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1.
Glob Chang Biol ; 30(5): e17333, 2024 May.
Article in English | MEDLINE | ID: mdl-38798169

ABSTRACT

Plant metabolites significantly affect soil nitrogen (N) cycling, but their influence on nitrous oxide (N2O) emissions has not been quantitatively analyzed on a global scale. We conduct a comprehensive meta-analysis of 173 observations from 42 articles to evaluate global patterns of and principal factors controlling N2O emissions in the presence of root exudates and extracts. Overall, plant metabolites promoted soil N2O emissions by about 10%. However, the effects of plant metabolites on N2O emissions from soils varied with experimental conditions and properties of both metabolites and soils. Primary metabolites, such as sugars, amino acids, and organic acids, strongly stimulated soil N2O emissions, by an average of 79%, while secondary metabolites, such as phenolics, terpenoids, and flavonoids, often characterized as both biological nitrification inhibitors (BNIs) and biological denitrification inhibitors (BDIs), reduced soil N2O emissions by an average of 41%. The emission mitigation effects of BNIs/BDIs were closely associated with soil texture and pH, increasing with increasing soil clay content and soil pH on acidic and neutral soils, and with decreasing soil pH on alkaline soils. We furthermore present soil incubation experiments that show that three secondary metabolite types act as BNIs to reduce N2O emissions by 32%-45%, while three primary metabolite classes possess a stimulatory effect of 56%-63%, confirming the results of the meta-analysis. Our results highlight the potential role and application range of specific secondary metabolites in biomitigation of global N2O emissions and provide new biological parameters for N2O emission models that should help improve the accuracy of model predictions.


Subject(s)
Nitrous Oxide , Plants , Soil , Nitrous Oxide/analysis , Nitrous Oxide/metabolism , Soil/chemistry , Plants/metabolism , Plants/chemistry , Nitrification , Denitrification
2.
Sensors (Basel) ; 24(11)2024 May 31.
Article in English | MEDLINE | ID: mdl-38894347

ABSTRACT

One challenge in predicting soil parameters using in situ visible and near infrared spectroscopy is the distortion of the spectra due to soil moisture. External parameter orthogonalization (EPO) is a mathematical method to remove unwanted variability from spectra. We created two different EPO correction matrices based on the difference between spectra collected in situ and, respectively, spectra collected from the same soil samples after drying and sieving and after drying, sieving and finely grinding. Spectra from 134 soil samples recorded with two different spectrometers were split into calibration and validation sets and the two EPO corrections were applied. Clay, organic carbon and total nitrogen content were predicted by partial least squares regression for uncorrected and EPO-corrected spectra using models based on the same type of spectra ("within domain") as well as using laboratory-based models to predict in situ collected spectra ("cross-domain"). Our results show that the within-domain prediction of clay is improved with EPO corrections only for the research grade spectrometer, with no improvement for the other parameters. For the cross-domain predictions, there was a positive effect from both EPO corrections on all parameters. Overall, we also found that in situ collected spectra provided an equally successful prediction as laboratory-based spectra.

3.
Glob Chang Biol ; 28(15): 4589-4604, 2022 08.
Article in English | MEDLINE | ID: mdl-35543517

ABSTRACT

The structure of soil aggregates plays an important role for the turnover of particulate organic matter (POM) and vice versa. Analytical approaches usually do not disentangle the continuous re-organization of soil aggregates, caught between disintegration and assemblage. This led to a lack of understanding of the mechanistic relationship between aggregation and organic matter dynamics in soils. In this study, we took advantage of a process-based mechanistic model that describes the interaction between the dynamic (re-)arrangement of soil aggregates, based on dynamic image analysis data of wet-sieved aggregates, to analyze the turnover of POM, and simultaneous soil surface interactions in a spatially and temporally explicit way. Our novel modeling approach enabled us to unravel the temporal development of aggregate sizes, organic carbon (OC) turnover of POM, and surface coverage as affected by soil texture, POM input, and POM decomposition rate comparing a low and high clay soil (18% and 33% clay content). Our results reveal the importance of the dynamic re-arrangement of soil structure on POM-related turnover of OC in soils. Firstly, aggregation was largely determined by the POM input fostering aggregates through additional gluing joints outweighing soil texture at lower decomposition rate, whereas at higher decomposition rate, soil texture had a higher influence leading to larger aggregates in the high clay soil. Secondly, the POM storage increased with clay content, showing that surface interactions may delay the turnover of OC into CO2 . Thirdly, we observed a structural priming effect in which the increased input of POM induced increased structural re-arrangement stimulating the mineralization of old POM. This work highlights that the dynamic re-arrangement of soil aggregates has important implications for OC turnover and is driven by underlying surface interactions where temporary gluing spots stabilize larger aggregates.


Subject(s)
Carbon , Soil , Carbon/chemistry , Clay , Soil/chemistry
4.
Glob Chang Biol ; 27(19): 4921-4934, 2021 10.
Article in English | MEDLINE | ID: mdl-34228862

ABSTRACT

The ratio of soil organic carbon stock (SOC) to annual carbon input gives an estimate of the mean residence time of organic carbon that enters the soil (MRTOC ). It indicates how efficiently biomass can be transformed into SOC, which is of particular relevance for mitigating climate change by means of SOC storage. There have been few comprehensive studies of MRTOC and their drivers, and these have mainly been restricted to the global scale, on which climatic drivers dominate. This study used the unique combination of regional-scale cropland and grassland topsoil (0-30 cm) SOC stock data and average site-specific OC input data derived from the German Agricultural Soil Inventory to elucidate the main drivers of MRTOC . Explanatory variables related to OC input composition and other soil-forming factors were used to explain the variability in MRTOC by means of a machine-learning approach. On average, OC entering German agricultural topsoils had an MRT of 21.5 ± 11.6 years, with grasslands (29.0 ± 11.2 years, n = 465) having significantly higher MRTOC than croplands (19.4 ± 10.7, n = 1635). This was explained by the higher proportion of root-derived OC inputs in grassland soils, which was the most important variable for explaining MRTOC variability at a regional scale. Soil properties such as clay content, soil group, C:N ratio and groundwater level were also important, indicating that MRTOC is driven by a combination of site properties and OC input composition. However, the great importance of root-derived OC inputs indicated that MRTOC can be actively managed, with maximization of root biomass input to the soil being a straightforward means to extend the time that assimilated C remains in the soil and consequently also increase SOC stocks.


Subject(s)
Carbon , Soil , Agriculture , Carbon Sequestration
5.
Sensors (Basel) ; 19(18)2019 Sep 12.
Article in English | MEDLINE | ID: mdl-31547310

ABSTRACT

Most cultivated upland areas of northeast Thailand are characterized by sandy and infertile soils, which are difficult to improve agriculturally. Information about the clay (%) and cation exchange capacity (CEC-cmol(+)/kg) are required. Because it is expensive to analyse these soil properties, electromagnetic (EM) induction instruments are increasingly being used. This is because the measured apparent soil electrical conductivity (ECa-mS/m), can often be correlated directly with measured topsoil (0-0.3 m), subsurface (0.3-0.6 m) and subsoil (0.6-0.9 m) clay and CEC. In this study, we explore the potential to use this approach and considering a linear regression (LR) between EM38 acquired ECa in horizontal (ECah) and vertical (ECav) modes of operation and the soil properties at each of these depths. We compare this approach with a universal LR relationship developed between calculated true electrical conductivity (σ-mS/m) and laboratory measured clay and CEC at various depths. We estimate σ by inverting ECah and ECav data, using a quasi-3D inversion algorithm (EM4Soil). The best LR between ECa and soil properties was between ECah and subsoil clay (R2 = 0.43) and subsoil CEC (R2 = 0.56). We concluded these LR were unsatisfactory to predict clay or CEC at any of the three depths, however. In comparison, we found that a universal LR could be established between σ with clay (R2 = 0.65) and CEC (R2 = 0.68). The LR model validation was tested using a leave-one-out-cross-validation. The results indicated that the universal LR between σ and clay at any depth was precise (RMSE = 2.17), unbiased (ME = 0.27) with good concordance (Lin's = 0.78). Similarly, satisfactory results were obtained by the LR between σ and CEC (Lin's = 0.80). We conclude that in a field where a direct LR relationship between clay or CEC and ECa cannot be established, can still potentially be mapped by developing a LR between estimates of σ with clay or CEC if they all vary with depth.

6.
J Sci Food Agric ; 97(8): 2633-2640, 2017 Jun.
Article in English | MEDLINE | ID: mdl-27748529

ABSTRACT

BACKGROUND: The influence of global warming on grape quality is a great concern among grapegrowers and enologists. The effects of simulated year 2100 expected CO2 , temperature and relative humidity (RH) conditions (FCC; 700 µmol CO2 mol-1 air, 28/18 °C day/night and 33/53% RH, day/night) versus the current situation (Curr; 390 µmol CO2 mol-1 air, 24/14 °C and 45/65% RH); well-irrigated versus expected future water deficit and three soils with different clay contents (41, 19 and 8%) on yield and berry quality of grapevine cv. Tempranillo were evaluated. RESULTS: FCC shortened the time between fruit set and veraison and between fruit set and maturity by up to 7 and 10 days, respectively. This faster maturity led to higher must pH and tonality and reduced malic and tartaric acid concentrations, total anthocyanin concentration and colour intensity. Water deficit delayed ripeness for up to 9 days and reduced vegetative growth and malic acid concentration of grapes. However, this malic acid reduction did not occur with the clayey soils. These soils induced the lowest root fresh weight and berries with lower total anthocyanin concentration. CONCLUSION: Among the adaptation techniques to cope with the described effects on fruit composition, soil selection should be considered with attention in addition to irrigation practices. © 2016 Society of Chemical Industry.


Subject(s)
Fruit/chemistry , Soil/chemistry , Vitis/chemistry , Anthocyanins/analysis , Climate Change , Fruit/growth & development , Malates/analysis , Quality Control , Temperature , Vitis/growth & development , Wine/analysis
7.
Heliyon ; 9(6): e17618, 2023 Jun.
Article in English | MEDLINE | ID: mdl-37408898

ABSTRACT

Water retention in earthen fishponds throughout a fish farming cycle is challenging due to climate-induced water loss via evapotranspiration, seepages, and lowering of the groundwater table. These processes depend on the soil hydrostratigraphic condition and constitute a major challenge for fish farmers in the Niger-Delta region of Nigeria, where seasonal variations cause groundwater levels to fluctuate. This study assesses the use of non-invasive geophysical methods, including electrical resistivity and induced polarization, to guide the selection of sites with appropriate hydrostratigraphic conditions for establishing earthen fishponds. We combined measurements of electrical resistivity and chargeability distributions to assess the subsurface of two earthen fishpond sites at Ugono-Abraka and Agbarha-Otor areas in the Niger-Delta region of Nigeria. Electrical soundings were acquired at ten locations, while two-dimensional electrical resistivity and Induced polarization were acquired across five transects using Schlumberger and dipole-dipole electrode configurations. The field data were inverted using IP2win, and Diprowin software. The geophysical models were combined with lithological data from soil cores to characterize the subsurface stratigraphy, while measured clay contents were used to estimate infiltration coefficients relying on established petrophysical relationships. The delineated subsurface properties at Ugono-Abraka and Agbarha-Otor show higher variations than assumed by practitioners. The complementary results of low resistivity (20-140 Ωm) and high chargeability (10-50 msec) revealed areas with clay-rich sediments. Soil samples confirmed higher clay contents of up to 10% at Ugono-Abraka and low values of 2% at Agbarha-Otor. Estimated infiltration coefficients are lower at the Ugono-Abraka site (1.6 m/day) compared to Agbarha-Otor (8.4 m/day). This implies variable water loss in the earthen fishponds; hence, we recommend characterizing these variations using non-invasive geophysical methods before establishing medium to large-scale earthen fishponds in the area.

8.
NanoImpact ; 28: 100433, 2022 10.
Article in English | MEDLINE | ID: mdl-36273810

ABSTRACT

Hazard assessment of silver nanoparticles is crucial as their presence in agricultural land is increasing through sewage sludge application. This study compared the uptake and elimination kinetics in the annelid Enchytraeus crypticus of AgNPs with different core sizes and coatings in Lufa 2.2 soil, and of Ag2S NPs (simulating aged AgNPs) in three different soils. For both experiments, AgNO3 was used as ionic control. E. crypticus was exposed to soil spiked at 10 µg Ag g-1 dry soil for 14 days and then transferred to clean soil for a 14-day elimination phase. The uptake rate constants were similar for 3-8 nm and 60 nm AgNPs and AgNO3, but significantly different between 3 and 8 nm and 50 nm AgNPs. The uptake kinetics of Ag from Ag2S NPs did not significantly differ compared to pristine AgNPs. Therefore, Ag bioavailability was influenced by AgNP form and characteristics. Uptake and elimination rate constants of both Ag forms (AgNO3 and Ag2S NPs) significantly differed between different test soils (Lufa 2.2, Dorset, and Woburn). For AgNO3, significantly higher uptake and elimination rate constants were found in the Dorset soil compared to the other soils, while for Ag2S NPs this soil showed the lowest uptake and elimination rate constants. Therefore, not only the form and characteristics but also soil properties affect the bioavailability and uptake of Ag nanoparticles.


Subject(s)
Metal Nanoparticles , Soil , Silver , Physics
9.
Ying Yong Sheng Tai Xue Bao ; 33(11): 3037-3045, 2022 Oct.
Article in Zh | MEDLINE | ID: mdl-36384838

ABSTRACT

Nuclear magnetic resonance (NMR) technology has been applied in soil science due to the characte-ristics of high efficiency, rapidity, no damage to soil structure, and harmlessness to the human body. However, the effect of the presence of paramagnetic materials in soils on the characteristics of NMR signals was still unclear. In this study, we investigated the effects of paramagnetic material on the low field nuclear magnetic (LF-NMR) signals and soil water content measurement in soils with different texture. The results showed that the LF-NMR signal of soil water could reach about 150, while that of all the solid materials including soil minerals, organic matter and microbes was less than 0.3, which was relatively negligible. Compared with the NMR signals produced by solid materials in soils, soil texture and paramagnetic material had stronger impact on the measured LF-NMR signals of soil water. LF-NMR equipment had a relaxation time monitoring blind area, and the loss of NMR signal was mainly due to the acceleration of the relaxation process of hydrogen protons in water by magnetic materials, resulting in extremely fast LF-NMR signals feed back by water in small pores that could not be captured by monitoring equipment. For loamy fluvo-aquic soil (1.2%) and clay loamy black soil (1.3%) with low paramagnetic material contents, the loss of LF-NMR signals was not large, which was linearly related to soil water content. For clayey red soil with high content of clay (45.3%) and paramagnetic materials (4.0%), a part of the LF-NMR signals would be lost in the measurement, and the monitored LF-NMR signal was not linearly related to the soil water content. In addition, external addition of paramagnetic materials (3.0 g·L-1 MnCl2 solution) would further reduce the LF-NMR signals that could be monitored in black and red soils. The maximum signal loss rates of black soil and red soil were 41.0% and 46.7%, respectively, which greatly changed the quantitative relationship between it and soil water content. Therefore, the influence of paramagnetic materials on the LF-NMR signals should be reduced first through correction when using LF-NMR to measure the water content of clay soil with rich internal paramagnetic materials (>1.3%) or external addition of paramagnetic materials. Our results would provide valuable insights into the study of soil water content measurement and soil pore structure analysis using low field nuclear magnetic resonance technology.


Subject(s)
Soil , Water , Humans , Water/analysis , Clay , Magnetic Resonance Spectroscopy/methods , Magnetics
10.
Sci Total Environ ; 838(Pt 4): 156528, 2022 Sep 10.
Article in English | MEDLINE | ID: mdl-35688244

ABSTRACT

The 15N natural abundance is an effective indicator of nitrogen dynamics in plants. The impact of different irrigation regimes as a function of varied soil clay contents on stable nitrogen isotope abundance (δ15N) in rice remains unknown. Therefore, the response of δ15N and nitrogen utilization efficiency (NUE) of rice to different combinations of alternate wetting and drying irrigation (AWD) and clay contents were investigated. The study included three AWD regimes, viz. I100, (100 % saturation, 30 mm flooded), I90 (90 % saturation, 30 mm flooded) and I70 (70 % saturation, 30 mm flooded), and three soil clay content treatments, viz. 40 % (S40), 50 % (S50), and 60 % (S60) clay content. Compared with I100, I90 and I70 with high clay content (S60) significantly increased the crack volumes and N leaching losses and reduced the total N accumulation and different forms of NUE of rice plants. The values of δ15N in above-ground organs and soil were greatly increased by I90 and I70 irrigation regimes compared to I100. An increasing trend of organs δ15N from root to shoot was found for all three irrigation regimes. Significant negative relationships were found between (i) N partial factor productivity (PFP) and grain 15N, (ii) PFP and leaf 15N, and (iii) N harvest index (NHI) and leaf 15N. These significant negative relationships might contribute to the increased N losses and changed N allocation under AWD with high clay contents. Hence, it is suggested that cracks should be taken into consideration in rice cultivation. Moreover, δ15N may serve as an effective indicator of NUE in rice grown under AWD irrigation with high clay contents as well as an indirect indicator for assessing the N loss in agro-ecosystems.


Subject(s)
Oryza , Soil , Agricultural Irrigation , Clay , Ecosystem , Nitrogen , Oryza/physiology , Water
11.
Front Plant Sci ; 13: 1077152, 2022.
Article in English | MEDLINE | ID: mdl-36531393

ABSTRACT

Natural abundance of the stable isotope (δ13C and δ15N) in plants is widely used to indicate water use efficiency (WUE). However, soil water and texture properties may affect this relationship, which remains largely elusive. Therefore, the purpose of this study was to evaluate δ13C as affected by different combinations of alternate wetting and drying irrigation (AWD) with varied soil clay contents in different organs and whole plant and assess the feasibility of using δ13C and δ15N as a physiological indicator of whole-plant water use efficiency (WUEwhole-plant). Three AWD regimes, I100 (30 mm flooded when soil reached 100% saturation), I90 (30 mm flooded when reached 90% saturation) and I70 (30 mm flooded when reached 70% saturation) and three soil clay contents, 40% (S40), 50% (S50), and 60% (S60), were included. Observed variations in WUEwhole-plant did not conform to theoretical expectations of the organs δ13C (δ13Corgans) of plant biomass based on pooled data from all treatments. However, a positive relationship between δ13Cleaf and WUEET (dry biomass/evapotranspiration) was observed under I90 regime, whereas there were no significant relationships between δ13Corgans and WUEET under I100 or I70 regimes. Under I100, weak relationships between δ13Corgans and WUEET could be explained by (i) variation in C allocation patterns under different clay content, and (ii) relatively higher rate of panicle water loss, which was independent of stomatal regulation and photosynthesis. Under I70, weak relationships between δ13Corgans and WUEET could be ascribed to (i) bigger cracks induced by water-limited irrigation regime and high clay content soil, and (ii) damage caused by severe drought. In addition, a negative relationship was observed between WUEwhole-plant and shoot δ15N (δ15Nshoot) across the three irrigation treatments, indicating that WUEwhole-plant is tightly associated with N metabolism and N isotope discrimination in rice. Therefore, δ13C should be used cautiously as an indicator of rice WUEwhole-plant at different AWD regimes with high clay content, whereas δ15N could be considered an effective indicator of WUEwhole-plant.

12.
Data Brief ; 32: 106147, 2020 Oct.
Article in English | MEDLINE | ID: mdl-32904338

ABSTRACT

Soil microbial biomass carbon (SMBC) is important in regulating soil organic carbon (SOC) dynamics along soil profiles by mediating the decomposition and formation of SOC. The dataset (VDMBC) is about the vertical distributions of SOC, SMBC, and soil microbial quotient (SMQ = SMBC/SOC) and their relations to environmental factors across five continents. Data were collected from literature, with a total of 289 soil profiles and 1040 observations in different soil layers compiled. The associated environment data collectd include climate, ecosystem types, and edaphic factors. We developed this dataset by searching the Web of Sciene and the China National Knowledge Infrastructure from the year of 1970 to 2019. All the data in this dataset met two creteria: 1) there were at least three mineral soil layers along a soil profile, and 2) SMBC was measured using the fumigation extraction method. The data in tables and texts were obtained from literature directly, and the data in figures were extracted by using the GetData Graph digitizer software version 2.25. When climate and soil properties were not available from publications, we obtainted the data from the World Weather Information Service (https://worldweather.wmo.int/en/home.html) and SoilGrids at a spatial resolution of 250 meters (version 0.5.3, https://soilgrids.org). The units of all the variables were converted to the standard international units or commonly used ones and the values were transformed correspondingly. For example, the value of soil organic matter (SOM) was converted to SOC by using the equation (SOC = SOM × 0.58). This dataset can be used in predicting global SOC changes along soil profiles by using the multi-layer soil carbon models. It can also be used to analyse how soil microbial biomass changes with plant roots as well as the composition, structure, and functions of soil microbial communities along soil profiles at large spatial scales. This dataset offers opportunities to improve our prediction of SOC dynamics under global changes and to advance our understanding of the environmental controls.

13.
Ying Yong Sheng Tai Xue Bao ; 30(2): 370-378, 2019 Feb 20.
Article in Zh | MEDLINE | ID: mdl-30915786

ABSTRACT

To explore the effects of small watersheds with different ecological managements on soil properties, the spatial differences of soil organic matter (SOM), bulk density (BD), and clay content (CC) in the four facets, including slope aspect, slope position, zone, and soil layer, were analyzed between Yangjiagou (YJG, artificial Robinia pseudoacacia forest watershed) and Dongzhuanggou (DZG, closed grassland watershed). The results showed that SOM, BD and CC were 12.78 g·kg-1, 1.24 g·cm-3, 19.2% for YJG and 11.13 g·kg-1, 1.21 g·cm-3, 18.2% for DZG, respectively. The values for YJG were slightly higher than those for DZG, but the difference was insignificant. All indices in the east slope were bigger than those in the west slope. Across different slope positions, the variation of BD was small, SOM and CC showed increasing trends from top to bottom. BD and CC declined downward the watershed, whereas SOM changed in an opposite trend. From the soil surface down to 60 cm soil depth, BD and CC increased and SOM decreased. The spatial sensitivity followed CC > SOM > BD, and the effects of the spatial factors can be ordered as soil layer > zone > slope aspect > slope position. There were significant differences in CC of the upper reaches, BD and CC of the middle reaches between the two basins. The sensitivity of each index to slope position, zone and soil layer in YJG was lower than that in DZG.


Subject(s)
Clay , Soil , China , Ecosystem , Forests
14.
R Soc Open Sci ; 5(5): 172270, 2018 May.
Article in English | MEDLINE | ID: mdl-29892411

ABSTRACT

Sand moulds are used in the casting process. However, after heating, the binder in the sand loses the binding properties, and the most part of the foundry sand has to be discarded from the process. The waste foundry sand after the regeneration can be recycled, and reclamation can reduce the production cost and lower waste emissions. The objective of this work was to investigate the possibility of reusing the animal glue binder waste foundry sand from the study of three regeneration methods. Studies with the waste foundry sand and reclaimed sand were performed in order to compare the results obtained with raw sand. The characterization of the samples was performed by scanning electron microscopy and energy dispersive spectroscopy. Results show that the waste sand was regenerated by mechanical regeneration, thermal regeneration and wet reclamation, respectively. The reclaimed sands have a better performance than the waste foundry sand, and are similar to raw sand. Further, the wet regeneration method is the best one among the three methods.

15.
Chemosphere ; 151: 220-4, 2016 May.
Article in English | MEDLINE | ID: mdl-26943743

ABSTRACT

The toxicity test using freshwater ostracods of the species Heterocypris incongruens is a sub-chronic static test that exposes individuals to whole sediments over a period of 6 d, the endpoints being mortality and growth. We tested the hypothesis that endpoints of the sediment bioassay using Heterocypris incongruens are affected by the presence of fine sediment particles by testing control sediment supplied with the commercial test kit with increasing proportions of kaolin clay as a proxy for fines. While mortality was not affected, the results showed that increasing the presence of clay reduced ostracod growth. Based on the variability in growth, a sublethal toxicity threshold of 35% is proposed to distinguish effects due to sediment properties from those due to toxicity. The relevance of this threshold was verified using data from toxicity tests of ambient sediment samples with low levels of contamination.


Subject(s)
Biological Assay/methods , Crustacea/drug effects , Ecotoxicology/methods , Geologic Sediments/chemistry , Toxicity Tests/methods , Animals
16.
Sci Total Environ ; 524-525: 148-56, 2015 Aug 15.
Article in English | MEDLINE | ID: mdl-25897723

ABSTRACT

The high variability of the soil-to-plant transfer factor of radiocaesium (RCs) compels a detailed analysis of the radiocaesium interception potential (RIP) of soil, which is one of the specific factors ruling the RCs transfer. The range of the RIP values for agricultural soils in the Fukushima accident affected area has not yet been fully surveyed. Here, the RIP and other major soil chemical properties were characterised for 51 representative topsoils collected in the vicinity of the Fukushima contaminated area. The RIP ranged a factor of 50 among the soils and RIP values were lower for Andosols compared to other soils, suggesting a role of soil mineralogy. Correlation analysis revealed that the RIP was most strongly and negatively correlated to soil organic matter content and oxalate extractable aluminium. The RIP correlated weakly but positively to soil clay content. The slope of the correlation between RIP and clay content showed that the RIP per unit clay was only 4.8 mmol g(-1) clay, about threefold lower than that for clays of European soils, suggesting more amorphous minerals and less micaceous minerals in the clay fraction of Japanese soils. The negative correlation between RIP and soil organic matter may indicate that organic matter can mask highly selective sorption sites to RCs. Multiple regression analysis with soil organic matter and cation exchange capacity explained the soil RIP (R(2)=0.64), allowing us to map soil RIP based on existing soil map information.


Subject(s)
Cesium Radioisotopes/analysis , Soil Pollutants, Radioactive/analysis , Soil/chemistry , Adsorption , Aluminum Silicates/chemistry , Cesium Radioisotopes/chemistry , Clay , Japan , Minerals/chemistry , Soil Pollutants, Radioactive/chemistry
17.
Int J Environ Res Public Health ; 8(7): 2640-55, 2011 07.
Article in English | MEDLINE | ID: mdl-21845150

ABSTRACT

Clayey soil found in coal mines in Appalachian Ohio is often sold to landfills for constructing Recompacted Soil Liners (RSL) in landfills. Since clayey soils possess low hydraulic conductivity, the suitability of mined clay for RSL in Ohio is first assessed by determining its clay content. When soil samples are tested in a laboratory, the same engineering properties are typically expected for the soils originated from the same source, provided that the testing techniques applied are standard, but mined clay from Appalachian Ohio has shown drastic differences in particle size distribution depending on the sampling and/or laboratory processing methods. Sometimes more than a 10 percent decrease in the clay content is observed in the samples collected at the stockpiles, compared to those collected through reverse circulation drilling. This discrepancy poses a challenge to geotechnical engineers who work on the prequalification process of RSL material as it can result in misleading estimates of the hydraulic conductivity of the samples. This paper describes a laboratory investigation conducted on mined clay from Appalachian Ohio to determine how and why the standard sampling and/or processing methods can affect the grain-size distributions. The variation in the clay content was determined to be due to heavy concentrations of shale fragments in the clayey soils. It was also concluded that, in order to obtain reliable grain size distributions from the samples collected at a stockpile of mined clay, the material needs to be processed using a soil grinder. Otherwise, the samples should be collected through drilling.


Subject(s)
Aluminum Silicates/analysis , Soil/analysis , Aluminum Silicates/chemistry , Appalachian Region , Clay , Coal Mining , Conservation of Natural Resources , Ohio , Particle Size , Soil/chemistry
18.
Ciênc. rural ; Ciênc. rural (Online);40(7): 1550-1556, jul. 2010. ilus
Article in Portuguese | LILACS | ID: lil-557040

ABSTRACT

A determinação do volume de água disponível às plantas é fundamental para o correto manejo da irrigação e definição quanto ao uso dos solos agrícolas. Os principais fatores que exercem influência na retenção e disponibilidade de água às plantas são a textura e a estrutura do solo. O objetivo deste trabalho foi quantificar a influência da textura na retenção da água, na condição de ponto de murcha permanente (PMP) das plantas (-1,5MPa), sendo utilizado um psicrômetro modelo WP4-T. Determinaram-se a textura de 100 amostras de solo e o teor de água no PMP. Os resultados indicaram que, em potenciais maiores que -1,0MPa, o psicrômetro mostrou-se pouco preciso, não se recomendando a sua utilização nessa condição. O PMP aumentou de 0,059 para 0,29g g-1, quando o teor de argila aumentou de 120 para 779g kg-1. Obteve-se um bom ajuste dos resultados do teor de água no PMP em função do teor de argila do solo, e 91 por cento da variação do teor de água no PMP puderam ser atribuídos à variação no teor de argila. Conclui-se que o psicrômetro é um equipamento que pode ser utilizado para determinar o PMP, e a equação PMP (g g-1)=0,0003*Argila (g kg-1)+0,0118 pode ser utilizada para estimar o PMP.


The determination of the available water to plants is essential to right irrigation management and definition regarding the use in agricultural soils. The main factors that exert influence on retention and availability of water to plants are texture and soil structure. The aim of this study was to quantify the influence of the texture on water retention in the condition of permanent wilting point (PWP) of plants (-1,5MPa) using a WP4-T Dewpoint Potentia Meter. The texture of 100 soil sample and soil moisture at PWP was determined. Results indicated that, in potentials higher than -1,0MPa, WP4-T seemed not very precise, therefore its use is not recommended in this condition. PWP increased from 0,059 to 0,29g g-1, while the clay content increased from 120 to 779g kg-1. It was obtained a good adjustment of the results of water content at PWP based on clay content of soil, being that 91 percent of variation in water content at PWP could be attributed to variation in clay content. It was concluded that WP4-T is an equipment that can be used to determine PWP and the equation PWP (g g-1)=0,0003 * Clay(g kg-1)+0,0118 can be used to estimate PWP.

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