1.
Chem Commun (Camb)
; 51(19): 4021-3, 2015 Mar 07.
Artículo
en Inglés
| MEDLINE
| ID: mdl-25659830
RESUMEN
Reaction of [Nb6O19](8-) with [Pt(OH)4(H2O)2] upon heating yielded first characterized platinum polyniobates. A dimeric complex [Nb6O19{Pt(OH)2}]2(12-) (1) is produced in a 1 : 1 molar ratio. Increasing the Pt/Nb6 molar ratio to 1 : 2 yields a mixture of 1 and a sandwich-type complex [Pt(Nb6O19)2](12-) (2).