Multimode Mamyshev oscillator.

We present a spatiotemporally mode-locked Mamyshev oscillator. A wide variety of multimode mode-locked states, with varying degrees of spatiotemporal coupling, are observed. We find that some control of the modal content of the output beam is possible through the cavity design. Comparison of simulations with experiments indicates that spatiotemporal mode locking (STML) is enabled by nonlinear intermodal interactions and spatial filtering, along with the Mamyshev mechanism. This work represents a first, to the best of our knowledge, exploration of STML in an oscillator with a Mamyshev saturable absorber.

Fabrication of ultra-high numerical aperture GeO2-doped fiber and its use for broadband supercontinuum generation: publisher's note.

This publisher's note serves to correct Appl. Opt.56, 9315 (2017)APOPAI0003-693510.1364/AO.56.009315.

Noise-like pulse generation around 1.3-µm based on cascaded Raman scattering.

Based on cascaded Raman scattering, near-infrared (NIR) noise-like pulses (NLPs) were successfully demonstrated using a Yb-doped fiber amplifier system. Through a nonlinear fiber amplifier using a germanium-zirconia-silica Yb3+-doped single mode fiber as a gain fiber, the fourth-order Stokes wave (4th-SW) can be excited to extend the emission peak of approximately 1.2-µm and a 3-dB bandwidth of approximately 130 nm. To further shift the wavelength more efficiently toward 1.3 µm, filtered NLPs with an emission peak at 1075 nm were adopted as seeded pulses to excite the fifth-order Stokes wave (5th-SW) because of the better conversion efficiency of stimulated Raman scattering without gain competition with Yb-doped fiber. The generated NIR NLPs were shown to be an excellent light source for the photoluminescence emission from three photon absorption of perovskite to illustrate the red shift of the emission peak owing to the reabsorption effect.

Regenerated grating produced in a multimaterial glass-based photosensitive fiber with an ultrahigh thermal regeneration ratio.

This work demonstrates thermal regeneration of gratings inscribed in a new type of multi-material glass-based photosensitive fiber. And isothermal annealing procedure has been carried out on a type-I seed grating (SG) imprinted in erbium-doped zirconia-yttria-alumina-germanium (Er-ZYAG) silica glass-based fiber, which is initiated from room temperature of 25°C up to 900°C. The findings show that the created regenerated grating (RG) has an ultrahigh thermal regeneration ratio with a value of 0.72.

Nanosecond pulse laser generation at 1.55 and 2 µm regions by integrating a piece of newly developed chromium-doped fiber-based saturable absorber.

This paper demonstrated the nanosecond pulse laser operation at 1.55 and 2 µm wavelength regions using a newly develop chromium-doped fiber (CrDF) as a saturable absorber (SA) to convert efficiently continuous-wave laser operation to nanosecond pulse laser operation. The laser uses an erbium-doped fiber (EDF) and thulium-doped fiber as the gain medium. A piece of 10 cm long CrDF was integrated into both laser cavities to generate nanosecond pulse laser operation. In 1.55 region generation, an additional single-mode fiber (SMF) 100 m long was added into the EDF laser cavity. Stable pulse generation occurred at a repetition rate of 1 MHz with a pulse width of 432 ns and a signal-to-noise ratio (SNR) of 66 dB. The highest peak power of 24 mW was obtained at 142 mW pump power. In 2 µm region generation, the obtained repetition rate was 10 MHz with a pulse width and SNR of 59 ns and 41 dB, respectively. The highest peak power was only 8.3 mW. By looking into the findings, the newly developed CrDF SA has a potential to be further enhanced toward better generation of ultrashort pulse fiber lasers.

Ex vivo testing of air-cooled CW/modulated 30 W thulium fiber laser for lithotripsy.

A diode-pumped, air-cooled, all-fiber, quasi-continuous-wave thulium laser at an operating wavelength of 1.94 µm has been designed to study the performance of the laser parameter on the rate of fragmentation and its dependence on stone composition, fragmented particle size, as well as the retropulsion effect. The optimized laser cavity with an active fiber core/cladding diameter of 10/130 µm under a counter-propagating pump provides a stable laser power of 30 W at a slope efficiency of 50% and wall plug efficiency of 17%. The rate of fragmentation along with the retropulsion effect has been studied with human calcium oxalate monohydrate (COM) urinary stones (N=36) of different composition by using the designed laser and 200-µm-core low OH silica delivery fiber. The thulium fiber laser setting of 2.7 J pulse energy at the pulse rate of 10 Hz, pulse width of 90 ms, and peak power of 30 W is successful in breaking human COM stones in a controlled manner at a fragmentation rate of 0.8±0.4 mg/s, with almost uniform fragments of particle size less than 1.6 mm. During the stone fragmentation, the stone displacement (retropulsion effect) is less than 15 mm, even for the fragmented stone mass of 15±5 mg.

Computationally efficient approach for identification of fuzzy dynamic groundwater sampling network.

In the present work, uncertainty-based dynamic sampling frameworks were tested for a sampling horizon with multiple time steps. Future concentration values were assumed as fuzzy numbers. Multiple realization-based simulations were used for generation of fuzzy numbers. The first framework considers fuzzy variance reduction. The second framework considers mass estimation error reduction with maximization of spatial coverage of the dynamic sampling network. It is a multi-objective optimization problem with a large number of objectives. In Dhar and Patil (2012), uncertainty-based optimal sampling design model was suggested using Nondominated Sorting Genetic Algorithm-II (NSGA-II) as its optimization algorithm. However, NSGA-II becomes computationally expensive while handling more than three objectives. We extend the previously suggested algorithm for multi-objective sampling network design problems based on NSGA-III framework. Two design frameworks were proposed: one incorporating a simulation model and a fuzzy covariance for minimizing the total contaminant-concentration variance and the other incorporating a simulation model and a fuzzy kriging model in conjunction with an optimization model to minimize the fuzzy mass estimation error and spatial coverage of spatiotemporal sampling locations. NSGA-III was used for solving the sampling network design model. Performances of the proposed frameworks were evaluated for two hypothetical illustrative examples. The results indicate that the proposed design frameworks perform satisfactorily under uncertain system conditions.

Fabrication of ultra-high numerical aperture GeO2-doped fiber and its use for broadband supercontinuum generation.

We report the fabrication, characterization, and application (broadband supercontinuum [SC] generation) of ultra-high numerical-aperture heavily (50 mol. %) GeO2-doped optical fiber, obtained through a modified chemical vapor deposition process and rod-in-tube method. The formation of Ge-related diamagnetic defect centers, such as germanium oxygen defect centers (GeODC) with nonbridging lone electron pairs, confirmed by x-ray photoelectron spectroscopy and optical absorption studies, inducing hypolarizable local dipoles, may be responsible in boosting the nonlinear effects and enhancing stimulated Raman scattering at pumping with high-power pulses, culminating in generation of broadband SC generation. The SC spans toward the Stokes side up to 2.4 µm, under the action of ns-range pulses launched from a smartly Q-switched erbium-doped fiber laser with operation wavelength (1.56 µm) matching the zero-dispersion wavelength of the high GeO2-doped fiber.

Near-infrared supercontinnum generation in single-mode nonlinear Yb(3+)-doped fiber amplifier.

Near-infrared supercontinnum (SC) generation, accompanied with several emission bands at visible and ultraviolet, is experimentally investigated in an all-fiber single-mode Yb(3+)-doped silica fiber MOPA. The seed is an all-normal-dispersion mode-locked Yb(3+)-doped single-mode fiber laser using a nonlinear polarization evolution mechanism. With the pump power of several hundreds of milliwatts, SC spanning of 1010 nm to 1600 nm was generated in a 20-m single-mode germano-zirconia-silica Yb(3+)-doped fiber amplifier. The intensive nonlinear effects, namely stimulated Raman scattering, four wave mixing, and self-phase modulation, enable the SC generation in the small-core fiber amplifier without the use of photonic crystal fibers or tapered fibers. Such a compact and cost-effective SC generation system enables applications in optical coherent tomography, optical metrology, and nonlinear microscopy.

Wormhole Mesoporous Silica Framework with Enhanced Thiol Loading for Improved Hg²âº Sequestration.

Thiol-functionalized mesoporous silica and materials potentially dedicated to diverse applications of composite materials, metal colloids, and metal catalysts, etc. Here, we developed a new synthesis route for 3-methacryloxypropyl trimethoxy silane (MPTMS) functionalized mesoporous silica (KIT-6), achieving a 71.5% enhancement in thiol functionalization on KIT-6 surfaces. Characterization using XRD, TEM, BET, FTIR, Raman, 29Si NMR, XPS, and ICP-OES revealed structural and morphological features. XRD, TEM, and BET confirmed the three-dimensional structural stabilization of mesoporous silica with ~4 nm pore diameter and a surface area of 1451 m2 g-1. FTIR, Raman, and 29Si NMR studies established the mechanism of thiol functionalization, the formation of a new wormhole chain structural framework (WCSF), and stabilization through hydrogen bonding within the mesopores. The 29Si NMR spectra showed characteristic peaks (T3, T2, Q4, Q3) indicating self-condensed functionalized thiols with siloxane networks. XPS analysis validated enhanced thiol functionalization, indicating a structurally homogeneous WCSF suitable for mercury adsorption. ICP-OES measured a mercury adsorption capacity of 3199.6 mg g-1 for KIT-6, with an Hg2+/S ratio of 1.8, corroborated by molecular structure and mechanism analysis. This innovative thiol functionalization approach enhances the efficacy of applications such as extracting Hg2+ from contaminated sources.

Spatiotemporal evaluation and assessment of shallow groundwater quality for irrigation of a tropical coastal groundwater basin.

The present study aims at analyzing groundwater quantity and quality simultaneously to identify its availability and suitability for irrigation. Various water quality indices were used to assess (i) origin of the groundwater sources (Gibbs diagram); (ii) salinity, alkalinity, and sodium hazard (sodium adsorption ratio, exchangeable sodium percentage, Kelly's ratio, US Salinity Laboratory diagram, Wilcox diagram); (iii) magnesium hazard (magnesium absorption ratio); (iv) carbonate and bicarbonate hazard (residual sodium carbonate); (v) hydro-chemical facie and evaluation (Piper diagram and Expanded Durov diagram); and (vi) statistical relationship among the variables, sample sites, and spatiotemporal grouping (principal component analysis and cluster analysis). The overall objective is to quantify the irrigation suitability of groundwater reserves. Gibb's diagram suggests that the groundwater quality is mainly controlled by rock-water interaction. Piper trilinear showed the presence of various types of hydro-chemical facies such as Ca-Mg-HCO3, mixed, and sodium bicarbonate. The expanded Durov diagram revealed the hydro-chemical evolution, grouping, and areal distribution of the groundwater samples. USSL diagram, Wilcox diagram, Kelly's ratio, magnesium hazard, and permeability index suggest that the groundwater quality is suitable for irrigation. Kaiser-Meyer-Olkin (KMO) and Bartlett's tests confirmed the applicability of principal component analysis (PCA), which indicates that groundwater quality is controlled by rock-water interaction mainly. It also suggests that the groundwater has carbonate dissolution, which indicates the groundwater's hardness increased. Cluster analysis (CA) from the year 2000 to 2010 shows 4 to 8 groups present within the study area. Irrigation water quality suitability map and predicted groundwater potential zone map together act as a master tool for deciding tube well location, pumping schedule, and crop planning for the sustainability of the agriculture eco-system in the study area. The implementation of the aforementioned activities in the study area will further stop the advancement of the seawater intrusion front. The methodology shows the potential applicability for similar coastal groundwater basins worldwide with or without modification.

Germanium microsphere high-Q resonator.

In this Letter, the fabrication and characterization of a microsphere resonator from the semiconductor germanium is demonstrated. Whispering gallery modes are excited in a 46 µm diameter germanium microsphere resonator using evanescent coupling from a tapered silica optical fiber with a waist diameter of 2 µm. Resonances with Q factors as high as 3.8×10(4) at wavelengths near 2 µm are observed. Because of their ultrahigh optical nonlinearities and extremely broad transparency window, germanium microsphere resonators offer the potential for optical processing devices, in particular at long wavelengths, such as around 2 µm.

Theoretical modeling of fiber laser at 810 nm based on thulium-doped silica fibers with enhanced 3H4 level lifetime.

A compact upconversion fiber laser operating around 810 nm is proposed using thulium-doped silica-based fiber with locally modified thulium environment by high alumina codoping. Using a comprehensive numerical model of thulium doped fiber we investigate performance of the proposed laser. Comparison with two other thulium hosts, fluoride glass and standard silica, is presented. Efficient lasing can be expected even for silica based fiber for specific ranges of the fiber and laser cavity parameters, especially when 3H4 lifetime is enhanced. With moderate pump power of 5 W at wavelength of 1064 nm, the predicted output power of the upconversion laser is about 2 W at 810 nm.

Ytterbium-sensitized Thulium-doped fiber laser in the near-IR with 980 nm pumping.

The use of an unidirectional auxiliary pump at approximately 1600 nm in conjunction with a 980 nm primary pump for Ytterbium (Yb(3+))-sensitized-Thulium (Tm(3+))-doped single mode silica fiber (YTDF) is found to be very effective to activate the most significant resonance energy transfer from Yb(3+) to Tm(3+), in order to obtain significant emission in the near-infrared. The resulting laser performance of the YTDF at 1874 nm is reported here. The influence of the Tm(3+)/Yb(3+) concentration, their relative proportions and the host glass composition on the lasing efficiency has also been investigated to optimize the fiber parameters for maximum laser output power.

The mechanism of rare earth incorporation in solution doping process.

The mechanism involved during solution doping process has been systematically investigated by correlating the soot characteristics and solution parameters with the amount of rare earth (RE) incorporated in the core of optical fiber. Experiments show that the amount of RE incorporation may be controlled with better precision by adjusting Al ion concentration in the soaking solution. A model has been developed on the basis of cooperative adsorption mechanism correlating different parameters in the overall process. Theoretical estimation shows good agreement with the experimental results and can be used to predict the extent of RE incorporation for any composition if the soot layer characteristics are known.

Characterization of porous core layer for controlling rare earth incorporation in optical fiber.

The porous core layer deposited by modified chemical vapour deposition process has been analyzed in terms of thickness, pore size distribution, homogeneity and characteristics of the soot particles to investigate their variation with deposition temperature and input vapour composition. The compositions selected were SiO(2), SiO(2)-GeO(2) and SiO(2)-P(2)O(5). Rare earth ions were incorporated into the deposit by a solution doping technique. The analysis of deposited microstructures was found to provide a quantitative indication about the rare earth incorporation and its variation with respect to process conditions. Thus the characterization provides a method of controlling rare earth doping and ultimate preform/fiber properties.

Homotopy Perturbation Method-Based Analytical Solution for Tide-Induced Groundwater Fluctuations.

The groundwater variations in unconfined aquifers are governed by the nonlinear Boussinesq's equation. Analytical solution for groundwater fluctuations in coastal aquifers under tidal forcing can be solved using perturbation methods. However, the perturbation parameters should be properly selected and predefined for traditional perturbation methods. In this study, a new dimensional, higher-order analytical solution for groundwater fluctuations is proposed by using the homotopy perturbation method with a virtual perturbation parameter. Parameter-expansion method is used to remove the secular terms generated during the solution process. The solution does not require any predefined perturbation parameter and valid for higher values of amplitude parameter A/D, where A is the amplitude of the tide and D is the aquifer thickness.

Global optimal design of ground water monitoring network using embedded kriging.

We present a methodology for global optimal design of ground water quality monitoring networks using a linear mixed-integer formulation. The proposed methodology incorporates ordinary kriging (OK) within the decision model formulation for spatial estimation of contaminant concentration values. Different monitoring network design models incorporating concentration estimation error, variance estimation error, mass estimation error, error in locating plume centroid, and spatial coverage of the designed network are developed. A big-M technique is used for reformulating the monitoring network design model to a linear decision model while incorporating different objectives and OK equations. Global optimality of the solutions obtained for the monitoring network design can be ensured due to the linear mixed-integer programming formulations proposed. Performances of the proposed models are evaluated for both field and hypothetical illustrative systems. Evaluation results indicate that the proposed methodology performs satisfactorily. These performance evaluation results demonstrate the potential applicability of the proposed methodology for optimal ground water contaminant monitoring network design.