Self-Assembling Graphene Layers for Electrochemical Sensors Printed in a Single Screen-Printing Process.

This article reports findings on screen-printed electrodes employed in microfluidic diagnostic devices. The research described includes developing a series of graphene- and other carbon form-based printing pastes compared to their rheological parameters, such as viscosity in static and shear-thinning conditions, yield stress, and shear rate required for thinning. In addition, the morphology, electrical conductivity, and electrochemical properties of the electrodes, printed with the examined pastes, were investigated. Correlation analysis was performed between all measured parameters for six electrode materials, yielding highly significant (p-value between 0.002 and 0.017) correlations between electron transfer resistance (Ret), redox peak separation, and static viscosity and thinning shear-rate threshold. The observed more electrochemically accessible surface was explained according to the fluid mechanics of heterophase suspensions. Under changing shear stress, the agglomeration enhanced by the graphene nanoplatelets' interparticle affinity led to phase separation. Less viscous pastes were thinned to a lesser degree, allowing non-permanent clusters to de-agglomerate. Thus, the breaking of temporary agglomerates yielded an unblocked electrode surface. Since the mechanism of phase ordering through agglomeration and de-agglomeration is affected by the pastes' rheology and stress during the printing process and requires no further treatment, it can be appropriately labeled as a self-assembling electrode material.

Influence of the Heat Transfer Process on the Electrical and Mechanical Properties of Flexible Silver Conductors on Textiles.

With the increase in the popularity of wearable and integrated electronics, a proper way to manufacture electronics on textiles is needed. This study aims to analyze the effect of different parameters of the heat transfer process on the electrical and mechanical properties of flexible electronics made on textiles, presenting it as a viable method of producing such electronics. Wires made from different composites based on silver microparticles and an insulating layer were screen-printed on a release film. Then, they were transferred onto a polyester cloth using heat transfer with different parameters. Research showed that different heat transfer parameters could influence the electrical properties of screen-printed wires, changing their resistance between -15% and +150%, making it imperative to adjust those properties depending on the materials used. Changes in the settings of heat transfer also influence mechanical properties, increasing adhesion between layers at higher temperatures. This study shows the importance of tailoring heat transfer properties and the differences that these properties make.