Microsphere kinematics from the polarization of tightly focused nonseparable light.

Recently, it was shown that vector beams can be utilized for fast kinematic sensing via measurements of their global polarization state [Optica2, 864 (2015)10.1364/OPTICA.2.000864]. The method relies on correlations between the spatial and polarization degrees of freedom of the illuminating field which result from its nonseparable mode structure. Here, we extend the method to the nonparaxial regime. We study experimentally and theoretically the far-field polarization state generated by the scattering of a dielectric microsphere in a tightly focused vector beam as a function of the particle position. Using polarization measurements only, we demonstrate position sensing of a Mie particle in three dimensions. Our work extends the concept of back focal plane interferometry and highlights the potential of polarization analysis in optical tweezers employing structured light.

Towards polarization-based excitation tailoring for extended Raman spectroscopy.

Undoubtedly, Raman spectroscopy is one of the most elaborate spectroscopy tools in materials science, chemistry, medicine and optics. However, when it comes to the analysis of nanostructured specimens or individual sub-wavelength-sized systems, the access to Raman spectra resulting from different excitation schemes is usually very limited. For instance, the excitation with an electric field component oriented perpendicularly to the substrate plane is a difficult task. Conventionally, this can only be achieved by mechanically tilting the sample or by sophisticated sample preparation. Here, we propose a novel experimental method based on the utilization of polarization tailored light for Raman spectroscopy of individual nanostructures. As a proof of principle, we create three-dimensional electromagnetic field distributions at the nanoscale using tightly focused cylindrical vector beams impinging normally onto the specimen, hence keeping the traditional beam-path of commercial Raman systems. In order to demonstrate the convenience of this excitation scheme, we use a sub-wavelength diameter gallium-nitride nanostructure as a test platform and show experimentally that its Raman spectra depend sensitively on its location relative to the focal vector field. The observed Raman spectra can be attributed to the interaction with transverse and pure longitudinal electric field components. This novel technique may pave the way towards a characterization of Raman active nanosystems, granting direct access to growth-related parameters such as strain or defects in the material by using the full information of all Raman modes.

Weak Measurement Enhanced Spin Hall Effect of Light for Particle Displacement Sensing.

A spherical nanoparticle can scatter tightly focused optical beams in a spin-segmented manner, meaning that the far field of the scattered light exhibits laterally separated left- and right-handed circularly polarized components. This effect, commonly referred to as giant spin Hall effect of light, strongly depends on the position of the scatterer in the focal volume. Here, a scheme that utilizes an optical weak measurement in a cylindrical polarization basis is put forward to drastically enhance the spin-segmentation and, therefore, the sensitivity to small displacements of a scatterer. In particular, we experimentally achieve a change of the spin-splitting signal of 5% per nanometer displacement.

Investigating the Optical Properties of a Laser Induced 3D Self-Assembled Carbon-Metal Hybrid Structure.

Carbon-based and carbon-metal hybrid materials hold great potential for applications in optics and electronics. Here, a novel material made of carbon and gold-silver nanoparticles is discussed, fabricated using a laser-induced self-assembly process. This self-assembled metamaterial manifests itself in the form of cuboids with lateral dimensions on the order of several micrometers and a height of tens to hundreds of nanometers. The carbon atoms are arranged following an orthorhombic unit cell, with alloy nanoparticles intercalated in the crystalline carbon matrix. The optical properties of this metamaterial are analyzed experimentally using a microscopic Müller matrix measurement approach and reveal a high linear birefringence across the visible spectral range. Theoretical modeling based on local-field theory applied to the carbon matrix links the birefringence to the orthorhombic unit cell, while finite-difference time-domain simulations of the metamaterial relates the observed optical response to the distribution of the alloy nanoparticles and the optical density of the carbon matrix.

Chiroptical response of a single plasmonic nanohelix.

We investigate the chiroptical response of a single plasmonic nanohelix interacting with a weakly focused circularly polarized Gaussian beam. The optical scattering at the fundamental resonance is characterized experimentally and numerically. The angularly resolved scattering of the excited nanohelix is verified experimentally and it validates the numerical results. We employ a multipole decomposition analysis to study the fundamental and first higher-order resonance of the nanohelix, explaining their chiral properties in terms of the formation of chiral dipoles.

Weak Measurement of Elliptical Dipole Moments by C-Point Splitting.

We investigate points of circular polarization in the far field of elliptically polarized dipoles and establish a relation between the angular position and helicity of these C points and the dipole moment. In the case of highly eccentric dipoles, the C points of opposite handedness exhibit only a small angular separation and occur in the low intensity region of the emission pattern. In this regard, we introduce an optical weak measurement approach that utilizes the transverse electric (azimuthal) and transverse magnetic (radial) far-field polarization basis. Projecting the far field onto a spatially varying postselected polarization state reveals the angular separation and the helicity of the C points. We demonstrate the applicability of this approach and determine the elliptical dipole moment of a particle sitting on an interface by measuring the C points in its far field.

Transverse Kerker Scattering for Angstrom Localization of Nanoparticles.

Angstrom precision localization of a single nanoantenna is a crucial step towards advanced nanometrology, medicine, and biophysics. Here, we show that single nanoantenna displacements down to few angstroms can be resolved with sub-angstrom precision using an all-optical method. We utilize the tranverse Kerker scattering scheme where a carefully structured light beam excites a combination of multipolar modes inside a dielectric nanoantenna, which then, upon interference, scatters directionally into the far field. We spectrally tune our scheme such that it is most sensitive to the change in directional scattering per nanoantenna displacement. Finally, we experimentally show that antenna displacement down to 3 Å is resolvable with a localization precision of 0.6 Å.

Single-mode squeezing in arbitrary spatial modes.

As the generation of squeezed states of light has become a standard technique in laboratories, attention is increasingly directed towards adapting the optical parameters of squeezed beams to the specific requirements of individual applications. It is known that imaging, metrology, and quantum information may benefit from using squeezed light with a tailored transverse spatial mode. However, experiments have so far been limited to generating only a few squeezed spatial modes within a given setup. Here, we present the generation of single-mode squeezing in Laguerre-Gauss and Bessel-Gauss modes, as well as an arbitrary intensity pattern, all from a single setup using a spatial light modulator (SLM). The degree of squeezing obtained is limited mainly by the initial squeezing and diffractive losses introduced by the SLM, while no excess noise from the SLM is detectable at the measured sideband. The experiment illustrates the single-mode concept in quantum optics and demonstrates the viability of current SLMs as flexible tools for the spatial reshaping of squeezed light.

Experimental generation of amplitude squeezed vector beams.

We present an experimental method for the generation of amplitude squeezed high-order vector beams. The light is modified twice by a spatial light modulator such that the vector beam is created by means of a collinear interferometric technique. A major advantage of this approach is that it avoids systematic losses, which are detrimental as they cause decoherence in continuous-variable quantum systems. The utilisation of a spatial light modulator (SLM) gives the flexibility to switch between arbitrary mode orders. The conversion efficiency with our setup is only limited by the efficiency of the SLM. We show the experimental generation of Laguerre-Gauss (LG) modes with radial indices 0 or 1 and azimuthal indices up to 3 with complex polarization structures and a quantum noise reduction up to -0.9dB±0.1dB. The corresponding polarization structures are studied in detail by measuring the spatial distribution of the Stokes parameters.

Lateral spin transport in paraxial beams of light.

We investigate the lateral transport of (longitudinal) spin angular momentum in a special polarization tailored light beam composed of a superposition of a y-polarized zero-order and an x-polarized first-order Hermite-Gaussian mode. This phenomenon is linked to the relative Gouy phase shift between the individual modes upon propagation, but can also be interpreted as a geometric phase effect. Experimentally, we demonstrate the implementation of such a mode and measure the spin density upon propagation.

Optical Polarization Möbius Strips and Points of Purely Transverse Spin Density.

Tightly focused light beams can exhibit complex and versatile structured electric field distributions. The local field may spin around any axis including a transverse axis perpendicular to the beams' propagation direction. At certain focal positions, the corresponding local polarization ellipse can even degenerate into a perfect circle, representing a point of circular polarization or C point. We consider the most fundamental case of a linearly polarized Gaussian beam, where-upon tight focusing-those C points created by transversely spinning fields can form the center of 3D optical polarization topologies when choosing the plane of observation appropriately. Because of the high symmetry of the focal field, these polarization topologies exhibit nontrivial structures similar to Möbius strips. We use a direct physical measure to find C points with an arbitrarily oriented spinning axis of the electric field and experimentally investigate the fully three-dimensional polarization topologies surrounding these C points by exploiting an amplitude and phase reconstruction technique.

Quantum uncertainty in the beam width of spatial optical modes.

We theoretically investigate the quantum uncertainty in the beam width of transverse optical modes and, for this purpose, define a corresponding quantum operator. Single mode states are studied as well as multimode states with small quantum noise. General relations are derived, and specific examples of different modes and quantum states are examined. For the multimode case, we show that the quantum uncertainty in the beam width can be completely attributed to the amplitude quadrature uncertainty of one specific mode, which is uniquely determined by the field under investigation. This discovery provides us with a strategy for the reduction of the beam width noise by an appropriate choice of the quantum state.

Measuring the transverse spin density of light.

We generate tightly focused optical vector beams whose electric fields spin around an axis transverse to the beams' propagation direction. We experimentally investigate these fields by exploiting the directional near-field interference of a dipolelike plasmonic field probe placed adjacent to a dielectric interface. This directionality depends on the transverse electric spin density of the excitation field. Near- to far-field conversion mediated by the dielectric interface enables us to detect the directionality of the emitted light in the far field and, therefore, to measure the transverse electric spin density with nanoscopic resolution. Finally, we determine the longitudinal electric component of Belinfante's elusive spin momentum density, a solenoidal field quantity often referred to as "virtual."

Polarization tailored light driven directional optical nanobeacon.

We experimentally demonstrate all-optical control of the emission directivity of a dipole-like nanoparticle with spinning dipole moment sitting on the interface to an optical denser medium. The particle itself is excited by a tightly focused polarization tailored light beam under normal incidence. The position dependent local polarization of the focal field allows for tuning the dipole moment via careful positioning of the particle relative to the beam axis. As an application of this scheme, we investigate the polarization dependent coupling to a planar two-dimensional dielectric waveguide.

Generation and subwavelength focusing of longitudinal magnetic fields in a metallized fiber tip.

We demonstrate experimentally and numerically that in fiber tips as they are used in NSOMs azimuthally polarized electrical fields (|E(azi)|2 / |E(tot)|2 ≈55% ± 5% for λ0 = 1550 nm), respectively subwavelength confined (FWHM ≈450 nm ≈λ0/3.5) magnetic fields, are generated for a certain tip aperture diameter (d = 1.4 µm). We attribute the generation of this field distribution in metal-coated fiber tips to symmetry breaking in the bend and subsequent plasmonic mode filtering in the truncated conical taper.

Observation of the geometric spin Hall effect of light.

The spin Hall effect of light (SHEL) is the photonic analogue of the spin Hall effect occurring for charge carriers in solid-state systems. This intriguing phenomenon manifests itself when a light beam refracts at an air-glass interface (conventional SHEL) or when it is projected onto an oblique plane, the latter effect being known as the geometric SHEL. It amounts to a polarization-dependent displacement perpendicular to the plane of incidence. In this work, we experimentally investigate the geometric SHEL for a light beam transmitted across an oblique polarizer. We find that the spatial intensity distribution of the transmitted beam depends on the incident state of polarization and its centroid undergoes a positional displacement exceeding one wavelength. This novel phenomenon is virtually independent from the material properties of the polarizer and, thus, reveals universal features of spin-orbit coupling.

The polarization properties of a tilted polarizer.

Polarizers are key components in optical science and technology. Thus, understanding the action of a polarizer beyond oversimplifying approximations is crucial. In this work, we study the interaction of a polarizing interface with an obliquely incident wave experimentally. To this end, a set of Mueller matrices is acquired employing a novel procedure robust against experimental imperfections. We connect our observation to a geometric model, useful to predict the effect of polarizers on complex light fields.

Investigation of the Influence of Wound-Treatment-Relevant Buffer Systems on the Colloidal and Optical Properties of Gold Nanoparticles.

Biocompatible gold nanoparticles (AuNPs) are used in wound healing due to their radical scavenging activity. They shorten wound healing time by, for example, improving re-epithelialization and promoting the formation of new connective tissue. Another approach that promotes wound healing through cell proliferation while inhibiting bacterial growth is an acidic microenvironment, which can be achieved with acid-forming buffers. Accordingly, a combination of these two approaches appears promising and is the focus of the present study. Here, 18 nm and 56 nm gold NP (Au) were prepared with Turkevich reduction synthesis using design-of-experiments methodology, and the influence of pH and ionic strength on their behaviour was investigated. The citrate buffer had a pronounced effect on the stability of AuNPs due to the more complex intermolecular interactions, which was also confirmed by the changes in optical properties. In contrast, AuNPs dispersed in lactate and phosphate buffer were stable at therapeutically relevant ionic strength, regardless of their size. Simulation of the local pH distribution near the particle surface also showed a steep pH gradient for particles smaller than 100 nm. This suggests that the healing potential is further enhanced by a more acidic environment at the particle surface, making this strategy a promising approach.

Resonant metamaterials for contrast enhancement in optical lithography.

The transmission through ultra-thin metal films is noticeable and thus limits their potential for the formation of lithographic masks. By sub-wavelength patterning of a metal film with a post structure, a resonant metamaterial is formed, which can effectively suppress the transmission. Measurements as well as calculations identify the width of the metal islands as a critical geometrical feature. Hence, the extraordinarily low transmission effect can be explained by the resonant response of single scatterers known as Localized Surface Plasmon Resonances (LSPR). A potential application of this suppressed transmission effect to thin metal masks in optical lithography is experimentally investigated.

Extreme Concentration and Nanoscale Interaction of Light.

Concentrating light strongly calls for appropriate polarization patterns of the focused light beam and for up to a full 4π solid angle geometry. Focusing on the extreme requires efficient coupling to nanostructures of one kind or another via cylindrical vector beams having such patterns, the details of which depend on the geometry and property of the respective nanostructure. Cylindrical vector beams can not only be used to study a nanostructure, but also vice versa. Closely related is the discussion of topics such as the ultimate diffraction limit, a resonant field enhancement near nanoscopic absorbers, as well as speculations about nonresonant field enhancement, which, if it exists, might be relevant to pair production in vacuum. These cases do require further rigorous simulations and more decisive experiments. While there is a wide diversity of scenarios, there are also conceptually very different models offering helpful intuitive pictures despite this diversity.