waste accounted for more than 76% of the total material. Additionally, they possessed a modulus of rupture of more than 73.2 MPa and a corresponding water absorption rate of less than 0.05%.

Naturally Occurring Radionuclides in Tiles Available in Ibadan, Nigeria, and the Associated Radiological Hazards.

Introduction: All building materials of natural origin contain some amounts of primordial radionuclides, 40K, 232Th, and 238U, as well as other radionuclides in the decay series of 232Th and 238U. Purpose: The use of tiles to beautify walls and floors in dwellings has become popular worldwide and in Nigeria in particular. However, not much has been done in assessing the impact of the use of floor and wall tiles on the radiation exposure of dwellers. In this study, radioisotopes of natural origin (226Ra, 232Th, and 40K) in selected ceramic tiles often used in Ibadan Southwest Nigeria were estimated and the associated radiological parameters evaluated. Methodology: Forty-five samples of different types of floor and wall tiles were obtained from local markets within the study area. Each of the 45 samples was pulverized and sealed in an airtight sample container for 4 weeks before analysis using a sodium iodide-based gamma-ray spectrometer. Results: The average values of 226Ra, 232Th, and 40K obtained were 44.28 ± 0.56, 84.71 ± 0.60, and 830.44 ± 0.63 Bqkg-1, respectively, which shows that they are greater than the corresponding estimated worldwide average concentration. Again, the estimated average values obtained for the radiological hazard parameters for equivalent activity due to radium and representative gamma-ray level index were found to be lower than the world averages. Similarly, the absorbed dose rates due to gamma-ray emission were found to be higher than the world common values. Conclusion: This study indicates that the use of these tiles will not be posing potential radiological risk if used in dwellings. However, construction works that requires the use of these tiles must be designed in such a way that the emission of dangerous radiation will not be a threat to the occupants.

The implicit preference evaluation for the ceramic tiles with different visual features: Evidence from an event-related potential study.

Background: Ceramic tiles are popular because of their various forms, and they are often used to decorate the environment. However, few studies have applied objective methods to explore the implicit preference and visual attention of people toward ceramic tile features. Using event-related potential technology can provide neurophysiological evidence for the study and applications of tiles. Materials and methods: This study explored the influence of pattern, lightness, and color system factors of ceramic tiles on the preferences of people using a combination of subjective questionnaires and event-related potential (ERP) technology. Twelve different conditions of tiles (2 × 3 × 2) were used as stimuli. EEG data were collected from 20 participants while they watched the stimuli. Subjective preference scores and average ERPs were analyzed using analysis of variance and correlation analysis. Results: (1) Pattern, lightness, and color system factors significantly affected the subjective preference scores for tiles; the unpatterned tiles, light-toned tiles, and warm-colored tiles received higher preference scores. (2) The preferences of people for different features of tiles moderated ERP amplitudes. (3) The light-toned tiles with a high preference score caused a greater N100 amplitude than the medium-toned and dark-toned tiles; and the patterned tiles and warm-colored tiles with low preference scores induced greater P200 and N200 amplitudes. Discussion: In the early stage of visual processing, light-toned tiles attracted more attention, possibly because of the positive emotional effects related to the preference. The greater P200 and N200 elicited by the patterned and neutral-colored tiles in the middle stage of visual processing indicates that patterned and neutral-colored tiles attracted more attention. This may be due to negativity bias, where more attention is allocated to negative stimuli that people strongly dislike. From the perspective of cognitive processes, the results indicate that the lightness of ceramic tiles is the factor that people first detect, and the visual processing of pattern and color system factors of ceramic tiles belong to a higher level of visual processing. This study provides a new perspective and relevant information for assessing the visual characteristics of tiles for environmental designers and marketers involved in the ceramic tiles industry.

New Ceramic Tiles Produced Using Old Technology Applied on Historic Roofs-Possibilities and Challenges.

In the case of historic buildings, especially those under protection, it is important to replace elements of the roof covering, while maintaining current technical standards, to meet the requirements of the conservator. The authors of the article present alternatives to commonly used solutions, based on their experience with replacing historic building roofing with ceramic tiles made according to the production and firing technology of the nineteenth century. They emphasize that the correct/specialized restoration of existing tiles in a building makes it possible to preserve and reuse them, which is in line with the principles of historic preservation. However, due to the preservation of the roof tiles, it is not always possible to revitalize them. As a solution to the problem, the use of clay roof tiles manufactured according to 19th-century firing technology, including handmade methods, is presented, which preserves the geometry of the historic roof tiles. The approach presented by the authors meets both the requirements of conservation theory and the building standards for roofing elements. Although it is much more expensive than the solutions currently commonly used that result from modern technical requirements and tile-manufacturing technology, in the case of objects of significant cultural heritage, it is a solution that meets modern technical requirements while not compromising the original appearance of the monument.

Pulmonary function and respiratory symptoms in workers exposed to respirable silica dust: A historical cohort study.

Background: The adverse health effects of silica are still a major concern in some industries. The purpose of this study was to evaluate pulmonary function in a group of sub-radiological silicotic workers after 11 years of silica dust exposure. Methods: The study sample consisted of 381 exposed and 254 non-exposed workers. The history of pulmonary function parameters was obtained from workers' medical records. The data were collected through interviews with employees and completing questionnaires on demographic variables, detailed occupational and medical history, and respiratory symptoms. Workers' exposure to silica dust was also determined. Results: The mean frequency of workers' exposure to silica dust was 6.3 times greater than its exposure limit. All pulmonary function parameters were significantly lower in the silica-exposed workers, and the difference between the two groups was still statistically significant after adjusting the potential confounding variables. FEV1 showed the greatest reduction, and FVC and FEV1 showed a significant decreasing trend. Also the prevalence of respiratory symptoms was significantly higher in smokers than in nonsmokers among silica-exposed workers. Conclusions: Even in the absence of radiographic evidence of silicosis, exposure to high levels of silica dust is associated with reductions in pulmonary function. In the absence of radiological evidence of silicosis, progressive deterioration of FEV1 over time most likely indicates sub-radiological silicosis. The effects were associated with the severity and duration of exposure. Exposure to sub-TLV levels of silica dust may not affect pulmonary function. Smoking appears to have a synergistic effect in relatively high silica exposures.

Thermal, physical, mechanical and microstructural properties of dredged sediment-based ceramic tiles as substituent of kaolin.

The aim of this study was to recycle dredged sediments as an alternative raw material in the production of ceramic tiles. The effect of the substitution of kaolin by raw sediment (HDS) and calcined sediment (HDSC) in the mixture of the ceramic tile samples sintered at 1100 and 1200 °C was studied. The samples were prepared with different proportions of HDS and HDSC (0, 10, 20 and 30 wt.%) substituting kaolin. The mineralogical analysis of the samples shows that mullite phase disappears in the samples incorporating raw sediments (HDS) and fired sediments (HDSC) leading to the formation of new crystalline phases such as anorthite and diopside.Moreover, ceramic tile samples with 20 wt.% of calcined sediment improve its densification and hence the compressive strength (171 MPa) and thermal conductivity (0.555 W/mK). An evaluation of the leaching was carried out in the ceramic samples, finding that the concentrations of heavy metals in the leachate were within the safety limit established by the USEPA. The heavy metals were immobilised in the ceramic matrix. Therefore, the results showed that dredged sediment (HDS) and calcined sediment (HDSC) could be used as substituent of kaolin to produce eco-friendly ceramic building materials as floor tile ceramics.

The relationship between aesthetic preferences of people for ceramic tile design and neural responses: An event-related potential study.

Introduction: The aesthetic preferences of people can determine the success of a design and are often closely related to design features. The discovery of designs that match user preferences can provide a reference for designers. Ceramic tiles are widely used in environmental design; however, little attention has been paid to the aesthetic preferences of people for tiles. This study aimed to explore the relationship between aesthetic preferences for tile design and neural responses. Materials and methods: In this study, two groups of tiles with different preference levels were randomly presented to 16 participants, and their electroencephalograms were recorded. The mean amplitudes of event-related potentials were analyzed by ANOVA. Results: The results showed that: (1) the aesthetic preferences of people for tiles could modulate brain activity; (2) tiles that people liked triggered higher N100 amplitudes; and (3) tiles that people disliked triggered higher P200 and late positive potential (LPP) amplitudes. Discussion: These results suggest that N100, P200, and LPP are significantly related to the aesthetic preferences of people for ceramic tiles. The difference in N100 and P200 amplitudes indicates that participants developed aesthetic perceptions of the tiles in the early and middle stages of vision and formed different attention allocations to tiles with varying levels of aesthetic preference; in the middle and late stages of visual processing, the difference in the LPP amplitude indicates that the impression of people for tiles is further deepened in the later stage, forming a top-down emotion-driven evaluation. Exploring the relationship between the aesthetic preferences of people and neural responses is significant in establishing objective aesthetic judgment indicators for tiles and understanding the process of aesthetic cognition. This study provides relevant information for quantitative aesthetic assessments of environmental design, interior design, and marketing involving ceramic tiles.

Ricochet of AK bullets (7.62 MM X 39 MM) on glazed ceramic tiles: An empirical study in support of shooting incident reconstructions.

Indoor environments provide numerous hard surfaces and nearby objects which facilitate the shots fired to ricochet off and hit victims. Out of many surface types, ceramic tile surfaces are considered to be one of the most commonly available and encountered surface type in indoor shootings. However, no studies had attempted to understand the ricochet behaviour and surface evidence of ceramic tiles with any bullet type. This study explores the ricochet behaviour of one of the most commonly reported bullet type in recent shooting incidents; AK bullets (7.62 mm × 39 mm/ M43) on two glazed ceramic tile samples used for indoor walls and flooring. The study's results present the critical angles of glazed ceramic floor and wall tile samples along with a few significant and currently not reported ricochet-surface mark characteristics with greater forensic significance for use in AK gun-related ricochet investigations. This study further emphasises the need for case-by-case empirical approaches to understanding the ricochet behaviour of different bullet-target combinations during ricochet investigations. The study also opens up a new research area to explore whether the observed results are common to steel core AK bullets or common to other ammunition types and tile surfaces with different compositions.

Advances in Nanoarchitectonics of Antimicrobial Tiles and a Quest for Anti-SARS-CoV-2 Tiles.

Design of antimicrobial tiles seems necessary to combat against contagious diseases, especially COVID-19. In addition to personal hygiene, this technology facilitates public hygiene as antimicrobial tiles can be installed at hospitals, schools, banks, offices, lobbies, railway stations, etc. This review is primarily focused on preparing antimicrobial tiles using an antimicrobial layer or coatings that fight against germs. The salient features and working mechanisms of antimicrobial tiles are highlighted. This challenge is a component of the exploratory nature of nanoarchitectonics, that also extends farther than the realm of nanotechnology. This nanoarchitectonics has been successful at the laboratory scale as antimicrobial metal nanoparticles are mainly used as additives in preparing tiles. A detailed description of various materials for developing unique antimicrobial tiles is reported here. Pure metal (Ag, Zn) nanoparticles and a mixture of nanoparticles with other inorganic materials (SiO2,, TiO2, anatase, nepheline) have been predominantly used to combat microbes. The developed antimicrobial tiles have shown excellent activity against a wide range of Gram-positive and Gram-negative bacteria. The last section discussed a hypothetical overview of utilizing the antimicrobial tiles against SARS-CoV-2. Overall, this review gives descriptive knowledge about the importance of antimicrobial tiles to create a clean and sustainable environment.

Recycling of ceramic tiles waste and marble waste in sustainable production of concrete: a review.

Currently, recycling of waste materials in construction is being considered very important because waste generation is posing serious threats to our living environment. Hence, to induce sustainability in the ongoing urban development, researchers around the globe are using numerous wastes in concrete as partial substitutes of binders (cement, lime, etc.) and fillers (fine and coarse aggregates) with the aim of reducing the depletion of natural resources and cutting the carbon dioxide emissions emerging from increased demand and production of cement. This review paper has summarized the findings of literature relating to recycling of marble wastes and ceramic tiles wastes in production of concrete. The physical, fresh-state, and strength properties of concrete were reviewed from available extensive literature, and it was found that the concrete prepared from marble waste and ceramic waste as partial substitution of cement and aggregates is expected to perform at least comparable to conventional cement concrete and better if applicable. Both marble wastes and ceramic tiles wastes can be incorporated and recycled in concrete as cementitious materials and aggregate replacing materials. With such approach, the concrete can be made strong and durable, and the issues relating to depletion of natural resources and environmental degradation can also be solved without compromising sustainability in infrastructure development.

Redispersible polymer powder modified cementitious tile adhesive as an alternative to ordinary cement-sand grout.

With the advent of technologies on modern structural and building materials, adaptation of such technological features has been the pivotal concern of researchers. Ceramic tiles attained a distinctive focus due to its decorative feature for both indoor and outdoor conditions and also for their ease of implementation. The purpose of exploiting ceramic tiles is not only to impart structural strength but also the aesthetical characteristics that seem to matter a great deal. When it comes to the adhesion of these tiles onto the substrate wall, traditional method exerts the use of sand-cement grout. This faces some drawbacks including poor water retention property, hard and brittleness of the surface, much higher drying time, no flexibility, higher thickness of the paste and so on. These difficulties can be overcome by the addition of redispersible polymer powder (RPP) along with other cementitious constituents. The blended polymers interact with cement components to improve the physical and mechanical properties such as increased adhesion strength, reduced shrinkage and lower water absorption. This review article made an effort to provide the generalized idea about the cementitious tile adhesive (CTA) and its components. Focus was made onto the commercially available RPP and formulation of CTA with the inclusion of RPP. Critical analysis of the repercussions of RPP fortification was also carried out based on different researcher's findings.

New Clayey Deposit and Their Potential as Raw Material for Red or Structured Ceramics: Technological Characterization.

Mineralogical and technological characterization of ceramic raw materials from a new deposit located at Caxias city, Maranhão State-Brazil, was accomplished to determine their potential as raw materials for the ceramics industry in northeastern Brazil. The ceramic raw materials were collected from three different locations on the site and characterized by X-ray fluorescence (XRF), X-ray diffraction (XRD), differential thermal analysis (DTA), and thermogravimetry (TG). The XRF analysis of the fraction < 2 µm revealed that most samples had SiO2 (35-51 wt%), Al2O3 (19-29 wt%), Fe2O3 (2-21 wt%), MgO (0.7 to 4.5 wt%) and K2O (0.9 to 5 wt%) as components. Quartz, kaolinite, illite, hematite and montmorillonite were the main mineral phases identified. DTA and TG analysis confirmed the mineral identification. The technological potential of the ceramic raw materials was investigated by: cation exchange capacity (CEC), plastic behavior (Atterberg Limits), linear shrinkage at 950 °C (LSF), flexural strength (FS), apparent porosity (AP), water absorption (WA) and bulk density (BD). The main experimental results-WA (9-17%), AP (19-31%), FS (2.0-23 MPa), and the Atterberg limits-indicated that the ceramic raw materials investigated have high potential to be used to develop mass for red or structured ceramics, such as bricks and roof tiles.

What Makes a Floor Slippery? A Brief Experimental Study of Ceramic Tiles Slip Resistance Depending on Their Properties and Surface Conditions.

The safety of the use of construction facilities should be a priority in today's busy world, where it is not difficult to get involved in an accident. Most of them, due to the pace at which we live today, are caused by slips, trips, and falls. This work presents a detailed analysis of the resistance of ceramic floors to these events, taking into account the surface properties and conditions (dry/wet), which, as presented, have a significant impact on the final slip resistance values. This study also investigates the relationship between surface roughness and anti-slip properties. According to the obtained results, it can be concluded that the surface roughness is not the main determinant of slip resistance, and the final value of it is influenced by many components that should be considered together and not be neglected when designing the surface finish. Furthermore, based on experimental measurements, it can be noted that the highest slip resistance in both wet and dry conditions showed the unglazed tiles with lapatto finish and the glazed tiles without any extra finish.

Preliminary Studies of the Durability of Tools Used to Form Ceramic Tiles Made of Hardox 600 and NC11LV Steel.

The study performs a comparative analysis of the wear of tools made of two wear-resistant materials: steel Hardox 600 and NC11LV, used in the process of forming a band for roofing tiles. The analyses were to allow the assessment of the possibility of replacing the standard material for tools in this process with a much less expensive tool steel for cold work after heat treatment (with a large number of carbides), as an alternative material dedicated to tools resistant to intense abrasive wear. The performed investigations included a macroscopic and geometrical analysis with the use of 3D scanning, microstructural analyses conducted by means of a light microscope, as well as an analysis of the topography of the working areas of the tools with the use of SEM, and microhardness tests. The obtained results demonstrate that the tools made of both materials were characterized with a similar level of wear, which, in the most critical area, reached over 4 mm, while the tools made of steel NC11LV worked over a much longer period of time without regeneration, equaling 912 h, and an insert made of steel Hardox 600 operated for 384 h. A higher tool life in the case of NC11LV steel may be the result of higher hardness and the presence of hard carbides.

Interlaboratory Comparison as a Source of Information for the Product Evaluation Process. Case Study of Ceramic Tiles Adhesives.

In this study, the results obtained by 19 laboratories participating in 2 editions of the interlaboratory comparison (ILC) determining 2 properties of ceramic tiles adhesives (CTAs), i.e., initial tensile adhesion strength and tensile adhesion strength after water immersion following EN 12004, were analyzed. The results show that participating laboratories maintain a constant quality of their work. The use of z-score analysis, under ISO 13528, allows for classifying 89.5% to 100% of laboratories as satisfactory, depending on the measurement's kind and edition. The remaining laboratories are classified as questionable. The investigation of the predominant mode of failure of the CTA's samples tested in the two editions shows significant differences. From the perspective of laboratories, the goal of the ILC has been achieved. From the standpoint of a manufacturer who evaluates a product's properties when placing it on the market, the results indicate the necessity of a particular treatment of the product evaluation process because the variability of the obtained results is significant. It increases the possibility of the product failing to meet the assessment criteria verified by the construction market supervision authorities. The manufacturer must consider all possible variations in the risk analysis, including the ILC results, to improve the assessment process of CTAs.

Automated Control of Surface Defects on Ceramic Tiles Using 3D Image Analysis.

This paper presents a method of acquisition and analysis of three-dimensional images in the task of automatic location and evaluation of defects on the surface of ceramic tiles. It presents a brief description of selected defects appearing on the surface of tiles, along with the analysis of their formation. The paper includes the presentation of the method of constructing a 3D image of the tile surface using the Laser Triangulation Method (LTM), along with the surface imaging parameters employed in the research. The algorithms of three-dimensional surface image analysis of ceramic tiles used in the process of image filtering and defect identification are presented. For selected defects, the method of measuring defect parameters and the method of visualization of defects on the surface are also presented. The developed method was tested on defective products to confirm its effectiveness in the field of quick defect detection in automated control systems installed on production lines.

Pilot scale thin film plate reactors for the photocatalytic treatment of sugar refinery wastewater.

Pilot scale thin film plate reactors (TFPR) were fabricated to study the solar photocatalytic treatment of wastewater obtained from the secondary treatment plant of a sugar refinery. Silver-impregnated titanium dioxide (TiO2) was prepared by a facile chemical reduction method, characterized, and immobilized onto the surface of ceramic tiles used in the pilot scale reactors. On 8 h of solar irradiation, percentage reduction of chemical oxygen demand (COD) of the wastewater by Ag/TiO2, pure TiO2, and control (without catalyst) TFPR was about 95, 86, and 22 % respectively. The effects of operational parameters such as, flow rate, pH, and addition of hydrogen peroxide (H2O2) were optimized as they influence the rate of COD reduction. Under 3 h of solar irradiation, 99 % COD reduction was observed at an optimum flow rate of 15 L h(-1), initial pH of 2, and addition of 5 mM of H2O2. The results show that Ag/TiO2 TFPR could be effectively used for the tertiary treatment of sugar refinery effluent using sunlight as the energy source. The treated water could be reused for industrial purposes, thus reducing the water footprint of the industry. Graphical Abstract Sugar refinery effluent treatment by solar photocatalytic TFPR.

Laser Treatment of Nanoparticulated Metal Thin Films for Ceramic Tile Decoration.

This paper presents a new method for the fabrication of metal-like decorative layers on glazed ceramic tiles. It consists of the laser treatment of Cu thin films prepared by electron-beam evaporation at glancing angles. A thin film of discontinuous Cu nanoparticles was electron-beam-evaporated in an oblique angle configuration onto ceramic tiles and an ample palette of colors obtained by laser treatment both in air and in vacuum. Scanning electron microscopy along with UV-vis-near-IR spectroscopy and time-of-flight secondary ion mass spectrometry analysis were used to characterize the differently colored layers. On the basis of these analyses, color development has been accounted for by a simple model considering surface melting phenomena and different microstructural and chemical transformations of the outmost surface layers of the samples.