RESUMEN
Changing the wettability and surface texturing have a significant impact on lubrication. In this study, the researchers used the molecular dynamics (MD) method to investigate how adjusting the interaction between alkanes and the wall affects oil film morphology and frictional properties under boundary lubrication. The findings revealed that the bearing capacity was influenced by both the morphology of the oil film and the strength of solid-liquid adsorption. In cases where the walls had weak wettability, the alkanes formed clusters to effectively separate the walls, while in cases where the walls had strong wettability, the oil film spread and formed a strong adsorption film. The super oleophilic textured surface could enhance the oil film adsorption capacity and replenish the oil film to the friction area in time, and the super oleophobic smooth surface could further reduce the friction coefficient. Therefore, a composite surface consisting of a super oleophilic textured surface and a super oleophobic smooth surface can be designed to enhance the bearing capacity of the oil film and reduce friction.
RESUMEN
Calcium salt precipitation is an effective solution to wastewater fluoride pollution. The purity and precipitation efficiency of calcium fluoride is critical for its removal and recovery. This study aimed to reveal the role of coexisting sulfates in the precipitation of calcium fluoride. A low sulfate concentration promoted calcium fluoride precipitation. The size of calcium fluoride-aggregated particle clusters increased from 750 to 2000 nm when the molar ratio of sulfate to fluoride was increased from 0 to 3:100. Sulfate doped in the calcium fluoride crystals neutralized the positive charge of the calcium fluoride. Online atomic force microscopy measurements showed that sulfate reduced the repulsive force between calcium fluoride crystals and increased the adhesion force from 1.62 to 2.46 nN, promoting the agglomeration of calcium fluoride crystals. Sulfate improved the precipitation efficiency of calcium fluoride by promoting agglomeration; however, the purity of calcium fluoride was reduced by doping. Sulfate reduced the induction time of calcium fluoride crystallization and improved the nucleation rate of calcium fluoride. Sulfate should be retained to improve the precipitation of calcium fluoride and to avoid its loss from the effluents. However, it is necessary to separate sulfate from fluoride to obtain high-purity calcium fluoride. Therefore, sulfate concentration regulation in high-fluoride wastewater is key to achieving the efficient removal and recovery of fluoride ions.
Asunto(s)
Fluoruro de Calcio , Fluoruros , Fluoruros/química , Aguas Residuales , Sulfatos/química , Contaminación Ambiental , CalcioRESUMEN
The effect of aqueous solution chemistry on the ionic hydration structure and its corresponding nanofiltration (NF) selectivity is a research gap concerning ion-selective transport. In this study, the hydration distribution of two typical monovalent anions (Cl- and NO3-) under different aqueous solution chemical conditions and the corresponding transmembrane selectivity during NF were investigated by using in situ liquid time-of-flight secondary ion mass spectrometry in combination with molecular dynamics simulations. We demonstrate the inextricable link between the ion hydration structure and the pore steric effect and further find that ionic transmembrane transport can be regulated by breaking the balance between the hydrogen bond network (i.e., water-water) and ion hydration (i.e., ion-water) interactions of hydrated ion. For strongly hydrated (H2O)nCl- with more intense ion-water interactions, a higher salt concentration and coexisting ion competition led to a larger hydrated size and, thus, a higher ion rejection by the NF membrane, whereas weakly hydrated (H2O)nNO3- takes the reverse under the same conditions. Stronger OH--anion hydration competition resulted in a smaller hydrated size of (H2O)nCl- and (H2O)nNO3-, showing a lower observed average hydration number at pH 10.5. This study deepens the long-overlooked understanding of NF separation mechanisms, concerning the hydration structure.
Asunto(s)
Filtración , Agua/química , Iones , Simulación de Dinámica Molecular , Soluciones , Aniones/químicaRESUMEN
Most aquatic plants applied to ecological restoration have demonstrated a clonal growth pattern. The risk-spreading strategy plays a crucial role in facilitating clonal plant growth under external environmental stresses via clonal integration. However, the effects of different concentrations of nanoplastics (NPs) on the growth traits of clonal aquatic plants are not well understood. Therefore, this study aimed to investigate the impact of NPs exposure on seedlings of parent plants and connected offspring ramets. A dose response experiment (0.1, 1, and 10 mg L-1) showed that the growth of Eichhornia crassipes (water hyacinth) was affected by 100 nm polystyrene nanoplastics after 28 days of exposure. Tracer analysis revealed that NPs are accumulated by parent plants and transferred to offspring ramets through stolon. Quantification analysis showed that when the parent plant was exposed to 10 mg L-1 NPs alone for 28 days, the offspring ramets contained approximately 13 ± 2 µg/g NPs. In the case of connected offspring ramets, leaf and root biomass decreased by 24%-51% and 32%-51%, respectively, when exposed to NP concentrations ranging from 0.1 to 10 mg L-1. Excessive enrichment of NPs had a detrimental effect on the photosynthetic system, decreasing the chlorophyll content and nonphotochemical quenching. An imbalance in the antioxidant defense systems, which were unable to cope with the oxidative stress caused by NP concentrations, further damaged various organs. The root system can take up NPs and then transfer them to the offspring through the stolon. Interference effects of NPs were observed in terms of root activity, metabolism, biofilm composition, and the plant's ability to purify water. However, the risk-spreading strategy employed by parent plants (interconnected offspring ramets) offered some relief from NP-induced stress, as it increased their relative growth rate by 1 to 1.38 times compared to individual plants. These findings provide substantial evidence of the high NP enrichment capacity of E. crassipes for ecological remediation. Nevertheless, we must also remain aware of the environmental risk associated with the spread of NPs within the clonal system of E. crassipes, and contaminated cloned individuals need to be precisely removed in a timely manner to maintain normal functions.
Asunto(s)
Microplásticos , Fotosíntesis , Humanos , Clorofila , Biomasa , Plantas/metabolismoRESUMEN
A large amount of sludge is inevitably produced during sewage treatment. Ultrasonication (US) as anaerobic digestion (AD) pretreatment was implemented on different sludges and its effects on batch and semi-continuous AD performance were investigated. US was effective in sludge SCOD increase, size decrease, and CH4 production in the subsequent AD, and these effects were enhanced with an elevated specific energy input. As indicated by semi-continuous AD experiments, the mean daily CH4 production of US-pretreated A2O-, A2O-MBR-, and AO-AO-sludge were 176.9, 119.8, and 141.7 NmL/g-VSadded, which were 35.1%, 32.1% and 78.2% higher than methane production of their respective raw sludge. The US of A2O-sludge achieved preferable US effects and CH4 production due to its high organic content and weak sludge structure stability. In response to US-pretreated sludge, a more diverse microbial community was observed in AD. The US-AD system showed negative net energy; however, it exhibited other positive effects, e.g., lower required sludge retention time and less residual total solids for disposal. US is a feasible option prior to AD to improve anaerobic bioconversion and CH4 yield although further studies are necessary to advance it in practice.
Asunto(s)
Reactores Biológicos , Metano , Aguas del Alcantarillado , Eliminación de Residuos Líquidos , Metano/metabolismo , Metano/análisis , Anaerobiosis , Eliminación de Residuos Líquidos/métodos , SonicaciónRESUMEN
With the increasing demand of recycling disposal of industrial wastewater, oil-in-water (O/W) emulsion has been paid much attention in recent years owing to its high oil content. However, due to the presence of surfactant and salt, the emulsion was usually stable with complex physicochemical interfacial properties leading to increased processing difficulty. Herein, a novel flow-through electrode-based demulsification reactor (FEDR) was well designed for the treatment of saline O/W emulsion. In contrast to 53.7% for electrical demulsification only and 80.3% for filtration only, the COD removal efficiency increased to 92.8% under FEDR system. Moreover, the pore size of electrode and the applied voltage were two key factors that governed the FEDR demulsification performance. By observing the morphology of oil droplets deposited layer after different operation conditions and the behavior of oil droplets at the electrode surface under different voltage conditions, the mechanism was proposed that the oil droplets first accumulated on the surface of flow-through electrode by sieving effect, subsequently the gathered oil droplets could further coalesce with the promoting effect of the anode, leading to a high-performing demulsification. This study offers an attractive option of using flow-through electrode to accomplish the oil recovery with simultaneous water purification.
Asunto(s)
Electrodos , Filtración , Eliminación de Residuos Líquidos , Purificación del Agua , Purificación del Agua/métodos , Filtración/métodos , Eliminación de Residuos Líquidos/métodos , Aceites/química , Aguas Residuales/química , Contaminantes Químicos del Agua/química , Emulsiones/química , Técnicas Electroquímicas/métodos , Técnicas Electroquímicas/instrumentaciónRESUMEN
Exploring the vast extraterrestrial space is an inevitable trend with continuous human development. Water treatment and reuse are crucial in the limited and closed space that is available in spaceships or long-term use space bases that will be established in the foreseeable future. Dedicated water treatment technologies have experienced iterative development for more than 60 years since the first manned spaceflight was successfully launched. Herein, we briefly review the related wastewater characteristics and the history of water treatment in space stations, and we focus on future challenges and perspectives, aiming at providing insights for optimizing wastewater treatment technologies and closing the water cycle in future.
Asunto(s)
Eliminación de Residuos Líquidos , Aguas Residuales , Purificación del Agua , Eliminación de Residuos Líquidos/métodos , Purificación del Agua/métodos , Vuelo EspacialRESUMEN
The desalination performance of flow electrode capacitive deionization (FCDI) is determined by the ion adsorption on the powdered activated carbon (PAC) and the electron transfer between the current collector and PAC. However, a comprehensive understanding of rate-limiting steps is lacking, let alone to enhance FCDI desalination by regulating the PAC characteristics. This study showed that the electron transfer between PAC and the current collector on the anode side was the rate-limiting step of FCDI desalination. Compared with W900, the desalination performance of FCDI decreased by 95% when W1200 with weak electron transfer ability was used as a flow electrode. The PAC selected in this study transferred electrons directly through the conductive carbon matrix in FCDI and was mainly affected by graphitization. The desalination performance of FCDI was improved by 20 times when the graphitization degree of PAC increased from 0.69 to 1.03. The minimum energy required for electrons to escape from the PAC surface was reduced by the high degree of graphitization, from 4.27 to 3.52 eV, thus improving the electron transfer capacity of PAC on the anode side. This study provides a direction for the optimization of flow electrodes and further promotes the development of FCDI.
Asunto(s)
Cloruro de Sodio , Purificación del Agua , Carbón Orgánico , Electrones , ElectrodosRESUMEN
Antibacterial modification is a chemical-free method to mitigate biofouling, but surface accumulation of bacteria shields antibacterial groups and presents a significant challenge in persistently preventing membrane biofouling. Herein, a great synergistic effect of electrorepulsion and quaternary ammonium (QA) inactivation on maintaining antibacterial activity against biofouling has been investigated using an electrically conductive QA membrane (eQAM), which was fabricated by polymerization of pyrrole with QA compounds. The electrokinetic force between negatively charged Escherichia coli and cathodic eQAM prevented E. coli cells from reaching the membrane surface. More importantly, cathodic eQAM accelerated the detachment of cells from the eQAM surface, particularly for dead cells whose adhesion capacity was impaired by inactivation. The number of dead cells on the eQAM surface was declined by 81.2% while the number of live cells only decreased by 49.9%. Characterization of bacteria accumulation onto the membrane surface using an electrochemical quartz crystal microbalance revealed that the electrorepulsion accounted for the cell detachment rather than inactivation. In addition, QA inactivation mainly contributed to minimizing the cell adhesion capacity. Consequently, the membrane fouling was significantly declined, and the final normalized water flux was promoted higher than 20% with the synergistic effect of electrorepulsion and QA inactivation. This work provides a unique long-lasting strategy to mitigate membrane biofouling.
RESUMEN
Electrocatalytic hydrogenation is acknowledged as a promising strategy for chlorophenol dechlorination. However, the widely used Pd catalysts exhibit drawbacks, such as high costs and low selectivity for phenol hydrosaturation. Herein, we demonstrate the potential and mechanism of Ru in serving as a Pd substitute using 2,4,6-trichlorophenol (TCP) as a model pollutant. Up to 99.8% TCP removal efficiency and 99% selectivity to cyclohexanol, a value-added compound with an extremely low toxicity, were achieved on the Ru electrode. In contrast, only 66% of TCP was removed on the Pd electrode, with almost no hydrosaturation selectivity. The superiority of Ru over Pd was especially noteworthy in alkaline conditions or the presence of interfering species such as S2-. The theoretical simulation demonstrates that Ru possesses a hydrodechlorination energy barrier of 0.72 eV, which is comparable to that on Pd. Meanwhile, hydrosaturation requires an activation energy of 0.69 eV on Ru, which is much lower than that on Pd (0.92 eV). The main reaction mechanism on Ru is direct electron transfer, which is distinct from that on Pd (indirect pathway via atomic hydrogen, H*). This work thereby provides new insights into designing cost-effective electrocatalysts for halogenated phenol detoxification and resource recovery.
Asunto(s)
Clorofenoles , Hidrogenación , Electrones , Fenol , Transporte de ElectrónRESUMEN
Membrane science and technology is growing rapidly worldwide and continues to play an increasingly important role in diverse fields by offering high separation efficiency with low energy consumption. Membranes have also shown great promise for "green" separation. A majority of the investigations in the field are devoted to the membrane fabrication and modification with the ultimate goals of enhancing the properties and separation performance of membranes. However, less attention has been paid to membrane life cycle management, particularly at the end of service. This is becoming very important, especially taking into account the trends toward sustainable development and carbon neutrality. On the contrary, this can be a great opportunity considering the large variety of membrane processes, especially in terms of the size and capacity of plants in operation. This work aims to highlight the prominent aspects that govern membrane life cycle management with special attention to life cycle assessment (LCA). While fabrication, application, and recycling are the three key aspects of LCA, we focus here on membrane (module) recycling at the end of life by elucidating the relevant aspects, potential criteria, and strategies that effectively contribute to the achievement of green development and sustainability goals.
Asunto(s)
Reciclaje , Tecnología , Animales , Estadios del Ciclo de VidaRESUMEN
Owing to nano-MoS2's excellent anti-friction and anti-wear properties, nano-MoS2, which can act as a nano-additive in lubricating oil or solid lubricants, is believed to have great potential in the lubrication of power machinery and moving parts of a spacecraft. The molecular dynamics method was used to construct a rough surface and a multi-level asperity structure to simulate starved lubrication before oil film breakdown, and the lubrication mechanism of MoS2 as a nano-additive or directly coated on the textured surface could reduce the friction coefficient and wear was explained from the atomic perspective. Simulations showed that the multilayer MoS2 played a role of load-bearing at light load or low velocity, and slipped into the grooves to repair the surface under heavy load or high velocity. Even if local asperity contact occurs, MoS2 nanoparticles could accelerate the detachment of the initial asperity contact to prevent large-scale adhesion. The MoS2 nanoparticles transformed the pure liquid oil film into a liquid-solid composite oil film, which was more suitable for lubrication under heavy load and high velocity because it increased the contact area, protected the friction surface and prevented asperity contact. The proposed lubrication mechanism contributes to understanding the frictional properties of layered nanomaterials under extreme conditions and provides a reference for further application of MoS2 materials in the field of lubrication.
RESUMEN
Selective separation of nitrate over chloride is crucial for eutrophication mitigation and nitrogen resource recovery but remains a challenge due to their similar ionic radius and the same valence. Herein, a polypyrrole membrane electrode (PME) was fabricated by polymerization of pyrrole (Py) and p-toluenesulfonate (pTS), which was used as a working electrode in redox transistor electrodialysis. The anions in the source solution were first incorporated into the PME at reduction potentials and then released to receiving solution at oxidation potentials. Pulse widths and potentials were optimized to maximize the ion separation performance of PME, resulting in the improvement of NO3-/Cl- separation factor up to 6.93. The ion distributions in various depths of PME indicated that both NO3- and Cl- were incorporated into PME at negative potentials. Then, NO3- was preferentially released from PME at positive potentials, but most Cl- was retained. This was ascribed to the high binding energy between Cl- and PPy/pTS structure, which was 51.4% higher than that between NO3- and PPy/pTS structure. Therefore, the higher transport rate of NO3- in comparison with Cl- was achieved, leading to a high NO3- selectivity over Cl-. This work provides a promising avenue for the selective separation of nitrate over chloride, which may contribute to nitrogen resource recycling and reuse.
Asunto(s)
Cloruros , Nitratos , Polímeros/química , Pirroles/química , Aniones , Electrodos , Oxidación-ReducciónRESUMEN
Electrocoagulation (EC) is a promising alternative for decentralized drinking water treatment in rural areas as a chemical-free technology. However, seasonal fluctuations of water quality in influent remain a significant challenge for rural decentralized water supply, which was a potential threat to water safety. The frequent operation was required to ensure the effluent water quality by the experienced technicians, who were in shortage in rural areas. If the operational parameters prediction model based on water quality could be established, it might reduce the dependence on technicians. Therefore, an artificial neural network (ANN) model combined with genetic algorithm (GA) was used to establish a prediction model for unattended intelligent operation. Data on water quality and operational parameters were collected from a practical EC system in a decentralized water treatment plant. Seven water quality parameters (e.g., turbidity, temperature, pH and conductivity) were selected as input variables and the operational current was employed as the output. A non-linear relationship between water quality parameters and the operational current was verified by correlation analysis and principal component analysis (PCA). The mean squared error (MSE) and coefficient of determination (R2) were used as evaluation indexes to optimize the structure of the GA-ANN model. Influent turbidity was identified to be crucial in the GA-ANN model by model interpretation using sensitivity analysis and scenario analysis. The Garson weight of turbidity in the seven input variables achieved 45.4%. The predictive accuracy of the GA-ANN model sharply declined from 90% to 67.1% when influent turbidity data were absent. In addition, it was estimated that energy consumption savings of the GA-ANN method declined by 14.2% in comparison with the gradient control method. This study verifies the feasibility and stability of machine learning strategy for unattended operation in the rural decentralized water treatment plant.
Asunto(s)
Redes Neurales de la Computación , Purificación del Agua , Calidad del Agua , Purificación del Agua/métodos , Electrocoagulación , Aprendizaje AutomáticoRESUMEN
Encapsulation of live cells in protective, semipermeable microcapsules is one of the kernel techniques for in vitro tissue regeneration, cell therapies, and pharmaceutical screening. Advanced fabrication techniques for cell encapsulation have been developed to meet different requirements. Existing cell encapsulation techniques place substantial constraints on the spatial patterning of live cells as well as on the compartmentalization of heterotypic cells. Alginate-Poly-L-lysine-alginate (APA) microcapsules that use sodium alginate as the polyanion and poly-L-lysine (PLL) as the polycation have been extensively employed for cell microencapsulation due to their excellent biocompatibility and biodegradability. This study proposes a novel method for developing programmable Janus APA microcapsules with variable shapes and sizes by using electrodeposition. By the versatile design of the microelectrode device, sequential electrodeposition is triggered to electro-address the cells at specific locations immobilized within a Janus APA microcapsule. The osteogenesis is evaluated by resembling cell compartmentalized and vascularized osteoblast-laden constructs. This technique allows precise spatial patterning of heterotypic cells inside the APA microcapsule, enabling the observation of cellular growth, interactions, and differentiation in a well-controlled chemical and mechanical microenvironment.
Asunto(s)
Galvanoplastia , Polilisina , Alginatos , Cápsulas , Polilisina/análogos & derivadosRESUMEN
Efficient pollutants removal and simultaneous resource recovery from wastewater are of great significance for sustainable development. In this study, an electrocatalytic hydrogenation (ECH) approach was developed to selectively and rapidly transform phenol to cyclohexanol, which possesses high economic value and low toxicity and can be easily recovered from the aqueous solution. A three-dimensional Ru/TiO2 electrode with abundant active sites and massive microflow channels was prepared for efficient phenol transformation. A pseudo-first-order rate constant of 0.135 min-1 was observed for ECH of phenol (1 mM), which was 34-fold higher than that of traditional electrochemical oxidation (EO). Both direct electron transfer and indirect reduction by atomic hydrogen (H*) played pivotal roles in the hydrogenation of phenol ring. The ECH technique also showed excellent performance in a wide pH range of 3-11 and with a high concentration of phenol (10 mM). Moreover, the functional groups (e.g., chloro- and methyl-) on phenol showed little influence on the superiority of the ECH system. This work provides a novel and practical solution for remediation of phenolic wastewater as well as recovery of valuable organic compounds.
Asunto(s)
Aguas Residuales , Contaminantes Químicos del Agua , Hidrogenación , Fenol/química , Fenoles , Contaminantes Químicos del Agua/químicaRESUMEN
Non-equilibrium molecular dynamics simulations of liquid flow through the surface were performed to investigate the flow resistance and thermal resistance under conditions of different solid-liquid interactions and surface temperatures. A novel phenomenon was observed in the simulation, namely the rise of surface temperature increases the flow resistance when solid-liquid interaction is weak, but decreases the flow resistance when solid-liquid interaction is strong. A higher density of the boundary layer brings a larger friction force to increase the flow resistance. For heat transfer, it is innovative to calculate the heat conduction and convection of the boundary region discretely. The results showed that the heat transfer performance of the interface is not positively correlated with the boundary liquid density, and the structure of the boundary liquid is also crucial. We believe that this research can improve the existing theory of flow heat transfer and provide a more effective method for analyzing the flow heat transfer of the solid-liquid interface.
RESUMEN
Molybdenum carbide is considered to be one of the most competitive catalysts for hydrogen evolution reaction (HER) regarding its high catalytic activity and superior corrosion resistance. But the low electrical conductivity and poor interfacial contact with the current collector greatly inhibit its practical application capability. Herein, carbon nanotube (CNT) supported molybdenum carbide was assembled via electrostatic adsorption combined with complex bonding. The N-doped molybdenum carbide nanocrystals were uniformly anchored on the surfaces of amino CNTs, which depressed the agglomeration of nanoparticles while strengthening the migration of electrons. The optimized catalyst (250-800-2h) showed exceptional electrocatalytic performance towards HER under both acidic and alkaline conditions. Especially in 0.5 M H2SO4 solution, the 250-800-2h catalyst exhibited a low overpotential of 136 mV at a current density of 10 mA/cm2 (η10) with the Tafel slope of 49.9 mV dec-1, and the overpotential only increased 8 mV after 20,000 cycles of stability test. The active corrosive experiment revealed that more exposure to high-activity γ-Mo2N promoted the specific mass activity of Mo, thus, maintaining the catalytic durability of the catalyst.
Asunto(s)
Nanotubos de Carbono , Adsorción , Catálisis , HidrógenoRESUMEN
Surfactants are widely used to improve the solubility of oil in water in petrochemical, making it more difficult to remove oil-water emulsions during the water treatment process. Electrocoagulation (EC) is an appropriate method for treating oily wastewater and destabilizing emulsions. However, the demulsification mechanism of oil-water droplets emulsified by surfactants with different charges have not been investigated systematically. The demulsification performance of electrocoagulation on emulsions wastewater containing cationic, non-ionic, and anionic surfactants was studied. The results showed that the removal rate of total organic carbon (TOC) in oily wastewater with anionic surfactant by EC reached 92.98% ± 0.40% at a current density of 1 mA/cm2, while that of the non-ionic surfactant was 84.88% ± 0.63%. The characterization of flocs showed that EC has the highest coagulation and demulsification of oil droplets with a negative charge on the surface (-70.50 ± 10.25 mV), which indicated that the charge neutralization of oil droplets was beneficial for the destabilization of the formed oily flocs. However, when the zeta potential of the oil droplets reached 75.50 ± 1.25 mV, the TOC removal efficiency was only 11.80% ± 1.43%. The TOC removal could achieve 33.23% ± 3.21% when the current density improved from 1 mA/cm2 to 10 mA/cm2. The enhanced removal was due to the sweep coagulation rather than charge neutralization. This study provides a fundamental basis for the electrochemical treatment of oily wastewater.
Asunto(s)
Surfactantes Pulmonares , Purificación del Agua , Electrocoagulación , Emulsiones/química , Tensoactivos/química , Purificación del Agua/métodosRESUMEN
Systemic cancer therapy is always accompanied with toxicity to normal tissue, which has prompted concerted efforts to develop precise treatment strategies. Herein, we firstly develop an approach that enables spatiotemporally controlled formation and rotation of magnetic nanochains in vivo, allowing for precise mechanotherapy of tumor. The nanochain comprised nanocomposites of pheophorbide-A (PP) modified iron oxide nanoparticle (IONP) and lanthanide-doped down-conversion NP (DCNP). In a permanent magnetic field, the nanocomposites would be aligned to form nanochain. Next, MnO2 NPs were subsequently administered to accumulate in tumor as suppliers of Mn2+ , which coordinates with PP to immobilize the nanochain. In a rotating magnetic field, the nanochain would rapidly rotate, leading to apoptosis/necrosis of tumor cell. The nanochain showed high T2 -MR and NIR-II fluorescence imaging signals, which facilitated guided therapy. The strategy has great potential in practical applications.