Raman spectroscopy for profiling physical and chemical properties of atmospheric aerosol particles: A review.

Atmosphere aerosols have significant impact on human health and the environment. Aerosol particles have a number of characteristics that influence their health and environmental effects, including their size, shape, and chemical composition. A great deal of difficulty is associated with quantifying and identifying atmospheric aerosols because these parameters are highly variable on a spatial and temporal scale. An important component of understanding aerosol fate is Raman Spectroscopy (RS), which is capable of resolving chemical compositions of individual particles. This review presented strategic techniques, especially RS methods for characterizing atmospheric aerosols. The nature and properties of atmospheric aerosols and their influence on environment and human health were briefly described. Analytical methodologies that offer insight into the chemistry and multidimensional properties of aerosols were discussed. In addition, perspectives for practical applications of atmospheric aerosols using RS are featured.

Assessment of metal mobility in sediment, commercial fish accumulation and impact on human health risk in a large shallow plateau lake in southwest of China.

Sediment heavy metal pollution in the Dianchi Lake has been a long-term environmental problem of concern. This study investigated the lake sediment heavy metal contamination level, mobility, commercial fish metal accumulation and its impact on human health. The results show high As, Hg and Cd concentration in the sediment, while Pb and Cr contamination are insignificant. Sediment sequential extraction analysis shows that Hg in sediment has the highest portion of mobile fraction, followed by As, while the portion of mobile fractions of Cd, Pb and Cr in sediment is very low. The high concentrations of Hg and As in surface water and porewater were consistent with the chemical fraction composition of the two elements in sediment. Three major commercial fish species, Culterichthys erythropterus, Carassius auratus and Hypophthalmichthys molitrix, were collected for analysis of metal concentrations in their muscles. Among the same size of fish, C. auratus has the highest As concentration due to its bottom habitat and omnivorous feeding habits. On the other hand, C. erythropterus has the highest Hg concentration due to its relatively high trophic level position. The average THQ value of metals in fish tissue decrease in the order of As > Hg > Pb > Cd > Cr and the total THQ of average metal concentration in fish species decreased in the order of C. auratus > C. erythropterus > H. molitrix. Both THQ and total THQ is below 1, suggested no non-carcinogenic human health risk of fish consumption. However, TR of As in C. auratus was above 1.00E-04 threshold value, indicated potential carcinogenic human health risk. The results from this study indicate that although moderately to heavily contamination of Hg, As, and Cd occurred in Dianchi Lake sediment, only Hg and As tend to transport to surface water and accumulate in commercial fish due to their higher mobility in sediment.

Adverse effects of Microcystis aeruginosa exudates on the filtration, digestion, and reproduction organs of benthic bivalve Corbicula fluminea.

Cyanobacteria bloom and the secondary metabolites released by the microorganism are extremely harmful to aquatic animals, yet study on their adverse effects in zoobenthos is rare. Corbicula fluminea widely distributed in freshwater environment with algal blooms. It is a typical filter feeding zoobenthos that may be affected by the secondary metabolites of cyanobacteria due to its high filtering rate. In this study, C. fluminea was exposed to Microcystis aeruginosa exudates (MaE) for 96 h, which was obtained from 5 × 105 cells/mL and 2.5 × 106 cells/mL exponential stage M. aeruginosa culture solution that represented cyanobacteria cell density needs environmental risk precaution control and emergent control, respectively. The responses of C. fluminea critical organs to MaE were analyzed and evaluated based on histopathological sections, antitoxicity biomarkers, and organ function biomarkers. The results showed that all the organs underwent structural disorders, cell vacuolization, apoptosis, and necrosis, and the damage levels increased as MaE concentration increased. The detoxification and antioxidant defense systems biomarkers in each organ response to MaE exposure differently and the level of reaction improved when MaE concentration increased. The siphon rate and acetylcholinesterase activity showed that the filtration function decreased significantly as the MaE concentration increased. Increased activity of glutathione S-transferase and amylase in the digestive gland indicate that it is the major detoxification organ of C. fluminea. Increased vitellogenin concentration and enlarged oocytes in the gonad indicate that MaE may have an estrogenic effect on C. fluminea. This study demonstrates that cyanobacteria threat benthic bivalves by inducing oxidative stress, inhibiting filtering feeding system, and disturbing digestion system and reproduction potential of C. fluminea.

Au-NP-Decorated Cotton Swabs as a Facile SERS Substrate for Food-Safety-Related Molecule Detection.

Recently, food safety has received considerable attention, and various analytical techniques have been employed to monitor food quality. One of the promising techniques in this domain is the surface-enhanced Raman scattering (SERS) technique. This study developed a facile, cost-effective SERS method by supporting a wipe-type substrate with a small-head cotton swab. We fabricated Au-nanoparticle (NP)-decorated cotton swabs (CS-Au NP) via the dropwise addition of gold colloid on the cotton fibers. These swabs exhibit reduced gold colloid consumption and a compact fiber structure, allowing for the uniform distribution of Au NPs and easy capture of molecular signals. Experiments were conducted to obtain a CS-Au NP wiper performance optimized for cotton swab selection, NaCl concentration, and Au NP layers. The Raman reporter molecule 4-mercaptopyridine was detected at a concentration of 1 × 10-8 M and a relative standard deviation of ≤10%. The proposed SERS platform enables the facile and reliable detection of food-safety-related molecules such as malachite green on the surface of fruits and vegetables. This paper describes the development of an easy, cost-effective, and environment-friendly method of detecting food-safety-related molecules on various food surfaces through SERS.