The Technical Challenges for Applying Unsaturated Soil Sensors to Conduct Laboratory-Scale Seepage Experiments.

Although many unsaturated soil experiments have successfully delivered positive outcomes, most studies just concisely illustrated sensor techniques, because their main objectives focused on bridging research gaps. Inexperienced research fellows might rarely follow up those techniques, so they could encounter very trivial and skill-demanding difficulties, undermining the quality of experimental outcomes. With a motivation to avoid those, this work introduces technical challenges in applying three sensor techniques: high precision tensiometer, spatial time-domain reflectometry (spatial TDR) and digital bench scales, which were utilized to measure three fundamental variables: soil suction, moisture content and accumulative outflow. The technical challenges are comprehensively elaborated from five aspects: the functional mechanism, assembling/manufacturing approaches, installation procedure, simultaneous data-logging configurations and post data/signal processing. The conclusions drawn in this work provide sufficient technical details of three sensors in terms of the aforementioned five aspects. This work aims to facilitate any new research fellows who carry out laboratory-scale soil column tests using the three sensors mentioned above. It is also expected that this work will salvage any experimenters having troubleshooting issues with those sensors and help researchers bypass those issues to focus more on their primary research interests.

The pore solution of cement-based materials: structure and dynamics of water and ions from molecular simulations.

Diffusion processes are crucial to the durability and confinement capacity of cement-based materials as well as property development. The liquid phase in cement-based materials is the pore solution, whose composition changes with age and is a function of the cement system composition. Water structure and dynamics are recognized to be affected by the presence of ions. Fundamental understanding of the physical processes underlying these changes can be critical in the elucidation of the physical origin of durability issues and in the development of new admixtures. Here, the structure and dynamics of water and ions present in pore solutions are studied using molecular dynamics simulations. Self-diffusion coefficients are computed for bulk solutions mimicking the complex composition of pore solutions. Specific ion effects on water dynamics are interpreted in terms of water reorientation time. The composition dependency of ion dynamics explains the evolution of the ionic conductivity of the pore solutions.

Determination of the Porosity Distribution during an Erosion Test Using a Coaxial Line Cell.

The detection of porosity changes within a soil matrix caused by internal erosion is beneficial for a better understanding of the mechanisms that induce and maintain the erosion process. In this paper, an electromagnetic approach using Spatial Time Domain Reflectometry (STDR) and a transmission line model is proposed for this purpose. An original experimental setup consisting of a coaxial cell which acts as an electromagnetic waveguide was developed. It is connected to a transmitter/receiver device both measuring the transmitted and corresponding reflected electromagnetic pulses at the cell entrance. A gradient optimization method based on a computational model for simulating the wave propagation in a transmission line is applied in order to reconstruct the spatial distribution of the soil dielectric permittivity along the cell based on the measured signals and an inversion algorithm. The spatial distribution of the soil porosity is deduced from the dielectric permittivity profile by physically based mixing rules. Experiments were carried out with glass bead mixtures of known dielectric permittivity profiles and subsequently known spatial porosity distributions to validate and to optimize both, the proposed computational model and the inversion algorithm. Erosion experiments were carried out and porosity profiles determined with satisfying spatial resolution were obtained. The RMSE between measured and physically determined porosities varied among less than 3% to 6%. The measurement rate is sufficient to be able to capture the transient process of erosion in the experiments presented here.

Error Analysis of Clay-Rock Water Content Estimation with Broadband High-Frequency Electromagnetic Sensors--Air Gap Effect.

Broadband electromagnetic frequency or time domain sensor techniques present high potential for quantitative water content monitoring in porous media. Prior to in situ application, the impact of the relationship between the broadband electromagnetic properties of the porous material (clay-rock) and the water content on the frequency or time domain sensor response is required. For this purpose, dielectric properties of intact clay rock samples experimental determined in the frequency range from 1 MHz to 10 GHz were used as input data in 3-D numerical frequency domain finite element field calculations to model the one port broadband frequency or time domain transfer function for a three rods based sensor embedded in the clay-rock. The sensor response in terms of the reflection factor was analyzed in time domain with classical travel time analysis in combination with an empirical model according to Topp equation, as well as the theoretical Lichtenecker and Rother model (LRM) to estimate the volumetric water content. The mixture equation considering the appropriate porosity of the investigated material provide a practical and efficient approach for water content estimation based on classical travel time analysis with the onset-method. The inflection method is not recommended for water content estimation in electrical dispersive and absorptive material. Moreover, the results clearly indicate that effects due to coupling of the sensor to the material cannot be neglected. Coupling problems caused by an air gap lead to dramatic effects on water content estimation, even for submillimeter gaps. Thus, the quantitative determination of the in situ water content requires careful sensor installation in order to reach a perfect probe clay rock coupling.

Optimizing in-situ CO2 mineralisation: geomechanics and scalability in dunite and serpentinite rocks - Examples from Australia and New Zealand.

The collective drive towards achieving net-zero greenhouse gas emissions by 2050 has spurred interest in engineering solutions for carbon capture and storage worldwide. One such approach involves the permanent storage of CO2 in earth-abundant Ca-, Fe-, and Mg-bearing silicate rocks and minerals as carbonates via the process of CO2 mineralisation. This necessitates a thorough understanding of carbonate conversion under geologically relevant conditions. Nevertheless, research on CO2 injection for mineralisation via naturally fractured host rocks or induced fractures, with a research emphasis on rock mechanics and stimulated reservoir volumes (SRV) within geoengineering CO2 storage, is continuously expanding. This research addresses critical challenges related to identifying favourable geographic locations for CO2 mineralisation. It specifically focuses on the abundant availability of Mg, Ca, and Fe cations for exothermic CO2 reactions and their impact on fracture conductivity during in-situ mineralisation. A comprehensive analysis of 26 dunite and serpentinite samples from diverse locations in Australia and New Zealand, including 10 from a cored drilled hole, was conducted. Quantification of divalent cation (Mg, Ca, Fe) content and cation release capacity using XRF and XRD revealed higher cation percentages in dunite samples (approximately 30 %) compared to serpentinite samples (approximately 26 %). Additionally, the study estimated the stimulated rock mass-to-CO2 sequestered ratio, [Formula: see text] , with dunite samples averaging approximately 2.20 [Formula: see text] values and serpentinite samples averaging approximately 2.53. Geomechanical testing enabled the prediction of fracture propagation pressures during aqueous CO2 injection for in-situ mineralisation and the estimation of fracture geometries, emphasizing the role of rock stiffness in determining fracture width (averaging 6.0 mm). Furthermore, the research estimated the rock volume exposed to CO2-laden fluid during injection, particularly focusing on the GHQ-3 sample, which theoretically amounted to approximately 600 kg of rock capable of sequestering around 300 kg of CO2 for a 10 m3 fluid volume with a CO2 concentration of 1molkg-1. The study established a relationship between injected volume and CO2 uptake, suggesting the potential for significant CO2 sequestration scalability by employing horizontal wells and fracturing additional zones, thereby creating and intersecting multiple transverse fractures along a single target zone.